scholarly journals PList-based Divide and Conquer Parallel Programming

2020 ◽  
Vol 16 (2) ◽  
pp. 197-206
Author(s):  
Virginia Niculescu ◽  
Darius Bufnea ◽  
Adrian Sterca
Keyword(s):  
Parallel Programming ◽  
Building Blocks ◽  
Parallel Programs ◽  
Divide And Conquer ◽  
Existing Building ◽  
New Class ◽  
Programming Framework ◽  
Data Division ◽  
New Applications ◽  
Solvable Problems

This paper details an extension of a Java parallel programming framework – JPLF. The JPLF framework is a programming framework that helps programmers build parallel programs using existing building blocks. The framework is based on {\em PowerLists} and PList Theories and it naturally supports multi-way Divide and Conquer. By using this framework, the programmer is exempted from dealing with all the complexities of writing parallel programs from scratch. This extension to the JPLF framework adds PLists support to the framework and so, it enlarges the applicability of the framework to a larger set of parallel solvable problems. Using this extension, we may apply more flexible data division strategies. In addition, the length of the input lists no longer has to be a power of two – as required by the PowerLists theory. In this paper we unveil new applications that emphasize the new class of computations that can be executed within the JPLF framework. We also give a detailed description of the data structures and functions involved in the PLists extension of the JPLF, and extended performance experiments are described and analyzed.

A Bottom-Up Approach to Solution-Processed, Atomically Precise Graphitic Cylinders on Surfaces

2018 ◽  
Author(s):  
Erik Leonhardt ◽  
Jeff M. Van Raden ◽  
David Miller ◽  
Lev N. Zakharov ◽  
Benjamin Aleman ◽  
...  
Keyword(s):  
Self Assembly ◽  
Carbon Nanostructures ◽  
Carbon Nanomaterials ◽  
Circle Packing ◽  
Pyrolytic Graphite ◽  
Building Blocks ◽  
Bottom Up ◽  
Casting Technique ◽  
New Class ◽  
Solution Casting Technique

Extended carbon nanostructures, such as carbon nanotubes (CNTs), exhibit remarkable properties but are difficult to synthesize uniformly. Herein, we present a new class of carbon nanomaterials constructed via the bottom-up self-assembly of cylindrical, atomically-precise small molecules. Guided by supramolecular design principles and circle packing theory, we have designed and synthesized a fluorinated nanohoop that, in the solid-state, self-assembles into nanotube-like arrays with channel diameters of precisely 1.63 nm. A mild solution-casting technique is then used to construct vertical “forests” of these arrays on a highly-ordered pyrolytic graphite (HOPG) surface through epitaxial growth. Furthermore, we show that a basic property of nanohoops, fluorescence, is readily transferred to the bulk phase, implying that the properties of these materials can be directly altered via precise functionalization of their nanohoop building blocks. The strategy presented is expected to have broader applications in the development of new graphitic nanomaterials with π-rich cavities reminiscent of CNTs.

Electrochemical Oxidative Esterification of Thiophenols: Efficient Access to Sulfinic Esters

2020 ◽  
Vol 17 (7) ◽  
pp. 540-547
Author(s):  
Chun-Hui Yang ◽  
Cheng Wu ◽  
Jun-Ming Zhang ◽  
Xiang-Zhang Tao ◽  
Jun Xu ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Efficient Method ◽  
High Efficiency ◽  
Building Blocks ◽  
Constant Current ◽  
Good Efficiency ◽  
Oxidative Esterification ◽  
Efficient Access ◽  
New Applications ◽  
Sulfinic Esters

Background: The sulfinic esters are important and useful building blocks in organic synthesis. Objective: The aim of this study was to develop a simple and efficient method for the synthesis of sulfinic esters. Materials and Methods: Constant current electrolysis from thiols and alcohols was selected as the method for the synthesis of sulfinic esters. Results and Discussion: A novel electrochemical method for the synthesis of sulfinic esters from thiophenols and alcohols has been developed. Up to 27 examples of sulfinic esters have been synthesized using the current methods. This protocol shows good functional group tolerance as well as high efficiency. In addition, this protocol can be easily scaled up with good efficiency. Notably, heterocycle-containing substrates, including pyridine, thiophene, and benzothiazole, gave the desired products in good yields. A plausible reaction mechanism is proposed. Conclusion: This research not only provides a green and efficient method for the synthesis of sulfinic esters but also shows new applications of electrochemistry in organic synthesis. It is considered that this green and efficient synthetic protocol used to prepare sulfinic esters will have good applications in the future.

Parallel Computing Using the Prefix Problem

1994 ◽  
Author(s):  
S. Lakshmivarahan ◽  
Sudarshan K. Dhall
Keyword(s):  
Parallel Computing ◽  
Parallel Algorithms ◽  
Parallel Programming ◽  
Building Blocks ◽  
Efficient Solutions ◽  
Computer Scientists ◽  
Important Approach

The prefix operation on a set of data is one of the simplest and most useful building blocks in parallel algorithms. This introduction to those aspects of parallel programming and parallel algorithms that relate to the prefix problem emphasizes its use in a broad range of familiar and important problems. The book illustrates how the prefix operation approach to parallel computing leads to fast and efficient solutions to many different kinds of problems. Students, teachers, programmers, and computer scientists will want to read this clear exposition of an important approach.

scholarly journals Sophorolipid-Based Oligomers as Polyol Components for Polyurethane Systems

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 2001
Author(s):  
Maresa Sonnabend ◽  
Suzanne G. Aubin ◽  
Annette M. Schmidt ◽  
Marc C. Leimenstoll
Keyword(s):  
Special Property ◽  
Building Blocks ◽  
Conservation Of Resources ◽  
The Novel ◽  
Carbon Footprints ◽  
Proper Design ◽  
Chemical Products ◽  
Hydroxyl Fatty Acids ◽  
New Applications ◽  
Novel Products

Due to reasons of sustainability and conservation of resources, polyurethane (PU)-based systems with preferably neutral carbon footprints are in increased focus of research and development. The proper design and development of bio-based polyols are of particular interest since such polyols may have special property profiles that allow the novel products to enter new applications. Sophorolipids (SL) represent a bio-based toolbox for polyol building blocks to yield diverse chemical products. For a reasonable evaluation of the potential for PU chemistry, however, further investigations in terms of synthesis, derivatization, reproducibility, and reactivity towards isocyanates are required. It was demonstrated that SL can act as crosslinker or as plasticizer in PU systems depending on employed stoichiometry. (ω-1)-hydroxyl fatty acids can be derived from SL and converted successively to polyester polyols and PU. Additionally, (ω-1)-hydroxyl fatty acid azides can be prepared indirectly from SL and converted to A/B type PU by Curtius rearrangement.

Horde: A parallel programming framework for clusters

2009 ◽  
Author(s):  
Wenhao Xu ◽  
Yongwei Wu ◽  
Wei Xue ◽  
Wusheng Zhang ◽  
Ye Yuan ◽  
...  
Keyword(s):  
Parallel Programming ◽  
Programming Framework

3D printing technology in musical instrument research: reviewing the potential

2018 ◽  
Vol 24 (9) ◽  
pp. 1511-1523 ◽  
Author(s):  
Antreas Kantaros ◽  
Olaf Diegel
Keyword(s):  
Additive Manufacturing ◽  
Design Methodology ◽  
Musical Instrument ◽  
Musical Instruments ◽  
Wind Instruments ◽  
Content Type ◽  
New Class ◽  
History Of ◽  
New Applications ◽  
Practical Implications

Purpose This paper aims to discuss additive manufacturing (AM) in the context of applications for musical instruments. It examines the main AM technologies used in musical instruments, goes through a history of musical applications of AM and raises the questions about the application of AM to create completely new wind instruments that would be impossible to produce with conventional manufacturing. Design/methodology/approach A literature research is presented which covers a historical application of AM to musical instruments and hypothesizes on some potential new applications. Findings AM has found extensive application to create conventional musical instruments with unique aesthetics designs. It’s true potential to create entirely new sounds, however, remains largely untapped. Research limitations/implications More research is needed to truly assess the potential of additive manufacturing to create entirely new sounds for musical instrument. Practical implications The application of AM in music could herald an entirely new class of musical instruments with unique sounds. Originality/value This study highlights musical instruments as an unusual application of AM. It highlights the potential of AM to create entirely new sounds, which could create a whole new class of musical instruments.

scholarly journals Synthesis of new Cα-tetrasubstituted α-amino acids

2009 ◽  
Vol 5 ◽  
Author(s):  
Andreas A Grauer ◽  
Burkhard König
Keyword(s):  
Amino Acids ◽  
Secondary Structure ◽  
Aromatic Aldehydes ◽  
Building Blocks ◽  
Reaction Conditions ◽  
Peptide Backbone ◽  
Aliphatic Aldehydes ◽  
New Class ◽  
Cyclic Amino Acids

Cα-Tetrasubstituted α-amino acids are important building blocks for the synthesis of peptidemimetics with stabilized secondary structure, because of their ability to rigidify the peptide backbone. Recently our group reported a new class of cyclic Cα-tetrasubstituted tetrahydrofuran α-amino acids prepared from methionine and aromatic aldehydes. We now report the extension of this methodology to aliphatic aldehydes. Although such aldehydes are prone to give aldol products under the reaction conditions used, we were able to obtain the target cyclic amino acids in low to moderate yields and in some cases with good diastereoselectivity.

scholarly journals Cu/Pd-catalyzed borocarbonylative trifunctionalization of alkynes and allenes: synthesis of β-geminal-diboryl ketones

2021 ◽  
Author(s):  
Yang Yuan ◽  
Fu-Peng Wu ◽  
Anke Spannenberg ◽  
Xiao-Feng Wu
Keyword(s):  
Organic Synthesis ◽  
Functional Group ◽  
Building Blocks ◽  
Mechanistic Studies ◽  
Efficient Strategy ◽  
New Class ◽  
Reaction Proceeds

AbstractFunctionalized bisboryl compounds have recently emerged as a new class of synthetically useful building blocks in organic synthesis. Herein, we report an efficient strategy to synthesize β-geminal-diboryl ketones enabled by a Cu/Pd-catalyzed borocarbonylative trifunctionalization of readily available alkynes and allenes. This reaction promises to be a useful method for the synthesis of functionalized β-geminal-diboryl ketones with broad functional group tolerance. Mechanistic studies suggest that the reaction proceeds through borocarbonylation/hydroboration cascade of both alkynes and allenes.

scholarly journals Interaction with the User in the SAPFOR System

2021 ◽  
Vol 24 (1) ◽  
pp. 157-183
Author(s):  
Никита Андреевич Катаев
Keyword(s):  
Parallel Programming ◽  
Program Transformation ◽  
Heterogeneous Computing ◽  
Programming Model ◽  
Parallel Programs ◽  
Parallel Program ◽  
Program Parallelization ◽  
Parallel Programming Model ◽  
The One ◽  
High Level

Automation of parallel programming is important at any stage of parallel program development. These stages include profiling of the original program, program transformation, which allows us to achieve higher performance after program parallelization, and, finally, construction and optimization of the parallel program. It is also important to choose a suitable parallel programming model to express parallelism available in a program. On the one hand, the parallel programming model should be capable to map the parallel program to a variety of existing hardware resources. On the other hand, it should simplify the development of the assistant tools and it should allow the user to explore the parallel program the assistant tools generate in a semi-automatic way. The SAPFOR (System FOR Automated Parallelization) system combines various approaches to automation of parallel programming. Moreover, it allows the user to guide the parallelization if necessary. SAPFOR produces parallel programs according to the high-level DVMH parallel programming model which simplify the development of efficient parallel programs for heterogeneous computing clusters. This paper focuses on the approach to semi-automatic parallel programming, which SAPFOR implements. We discuss the architecture of the system and present the interactive subsystem which is useful to guide the SAPFOR through program parallelization. We used the interactive subsystem to parallelize programs from the NAS Parallel Benchmarks in a semi-automatic way. Finally, we compare the performance of manually written parallel programs with programs the SAPFOR system builds.

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