scholarly journals Non-Destructive Photon Activation Analysis in Paleontology

Proceedings ◽  
2018 ◽  
Vol 2 (10) ◽  
pp. 564
Author(s):  
Tyler C. Borgwardt

Paleontological samples are rare and non-renewable, which makes the study of their chemical or physical characteristics require non-destructive methods. Physical characteristics are routinely studied with non-destructive methods; however, chemical studies tend to require destructive methods unless samples are very small or only the surface compositions are of interest. One potential technique for non-destructive elemental analysis is photon activation analysis (PAA). PAA is a versatile, broad-spectrum, multi-element analysis tool with low sensitivities, capable of analyzing large samples without any alteration, preserving the physical characteristics. Recent work has applied PAA to fossils and their source matrices in an attempt to correlate provenance through trace element analysis. PAA was shown to be non-consumptive and able to identify 20+ elements in samples with sub-ppm sensitivities. From that work, several lessons were learned and the non-destructivity of the technique was better characterized. PAA doesn’t have one standardized methodology, as it varies depending on the sample type. As such, from the lessons learned from the previous research, a standard method of applying PAA non-destructively to paleontological samples has been developed and will be presented in the following paper.

2014 ◽  
Vol 61 (4) ◽  
pp. 2137-2143 ◽  
Author(s):  
Frederick Carrel ◽  
Bruno Charbonnier ◽  
Romain Coulon ◽  
Frederic Laine ◽  
Stephane Normand ◽  
...  

The elemental compositions of archaeological artefacts, ancient and medieval coins, and metallic art objects have been determined by non-destructive neutron activation analysis. Examples are given of studies of prehistoric trade routes and cultural contacts based on the identification of the geologic origins of obsidian artefacts, of early economic systems based on the determination of debasement patterns in medieval Islamic and Western gold and silver coinage, the region of manufacture as well as authentication of ancient metallic art objects based on trace element analysis. Special procedures devised for performing these analyses are described.


Minerals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 617
Author(s):  
Ivana Krausová ◽  
Jiří Mizera ◽  
Zdeněk Řanda ◽  
David Chvátil ◽  
Pavel Krist

This paper introduces instrumental photon activation analysis (IPAA) utilizing short-lived products of photonuclear reactions, mainly (γ, n) and (γ, p), initiated by bremsstrahlung from the MT-25 microtron. A rapid nondestructive IPAA method for geochemical major element analysis is introduced as a tool for the basic geochemical characterization of rocks. Procedures were developed and parameters such as beam energy and irradiation-decay-counting times optimized with a representative set of geochemical reference materials, and an optimized scheme was applied in analysis of various geological samples. A complete analytical scheme combined with long-time irradiation IPAA and the possibility of utilization of photoexcitation reactions (γ, γ′) are briefly outlined.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Pasquale Avino ◽  
Geraldo Capannesi ◽  
Francesco Lopez ◽  
Alberto Rosada

Human activities introduce compounds increasing levels of many dangerous species for environment and population. In this way, trace elements in airborne particulate have a preeminent position due to toxic element presence affecting the biological systems. The main problem is the analytical determination of such species at ultratrace levels: a very specific methodology is necessary with regard to the accuracy and precision and contamination problems. Instrumental Neutron Activation Analysis and Instrumental Photon Activation Analysis assure these requirements. A retrospective element analysis in airborne particulate collected in the last 4 decades has been carried out for studying their trend. The samples were collected in urban location in order to determine only effects due to global aerosol circulation; semiannual samples have been used to characterize the summer/winter behavior of natural and artificial origin. The levels of natural origin element are higher than those in other countries owing to geological and meteorological factors peculiar to Central Italy. The levels of artificial elements are sometimes less than those in other countries, suggesting a less polluted general situation for Central Italy. However, for a few elements (e.g., Pb) the levels measured are only slight lower than those proposed as air ambient standard.


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