scholarly journals Easy Access To Allylic Sulfones Through Transition Metal-Free Hydrosulfonylation Of Allenes

2021 ◽  
Author(s):  
Lucas Pages ◽  
Sebastien Lemouzy ◽  
Marc Taillefer ◽  
Florian Monnier
Keyword(s):  
Transition Metal ◽  
Good Yield ◽  
Easy Access ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Brönsted Acid ◽  
One Step

A Brønsted acid-mediated addition of (hetero)aryl and (cyclo)alkyl sodium sulfinates to <i>N</i>-allenyl derivatives is described under very smooth conditions. This reaction provided a practical and efficient protocol for the synthesis of allylic sulfones in an atom- and step-economic fashion. In addition, an one-step double hydrosulfonylation has also been demonstrated, affording the corresponding 1,3-disulfone in to good yield.<br>

scholarly journals Easy Access To Allylic Sulfones Through Transition Metal-Free Hydrosulfonylation Of Allenes

2021 ◽  
Author(s):  
Lucas Pages ◽  
Sebastien Lemouzy ◽  
Marc Taillefer ◽  
Florian Monnier
Keyword(s):  
Transition Metal ◽  
Good Yield ◽  
Easy Access ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Brönsted Acid ◽  
One Step

A Brønsted acid-mediated addition of (hetero)aryl and (cyclo)alkyl sodium sulfinates to <i>N</i>-allenyl derivatives is described under very smooth conditions. This reaction provided a practical and efficient protocol for the synthesis of allylic sulfones in an atom- and step-economic fashion. In addition, an one-step double hydrosulfonylation has also been demonstrated, affording the corresponding 1,3-disulfone in to good yield.<br>

An efficient synthesis of pyrido[1,2-a]indoles through aza-Nazarov type cyclization

2015 ◽  
Vol 51 (9) ◽  
pp. 1701-1704 ◽  
Author(s):  
Iyyanar Karthikeyan ◽  
Dhanarajan Arunprasath ◽  
Govindasamy Sekar
Keyword(s):  
Transition Metal ◽  
Formic Acid ◽  
Indole Derivatives ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Efficient Synthesis ◽  
Metal Free ◽  
Brönsted Acid

Transition metal free Brønsted acid mediated synthesis of pyrido[1,2-a]indole scaffolds has been developed through aza-Nazarov type cyclization of readily available diaryl(2-pyridyl)methanol using formic acid for the synthesis of biologically and medicinally important pyrido[1,2-a]indole, indolo[1,2-a]quinoline and pyrimido[1,2-a]indole derivatives.

scholarly journals Brønsted acid-catalysed hydroarylation of unactivated alkynes in a fluoroalcohol–hydrocarbon biphasic system: construction of phenanthrene frameworks

2019 ◽  
Vol 55 (63) ◽  
pp. 9267-9270 ◽  
Author(s):  
Ikko Takahashi ◽  
Takeshi Fujita ◽  
Noriaki Shoji ◽  
Junji Ichikawa
Keyword(s):  
Transition Metal ◽  
Solvent System ◽  
Biphasic System ◽  
System Construction ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Two Phase ◽  
Metal Free ◽  
Brönsted Acid

Transition metal-free, Brønsted acid-catalysed hydroarylation of unactivated alkynes was achieved in a two-phase solvent system consisting of 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP) and cyclohexane.

Metal free carboamination of internal alkynes – an easy access to polysubstituted quinolines

2016 ◽  
Vol 52 (33) ◽  
pp. 5761-5764 ◽  
Author(s):  
T. Stopka ◽  
M. Niggemann
Keyword(s):  
Bond Formation ◽  
Acid Catalyst ◽  
Easy Access ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Brönsted Acid ◽  
Brønsted Acid Catalyst ◽  
Internal Alkynes ◽  
Brönsted Acid Catalyst

A synergistic Brønsted acid catalyst was used to intermolecularly generate vinyl cations for a C–C bond formation – Schmidt rearrangement – sequence.

Brønsted Acid-Catalyzed Solvent-Controlled Regioselective Hydrothiolation and Diastereoselective Cascade Cyclization of Dienes

2021 ◽  
Author(s):  
Kai Ji ◽  
Ka Lu ◽  
Jie Huang ◽  
Zi-Hao Li ◽  
Tong-Mei Ding ◽  
...  
Keyword(s):  
Free Atom ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Cascade Cyclization ◽  
Brönsted Acid ◽  
Acid Catalyzed ◽  
First Time

A highly regio- and diastereo-selective Brønsted acid-catalyzed tandem hydrothiolation/Friedel-Crafts reaction of linear 1,3-dienes has been developed for the first time, which provides a metal-free, atom-economic and concise way of constructing...

scholarly journals Brønsted acid-catalyzed metal-free one-pot synthesis of benzimidazoles via [4+1] heteroannulation of ortho-phenylenediamines with β-oxodithioesters

ARKIVOC ◽  
2017 ◽  
Vol 2018 (2) ◽  
pp. 81-89
Author(s):  
Abhijeet Srivastava ◽  
Gaurav Shukla ◽  
Dhananjay Yadav ◽  
Maya Shankar Singh
Keyword(s):  
Bronsted Acid ◽  
Brønsted Acid ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis ◽  
Brönsted Acid ◽  
Acid Catalyzed

One-Step Conversion of Biomass-Derived Furanics into Aromatics by Brønsted Acid Ionic Liquids at Room Temperature

2018 ◽  
Vol 6 (2) ◽  
pp. 2541-2551 ◽  
Author(s):  
Lingli Ni ◽  
Jiayu Xin ◽  
Kun Jiang ◽  
Lu Chen ◽  
Dongxia Yan ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
One Step

Organic Photoredox Catalytic α-C(sp3)–H Phosphorylation of Saturated Aza-Heterocycles

2021 ◽  
Author(s):  
Ming-Jun Yi ◽  
Teng-Fei Xiao ◽  
Wen-Hui Li ◽  
Yi-Fan Zhang ◽  
Pen-Ji Yan ◽  
...  
Keyword(s):  
Acid Catalysis ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Mild Conditions ◽  
Brönsted Acid ◽  
Bronsted Acid Catalysis

A metal-free C(sp3)–H phosphorylation of saturated aza-heterocycles via the merger of organic photoredox and Brønsted acid catalysis was established under mild conditions. This protocol provided a straightforward and economic access...

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