scholarly journals Collective Magnetic Behavior of 11 nm Photo-Switchable CsCoFe Prussian Blue Analogue Nanocrystals: Effect of Dilution and Light Intensity

2021 ◽  
Vol 7 (7) ◽  
pp. 99
Author(s):  
Linh Trinh ◽  
Eric Rivière ◽  
Sandra Mazerat ◽  
Laure Catala ◽  
Talal Mallah

The collective magnetic behavior of photoswitchable 11 nm cyanide-bridged nanoparticles based of the Prussian blue analogue CsCoFe were investigated when embedded in two different matrices with different concentrations. The effect of the intensity of light irradiation was studied in the less concentrated sample. Magnetization studies and alternating magnetic susceptibility data are consistent with a collective magnetic behavior due to interparticle dipolar magnetic interaction for the two compounds, even though the objects have a size that place them in the superparamagnetic regime.

2021 ◽  
Vol 1028 ◽  
pp. 15-20
Author(s):  
Muhammad Abdan Syakuur ◽  
Yati Maryati ◽  
Togar Saragi ◽  
Risdiana

Structure and magnetic properties of electron-doped superconducting cuprates have been investigated in order to study the effect of magnetic impurity to its physical properties. Here, we reported structure and magnetic properties of Eu1.88Ce0.12Cu1-yZnyO4+α-δ (ECCZO) with y = 0 and 0.03. The properties of ECCZO have been studied from X-ray diffraction data and temperature dependence of magnetic susceptibility data, to elucidate the effect of partial substitution of non-magnetic impurity Zn for Cu to its structure, Tc and the value of magnetic moments per unit volume extracted from susceptibility data in normal state. Magnetic-susceptibility measurements were carried out down to 2 K on-field cooling at 5 Oe for Eu1.88Ce0.12Cu1-yZnyO4+a-d with y = 0 and 0.03. For ECCZO sample with y = 0 and d = 0.0669 indicated the change of magnetic behavior from paramagnetic to diamagnetic below 12 K which is addressed to the Tc onset of this samples. Diamagnetic behavior is observed starting from about 12 K. Above 12 K, all samples show paramagnetic behavior with the values of the magnetic moment in every volume unit increased with increasing Zn.


2008 ◽  
Vol 22 (05) ◽  
pp. 359-368 ◽  
Author(s):  
I. ARDELEAN ◽  
R. LUNGU ◽  
P. PASCUTA

Glasses of the x Fe 2 O 3 · (100 - x)[2 B 2 O 3 · SrO ] system (0 ≤ x ≤ 40 mol% ) were prepared and studied by electron paramagnetic resonance (EPR) and magnetic susceptibility measurements. EPR investigations indicated the compositional domains favorable to the presence of isolated iron ions or to those magnetically clustered. The magnetic susceptibility data evidenced the presence of both Fe 3+ and Fe 2+ ions, with their relative content depending on the Fe 2 O 3 concentration. Dipolar and superexchange interactions involving iron ions were revealed depending on the iron content of the sample.


1989 ◽  
Vol 175 ◽  
Author(s):  
Wolfgang Haase ◽  
Stefan Gehring ◽  
Bettina Borchers

AbstractMagnetic susceptibility data (300–520 K) of monomeric and dimeric mesogenic copper(II) compounds are presented. Different magnetic effects arising from the paramagnetic Cu(II)-centres and the diamagnetic anisotropy of the mesogenic groups are observed and discussed with respect to possible inter molecular interactions.


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