Frenkel’s model for the late stage of coalescence of viscous particles has been extended to describe pore collapse in a viscoelastic melt during polymer sintering. The shrinkage of a pore in a polymer melt driven by surface tension is extended by taking into account the effects of trapped gas and gas transport out of the pore. Viscoelasticity has been shown to have a considerable impact on the time scale of the coalescence process. In addition, gas diffusion modifies the coalescence dynamics. Based on a parameter study, different regimes for the pore collapse have been identified. At the beginning of pore collapse, surface tension is considerably stronger than gas pressure within the pore. In this time interval (surface-tension-driven regime), the pore shrinks even in the absence of gas diffusion through the matrix. In the absence of gas transport, the shrinkage dynamic slows down and stops when the surface tension balances the gas pressure in the pore. If gas transport out of the pore is possible, surface tension and gas pressure are balanced while the gas pressure slowly decreases (diffusion-controlled regime). The final phase of pore collapse, which occurs when the gas pressure within the pore decreases sufficiently, is controlled again by surface tension. The limitations of the model are discussed. To analyze the interplay between different mechanisms and process steps during selective laser sintering, the respective time scales are compared using experimental data.
Gas Transport across Carbon Nitride Nanopores: A Comparison of van der Waals Functionals against the Random-Phase Approximation
