Preparation of Polymer-Clay Nanocomposites by Melt Mixing in a Twin Screw Extruder: Using On-Line SAOS Rheometry to Assess the Level of Dispersion

2014 ◽  
Vol 29 (1) ◽  
pp. 63-70 ◽  
Author(s):  
S. Mould ◽  
J. Barbas ◽  
A. V. Machado ◽  
J. M. Nóbrega ◽  
J. A. Covas
2004 ◽  
Vol 19 (4) ◽  
pp. 342-349 ◽  
Author(s):  
H. Chen ◽  
U. Sundararaj ◽  
K. Nandakumar ◽  
M. D. Wetzel

2011 ◽  
Vol 322 ◽  
pp. 394-397 ◽  
Author(s):  
Lan Fang Guan ◽  
Jin Zhou Chen

This paper mainly researched how polyfunctional monomers affect the Compatibilization of PP/TPU blends. With triallylisocyanurate (TAIC) and trimethylolpropane triacrylate (TMPTA) which belong to polyfunctional monomers as compatibilizers, various PP/TPU blends were prepared via melt mixing by using a twin-screw extruder. It is investigated that the effect of polyfunctional monomer on the mechanical properties, morphology and melt flowing behavior of the blends. The results show that the compatibility of PP/TPU is improved by adding moderate TAIC or TMPTA, and the compatibilization effect of TMPTA is superior to TAIC, especially when the content of monomers is 3 phr.


2011 ◽  
Vol 66 (1) ◽  
pp. 103-110 ◽  
Author(s):  
Yasuya Nakayama ◽  
Eiji Takeda ◽  
Takashi Shigeishi ◽  
Hideki Tomiyama ◽  
Toshihisa Kajiwara

2010 ◽  
Vol 644 ◽  
pp. 17-20 ◽  
Author(s):  
S. López-García ◽  
Saul Sánchez-Valdés ◽  
L.F. Ramos de Valle

A study of the effect of an ionomer compatibilizer (surlyn® 9520 and 9721, both with zinc as the neutralizing cation) on the morphology and properties of a high density polyethylene (HDPE) - montmorillonite clay nanocomposite was carried out. The nanoclay used was cloisite 20A®. Polyethylene /Ionomer /Clay nanocomposites were prepared via melt mixing in a twin screw extruder. The nanoclay dispersion and exfoliation were examined through X-Ray Difraction (XRD) and Scanning Electron Microscopy (SEM). TGA was carried out to determine the effect of nanoclay on the thermal stability of the HDPE nanocomposites. Results showed that both ionomers impart a marked compatibility between the polymer and the nanoclay, promoting the exfoliation of the nanoclay within the HDPE matrix. Nonetheless, ionomer 9520 (with the higher degree of neutralization) at 10 and 12 wt% content produced completely exfoliated morphologies, whereas, the ionomer 9721 produced a lesser degree of exfoliation with few tactoids.


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