Open-shell Donors and Closed-shell Acceptors in Organic Solar Cells
Keyword(s):
The active materials of organic solar cells are widely recognized to show closed-shell singlet ground state and their electron spin resonance signals are attributed to the defects and impurities. Herein, we disclose the inherent open-shell singlet ground state of donors and the closed-shell structure of acceptors via the combination of variable temperature NMR, electron spin resonance, superconducting quantum interference device and theoretical calculation, providing a new perspective to understand the intrinsic molecular structure in organic solar cells.
2013 ◽
Vol 52
(5S1)
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pp. 05DC13
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2016 ◽
Vol 120
(21)
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pp. 11415-11425
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2002 ◽
Vol 16
(20n22)
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pp. 3373-3376
1974 ◽
Vol 96
(21)
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pp. 6559-6568
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2010 ◽
Vol 40
(2)
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pp. 171-176
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1967 ◽
Vol 1
(5)
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pp. 235-238
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