This work consists of the numerical simulation of high enthalpy flows. The numerical model is governed by Euler equations and supplemented by the equations of the chemical kinetics modeling the phenomena of the chemical air components in a non-equilibrium state. The finite differences method is used for numerical simulations, the phenomena of a hypersonic flow one-dimensional reactive, non-viscous, chemical non-equilibrium is developed taking into account the physicochemical phenomena like the vibration, the dissociation of the diatomic molecules, the ionization of molecules and the formed atoms of chemical species to higher temperatures which appear behind a strong shock detached and evolve according to time in a relaxation range until to reach the equilibrium state. We are interesting in particular on the temperature effect in ionization of the atoms and the molecules.