Phase Diagram of Binary Alloy Nanoparticles under High Pressure

CALPHAD (CALculation of PHAse Diagram) is a useful tool to construct phase diagrams of various materials under different thermodynamic conditions. Researchers have extended the use of the CALPHAD method to nanophase diagrams and pressure phase diagrams. In this study, the phase diagram of an arbitrary A–B nanoparticle system under pressure was investigated. The effects of the interaction parameter and excess volume were investigated with increasing pressure. The eutectic temperature was found to decrease in most cases, except when the interaction parameter in the liquid was zero and that in the solid was positive, while the excess volume parameter of the liquid was positive. Under these conditions, the eutectic temperature increased with increasing pressure.

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Quantification of the liquid window of deep eutectic solvents

Chemical Communications ◽

10.1039/c8cc05815f ◽

2018 ◽

Vol 54 (95) ◽

pp. 13351-13354 ◽

Cited By ~ 23

Author(s):

Laura J. B. M. Kollau ◽

Mark Vis ◽

Adriaan van den Bruinhorst ◽

A. Catarina C. Esteves ◽

Remco Tuinier

Keyword(s):

Phase Diagram ◽

Interaction Parameter ◽

Eutectic Temperature ◽

Deep Eutectic Solvents ◽

Eutectic Phase ◽

Eutectic Phase Diagram

The non-ideality of the eutectic phase diagram is quantified using a single interaction parameter that could be determined directly from the experimental eutectic temperature of the mixture.

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New-Type Co-Based Superalloys Designed by CALPHAD Method

Materials Science Forum ◽

10.4028/www.scientific.net/msf.816.578 ◽

2015 ◽

Vol 816 ◽

pp. 578-580 ◽

Cited By ~ 1

Author(s):

Shu Yu Yang ◽

Min Jiang ◽

Lei Wang

Keyword(s):

Phase Diagram ◽

Phase Equilibria ◽

Phase Diagrams ◽

Calculated Phase Diagram ◽

Calphad Method ◽

Two Phase ◽

Calculated Phase ◽

New Type

The phase equilibria of new-type Co-based superalloys which include the system of Co-Al-W were studied by CALPHAD method. It was shown that γ+γ' two-phase regions were existed in the calculated phase diagrams. The compositions of new-type Co-based superalloys which can obtain γ+γ' microstructures were predicted due to the calculated phase diagram. The mole fractions of the constituent phases of Co-Al-W-Ni-Cr alloys were calculated. The temperature of γ' phase began to precipitate at about 1050°C.

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Temperature-pressure phase diagram of deuterated tetramethylammonium tetrachlorozincate

Journal de Physique ◽

10.1051/jphys:01984004505092900 ◽

1984 ◽

Vol 45 (5) ◽

pp. 929-938 ◽

Cited By ~ 25

Author(s):

G. Marion ◽

R. Almairac ◽

M. Ribet ◽

U. Steigenberger ◽

C. Vettier

Keyword(s):

Phase Diagram ◽

Pressure Phase

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Calculation of phase diagrams and thermodynamic properties of 14 additive and reciprocal ternary systems containing Li2CO3, Na2CO3, K2CO3, Li2SO4, Na2SO4, K2SO4, LiOH, NaOH, and KOH

Canadian Journal of Chemistry ◽

10.1139/v84-078 ◽

1984 ◽

Vol 62 (3) ◽

pp. 457-474 ◽

Cited By ~ 19

Author(s):

A. D. Pelton ◽

C. W. Bale ◽

P. L. Lin

Keyword(s):

Phase Diagram ◽

Thermodynamic Properties ◽

Molten Salt ◽

Phase Diagrams ◽

Binary Systems ◽

Ternary Phase ◽

Ternary Phase Diagram ◽

Ternary Systems ◽

Maximum Error ◽

Critical Assessment

Phase diagrams and thermodynamic properties of five additive molten salt ternary systems and nine reciprocal molten salt ternary systems containing the ions Li+, Na+, [Formula: see text], OH− are calculated from the thermodynamic properties of their binary subsystems which were obtained previously by a critical assessment of the thermodynamic data and the phase diagrams in these binary systems. Thermodynamic properties of ternary liquid phases are estimated from the binary properties by means of the Conformal Ionic Solution Theory. The ternary phase diagrams are then calculated from these thermodynamic properties by means of computer programs designed for the purpose. It is found that a ternary phase diagram can generally be calculated in this way with a maximum error about twice that of the maximum error in the binary phase diagrams upon which the calculations are based. If, in addition, some reliable ternary phase diagram measurements are available, these can be used to obtain small ternary correction terms. In this way, ternary phase diagram measurements can be smoothed and the isotherms drawn in a thermodynamically correct way. The thermodynamic approach permits experimental data to be critically assessed in the light of thermodynamic principles and accepted solution models. A critical assessment of error limits on all the calculated ternary diagrams is made, and suggestions as to which composition regions merit further experimental study are given.

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Temperature–Pressure Phase Diagram for Rb2ZnCl4 Crystals

Journal of Applied Spectroscopy ◽

10.1007/s10812-015-0090-3 ◽

2015 ◽

Vol 82 (2) ◽

pp. 228-233 ◽

Cited By ~ 1

Author(s):

V. Yu. Kurlyak ◽

V. Yo. Stadnyk ◽

V. Stakhura

Keyword(s):

Phase Diagram ◽

Pressure Phase

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Investigations on the Phase Diagram and Interaction Parameter of Poly(styrene-b-1,3-cyclohexadiene) Copolymers

Macromolecules ◽

10.1021/acs.macromol.7b00104 ◽

2017 ◽

Vol 50 (6) ◽

pp. 2354-2363 ◽

Cited By ~ 1

Author(s):

Konstantinos Misichronis ◽

Jihua Chen ◽

Adam Imel ◽

Rajeev Kumar ◽

James Thostenson ◽

...

Keyword(s):

Phase Diagram ◽

Interaction Parameter

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In situ determination of high pressure phase diagrams of methane-heavy hydrocarbon mixtures using an infrared absorption method

Fluid Phase Equilibria ◽

10.1016/0378-3812(95)02982-6 ◽

1996 ◽

Vol 119 (1-2) ◽

pp. 213-230 ◽

Cited By ~ 25

Author(s):

Ph. Marteau ◽

P. Tobaly ◽

V. Ruffier-Meray ◽

A. Barreau

Keyword(s):

High Pressure ◽

Phase Diagrams ◽

Infrared Absorption ◽

High Pressure Phase ◽

Absorption Method ◽

Hydrocarbon Mixtures ◽

Heavy Hydrocarbon ◽

Pressure Phase

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Melting Temperature of FeO under Pressure

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.717.184 ◽

2013 ◽

Vol 717 ◽

pp. 184-187

Author(s):

Shuai Zhang ◽

Lei Chen

Keyword(s):

Phase Diagram ◽

Melting Temperature ◽

Surface Stress ◽

Clapeyron Equation ◽

Metallurgical Processes ◽

Pressure Phase ◽

Effect Of Surface ◽

Volume Difference

The melting temperature-pressure phase diagram [Tm(P)-P] for wustite (FeO) is predicted through the Clapeyron equation where the pressure-dependent volume difference is modeled by introducing the effect of surface stress induced pressure. FeO plays an important role in many metallurgical processes and in the Earths mantle mineralogy. FeO is also of great interest in the field of state solid physics and chemistry because of its electrical, magnetic, structural and non-stoichiometric properties.

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