Biotite supports long-range diffusive transport in dissolution–precipitation creep in halite through small porosity fluctuations

Phyllosilicates are generally regarded to have a reinforcing effect on chemical compaction by dissolution–precipitation creep (DPC) and thereby influence the evolution of hydraulic rock properties relevant to groundwater resources and geological repositories as well as fossil fuel reservoirs. We conducted oedometric compaction experiments on layered NaCl–biotite samples to test this assumption. In particular, we aim to analyse slow chemical compaction processes in the presence of biotite on the grain scale and determine the effects of chemical and mechanical feedbacks. We used time-resolved (4-D) microtomographic data to capture the dynamic evolution of the porosity in layered NaCl–NaCl/biotite samples over 1619 and 1932 h of compaction. Percolation analysis in combination with advanced digital volume correlation techniques showed that biotite grains influence the dynamic evolution of porosity in the sample by promoting a reduction of porosity in their vicinity. However, the lack of preferential strain localisation around phyllosilicates and a homogeneous distribution of axial shortening across the sample suggests that the porosity reduction is not achieved by pore collapse but by the precipitation of NaCl sourced from outside the NaCl–biotite layer. Our observations invite a renewed discussion of the effect of phyllosilicates on DPC, with a particular emphasis on the length scales of the processes involved. We propose that, in our experiments, the diffusive transport processes invoked in classical theoretical models of DPC are complemented by chemo-mechanical feedbacks that arise on longer length scales. These feedbacks drive NaCl diffusion from the marginal pure NaCl layers into the central NaCl–biotite mixture over distances of several hundred micrometres and several grain diameters. Such a mechanism was first postulated by Merino et al. (1983).

Integrating Laboratory Testing and Numerical Modelling for a Giant Maturing Carbonate Field in UAE — II. Coupled Geomechanical Modelling of Stacked Reservoir Intervals

A mature field located in a gently dipping structure onshore Abu Dhabi has multiple stacked oil and gas reservoirs experiencing different levels of depletion. The average reservoir pressure in some of these intervals had declined from the early production years to the present day by more than 2000 psi. Coupled geomechanical modelling is, therefore, of the greatest value to predict the stress paths in producing reservoir units, using the concept of effective stress. This paper examines the implications for long-term field management—focusing primarily on estimating the potential for reservoir compaction and predicting field subsidence. This paper takes the work reported in Noufal et al. (2020) one step further by integrating the results of a comprehensive geomechanical laboratory characterization study designed to assess the potential geomechanical changes in the stacked reservoirs from pre-production conditions to abandonment. This paper adopts a geomechanical modelling approach integrating a wide array of data—including prestack seismic inversion outputs and dynamic reservoir simulation results. This study comprised four phases. After the completion of rock mechanics testing, the first modelling phase examined geomechanics on a fine scale around individual wells. The goal of the second phase was to build 4D mechanical earth models (4D MEMs) by incorporating 14 reservoir models—resulting in one of the largest 4D MEMs ever built worldwide. The third phase involved determining the present-day stress state—matching calibrated post-production 1D MEMs and interpreted stress features. Lastly, the resulting model was used for field management and formation stimulation applications. The 4D geomechanical modelling results indicated stress changes in the order of several MPa in magnitude compared with the pre-production stress state, and some changes in stress orientations, especially in the vicinity of faults. This was validated using well images and direct stress measurements, indicating the ability of the 4D MEM to capture the changes in stress magnitudes and orientations caused by depletion. In the computed results, the 4D MEM captures the onset of pore collapse and its accelerating response as observed in the laboratory tests conducted on cores taken from different reservoir units. Pore collapse is predicted in later production years in areas with high porosity, and it is localized. The model highlights the influence of stress changes on porosity and permeability changes over time, thus providing insights into the planning of infill drilling and water injection. Qualitatively, the results provide invaluable insights into delineating potential sweet spots for stimulation by hydraulic fracturing.

Synchrotron 4D X-Ray Imaging Reveals Strain Localization at the Onset of System-Size Failure in Porous Reservoir Rocks

Understanding the mechanisms of strain localization leading to brittle failure in reservoir rocks can shed light on geomechanical processes such as porosity and permeability evolution during rock deformation, induced seismicity, fracturing, and subsidence in geological reservoirs. We perform triaxial compression tests on three types of porous reservoir rocks to reveal the local deformation mechanisms that control system-size failure. We deformed cylindrical samples of Adamswiller sandstone (23% porosity), Bentheim sandstone (23% porosity), and Anstrude limestone (20% porosity), using an X-ray transparent triaxial deformation apparatus. This apparatus enables the acquisition of three-dimensional synchrotron X-ray images, under in situ stress conditions. Analysis of the tomograms provide 3D distributions of the microfractures and dilatant pores from which we calculated the evolving macroporosity. Digital volume correlation analysis reveals the dominant strain localization mechanisms by providing the incremental strain components of pairs of tomograms. In the three rock types, damage localized as a single shear band or by the formation of conjugate bands at failure. The porosity evolution closely matches the evolution of the incremental strain components of dilation, contraction, and shear. With increasing confinement, the dominant strain in the sandstones shifts from dilative strain (Bentheim sandstone) to contractive strain (Adamswiller sandstone). Our study also links the formation of compactive shear bands with porosity variations in Anstrude limestone, which is characterized by a complex pore geometry. Scanning electron microscopy images indicate that the microscale mechanisms guiding strain localization are pore collapse and grain crushing in sandstones, and pore collapse, pore-emanated fractures and cataclasis in limestones. Our dynamic X-ray microtomography data brings unique insights on the correlation between the evolutions of rock microstructure, porosity evolution, and macroscopic strain during the approach to brittle failure in reservoir rocks.

Biotite supports long-range diffusive transport in dissolution-precipitation creep in halite

Phyllosilicates are generally regarded to have a reinforcing effect on chemical compaction by dissolution-precipitation creep (DPC) and thereby influence the evolution of hydraulic rock properties relevant to groundwater resources, geological repositories as well as fossil fuel reservoirs. We conducted oedometric compaction experiments on layered NaCl-biotite samples to test this assumption. In particular, we aim to analyse slow chemical compaction processes in the presence of biotite on the grain scale and determine the effects of chemical and mechanical feedbacks. We used time-resolved (4D) microtomographic data to capture the dynamic evolution of the transport properties in layered NaCl-NaCl/biotite samples over 1619 and1932 hours of compaction. Percolation analysis in combination with advanced digital volume correlation techniques showed that biotite grains influence the dynamic evolution of porosity in the sample by promoting a reduction of porosity in their vicinity. However, the lack of preferential strain localisation around phyllosilicates and a homogeneous distribution of axial shortening across the sample suggests that the porosity reduction is not achieved by pore collapse but by the precipitation of NaCl sourced from outside the NaCl/biotite layer. Our observations invite a renewed discussion of the effect of phyllosilicates on DPC, with a particular emphasis on the length scales of the processes involved. We propose that, in our experiments, the diffusive transport processes invoked in classical theoretical models of DPC are superseded by chemo-mechanical feedbacks that arise on longer length scales. These feedbacks drive NaCl diffusion from the marginal pure NaCl layers into the central NaCl-biotite mixture over distances of several hundredμm and several grain diameters. Such a mechanism was first postulated by Merino et al. (1983)

Constitutive Modeling of the Densification Behavior in Open-Porous Cellular Solids

The macroscopic mechanical behavior of open-porous cellular materials is dictated by the geometric and material properties of their microscopic cell walls. The overall compressive response of such materials is divided into three regimes, namely, the linear elastic, plateau and densification. In this paper, a constitutive model is presented, which captures not only the linear elastic regime and the subsequent pore-collapse, but is also shown to be capable of capturing the hardening upon the densification of the network. Here, the network is considered to be made up of idealized square-shaped cells, whose cell walls undergo bending and buckling under compression. Depending on the choice of damage criterion, viz. elastic buckling or irreversible bending, the cell walls collapse. These collapsed cells are then assumed to behave as nonlinear springs, acting as a foundation to the elastic network of active open cells. To this end, the network is decomposed into an active network and a collapsed one. The compressive strain at the onset of densification is then shown to be quantified by the point of intersection of the two network stress-strain curves. A parameter sensitivity analysis is presented to demonstrate the range of different material characteristics that the model is capable of capturing. The proposed constitutive model is further validated against two different types of nanoporous materials and shows good agreement.

Modelling of Pore Collapse during Polymer Sintering: Viscoelastic Model with Enclosed Gas

Frenkel’s model for the late stage of coalescence of viscous particles has been extended to describe pore collapse in a viscoelastic melt during polymer sintering. The shrinkage of a pore in a polymer melt driven by surface tension is extended by taking into account the effects of trapped gas and gas transport out of the pore. Viscoelasticity has been shown to have a considerable impact on the time scale of the coalescence process. In addition, gas diffusion modifies the coalescence dynamics. Based on a parameter study, different regimes for the pore collapse have been identified. At the beginning of pore collapse, surface tension is considerably stronger than gas pressure within the pore. In this time interval (surface-tension-driven regime), the pore shrinks even in the absence of gas diffusion through the matrix. In the absence of gas transport, the shrinkage dynamic slows down and stops when the surface tension balances the gas pressure in the pore. If gas transport out of the pore is possible, surface tension and gas pressure are balanced while the gas pressure slowly decreases (diffusion-controlled regime). The final phase of pore collapse, which occurs when the gas pressure within the pore decreases sufficiently, is controlled again by surface tension. The limitations of the model are discussed. To analyze the interplay between different mechanisms and process steps during selective laser sintering, the respective time scales are compared using experimental data.

The mechanical behaviour and failure modes of volcanic rocks: a review

The microstructure and mineralogy of volcanic rocks is varied and complex, and their mechanical behaviour is similarly varied and complex. This review summarises recent developments in our understanding of the mechanical behaviour and failure modes of volcanic rocks. Compiled data show that, although porosity exerts a first-order influence on the uniaxial compressive strength of volcanic rocks, parameters such as the partitioning of the void space (pores and microcracks), pore and crystal size and shape, and alteration also play a role. The presence of water, strain rate, and temperature can also influence uniaxial compressive strength. We also discuss the merits of micromechanical models in understanding the mechanical behaviour of volcanic rocks (which includes a review of the available fracture toughness data). Compiled data show that the effective pressure required for the onset of hydrostatic inelastic compaction in volcanic rocks decreases as a function of increasing porosity, and represents the pressure required for cataclastic pore collapse. Differences between brittle and ductile mechanical behaviour (stress-strain curves and the evolution of porosity and acoustic emission activity) from triaxial deformation experiments are outlined. Brittle behaviour is typically characterised by shear fracture formation, and an increase in porosity and permeability. Ductile deformation can either be distributed (cataclastic pore collapse) or localised (compaction bands) and is characterised by a decrease in porosity and permeability. The available data show that tuffs deform by delocalised cataclasis and extrusive volcanic rocks develop compaction bands (planes of collapsed pores connected by microcracks). Brittle failure envelopes and compactive yield caps for volcanic rocks are compared, highlighting that porosity exerts a first-order control on the stresses required for the brittle-ductile transition and shear-enhanced compaction. However, these data cannot be explained by porosity alone and other microstructural parameters, such as pore size, must also play a role. Compactive yield caps for tuffs are elliptical, similar to data for sedimentary rocks, but are linear for extrusive volcanic rocks. Linear yield caps are considered to be a result of a high pre-existing microcrack density and/or a heterogeneous distribution of porosity. However, it is still unclear, with the available data, why compaction bands develop in some volcanic rocks but not others, which microstructural attributes influence the stresses required for the brittle-ductile transition and shear-enhanced compaction, and why the compactive yield caps of extrusive volcanic rocks are linear. We also review the Young’s modulus, tensile strength, and frictional properties of volcanic rocks. Finally, we review how laboratory data have and can be used to improve our understanding of volcanic systems and highlight directions for future research. A deep understanding of the mechanical behaviour and failure modes of volcanic rock can help refine and develop tools to routinely monitor the hazards posed by active volcanoes.