scholarly journals Properties of Single Walled  Carbon Nanotube Films

2021 ◽  
Author(s):  
◽  
Shrividya Ravi

<p>The preparation and physical properties of transparent, single-walled carbon nanotube (SWNT) networks fabricated from a novel, organic dispersion are described here for the first time. Characterisation of SWNT dispersions uncovered shifts in the radial breathing modes as a function of aggregation. These modes were redshifted in centrifuged butylamine dispersions by ~3cm -1. SWNT films cast using a simple, drop-deposition technique were annealed at 300'C after fabrication to remove solvent and surfactant residue. Annealed films with a sheet resistance of magnitude ~10 4 kOhms/square and transparency of ~85 % were fabricated in this study. The optoelectronic properties showed some inconsistency due to varying levels of oxygen doping and film thickness. Thin films annealed at 500'C were found to be preferentially depleted of nanotubes with high chiral angle and small diameter. Oxidative effects were also observed upon annealing at temperatures as low as 300'C. However, the reasons for this premature combustion are as yet uncertain. Temperature-dependent conduction studies revealed that the removal of adsorbed surfactant considerably reduced tunnelling barriers in annealed films. The dominant conduction mechanism in both unannealed and annealed films was found to be 3D variable range hopping. In the annealed films, a high temperature activation regime (with activation energy of 220 meV) was observed above 225 K. This regime is due to thermal activation over Schottky barriers within the nanotube network or electron activation over the pseudogap in armchair tubes.</p>

2021 ◽  
Author(s):  
◽  
Shrividya Ravi

<p>The preparation and physical properties of transparent, single-walled carbon nanotube (SWNT) networks fabricated from a novel, organic dispersion are described here for the first time. Characterisation of SWNT dispersions uncovered shifts in the radial breathing modes as a function of aggregation. These modes were redshifted in centrifuged butylamine dispersions by ~3cm -1. SWNT films cast using a simple, drop-deposition technique were annealed at 300'C after fabrication to remove solvent and surfactant residue. Annealed films with a sheet resistance of magnitude ~10 4 kOhms/square and transparency of ~85 % were fabricated in this study. The optoelectronic properties showed some inconsistency due to varying levels of oxygen doping and film thickness. Thin films annealed at 500'C were found to be preferentially depleted of nanotubes with high chiral angle and small diameter. Oxidative effects were also observed upon annealing at temperatures as low as 300'C. However, the reasons for this premature combustion are as yet uncertain. Temperature-dependent conduction studies revealed that the removal of adsorbed surfactant considerably reduced tunnelling barriers in annealed films. The dominant conduction mechanism in both unannealed and annealed films was found to be 3D variable range hopping. In the annealed films, a high temperature activation regime (with activation energy of 220 meV) was observed above 225 K. This regime is due to thermal activation over Schottky barriers within the nanotube network or electron activation over the pseudogap in armchair tubes.</p>


2016 ◽  
Vol 697 ◽  
pp. 789-794
Author(s):  
Kai Zhang ◽  
Zi Wei Xu ◽  
Feng Ding ◽  
Gui Wu Liu ◽  
Guan Jun Qiao

The coalescence of the fullerenes encapsulated in the host single-walled carbon nanotube (SWNT) with bend junction is explored theoretically by energy driven kinetic Monte Carlo (EDKMC) method. Despite the lower productivity of successful coalescence (with clear identified chiralitys), there is still a possibility to form the inner tube with bend junction which can copy the separated pentagon and heptagon from the host tube exactly with the chiralitys at the two sides clearly identified. The statistic to ~20 successfully coalesced inner tubes with bend junctions shows that the chiral angle differences (CAD) between the two sides > 20 o, which is determined by the minimization of the formation energies of the junctions. Therefore, the chirality distribution of the inner tube may be effectively narrowed by tuning the CAD of the bend host tube, which may provide an alternative way to the application of specific control to the chiralitys.


2003 ◽  
Vol 788 ◽  
Author(s):  
Diana-Andra Borca-Tasciuc ◽  
Yann LeBon ◽  
Claire Nanot ◽  
Gang Chen ◽  
Theodorian Borca-Tasciuc ◽  
...  

ABSTRACTThis work reports temperature dependent thermal and electrical properties characterization of long (mm size) single-walled carbon nanotube strands. Electrical properties are measured using a 4-probe method. Thermal conductivity and specific heat capacity are determined using an AC driven, self-heating method. Normalized values of resistivity, thermal conductivity, specific heat, thermal diffusivity, and the temperature coefficient of resistance are reported. The trends observed in the temperature dependent properties are comparable with previously published data on multi-walled carbon nanotube strands measured with a similar technique.


2013 ◽  
Vol 113 (14) ◽  
pp. 144306 ◽  
Author(s):  
Robert A. Sayer ◽  
Jeffrey D. Engerer ◽  
N. S. Vidhyadhiraja ◽  
Timothy S. Fisher

Carbon ◽  
2016 ◽  
Vol 107 ◽  
pp. 865-871 ◽  
Author(s):  
Maoshuai He ◽  
Lili Zhang ◽  
Hua Jiang ◽  
He Yang ◽  
Frédéric Fossard ◽  
...  

2015 ◽  
Vol 106 (18) ◽  
pp. 183108 ◽  
Author(s):  
A. Duzynska ◽  
A. Taube ◽  
K. P. Korona ◽  
J. Judek ◽  
M. Zdrojek

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