The Effect of Partial Substitution of Non-Magnetic Impurity Zn on the Magnetic Moments of Eu1.88Ce0.12Cu1-yZnyO4+α-δ

Structure and magnetic properties of electron-doped superconducting cuprates have been investigated in order to study the effect of magnetic impurity to its physical properties. Here, we reported structure and magnetic properties of Eu1.88Ce0.12Cu1-yZnyO4+α-δ (ECCZO) with y = 0 and 0.03. The properties of ECCZO have been studied from X-ray diffraction data and temperature dependence of magnetic susceptibility data, to elucidate the effect of partial substitution of non-magnetic impurity Zn for Cu to its structure, Tc and the value of magnetic moments per unit volume extracted from susceptibility data in normal state. Magnetic-susceptibility measurements were carried out down to 2 K on-field cooling at 5 Oe for Eu1.88Ce0.12Cu1-yZnyO4+a-d with y = 0 and 0.03. For ECCZO sample with y = 0 and d = 0.0669 indicated the change of magnetic behavior from paramagnetic to diamagnetic below 12 K which is addressed to the Tc onset of this samples. Diamagnetic behavior is observed starting from about 12 K. Above 12 K, all samples show paramagnetic behavior with the values of the magnetic moment in every volume unit increased with increasing Zn.

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The Dependence of Magnetic Moments on Magnetic Impurities of Ni in Eu1.86Ce0.14Cu1-yNiyO4+a-d

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.860.148 ◽

2020 ◽

Vol 860 ◽

pp. 148-153

Author(s):

Muhammad Abdan Syakuur ◽

Yati Maryati ◽

Utami Widyaiswari ◽

Dita Puspita Sari ◽

Togar Saragi ◽

...

Keyword(s):

Magnetic Susceptibility ◽

Low Temperatures ◽

Unit Volume ◽

Magnetic Impurity ◽

Magnetic Moments ◽

Magnetic Impurities ◽

Superconducting Cuprates ◽

Susceptibility Data ◽

Diamagnetic Behavior ◽

Volume Unit

The partially substitution of magnetic impurity Ni for Cu in electron-doped superconducting cuprates of Eu2-xCexCu1-yNiyO4+a-d with x = 0.14 and y = 0, 0.01 and 0.02 has been studied in order to investigate the effect of Ni impurity on structure and the value of magnetic moments per unit volume extracted from susceptibility data in under-doped region. Magnetic-susceptibility measurements were carried out at low temperatures down to 2 K. For sample with y = 0, diamagnetic behavior is observed starting from about 9 K. The superconductivity disappeared at y ³ 0.01. The values of magnetic moment in every volume unit decreased with increasing Ni.

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Synthesis, Structures and Magnetic Properties of a Family of One-Dimensional Oxides

MRS Proceedings ◽

10.1557/proc-453-379 ◽

1996 ◽

Vol 453 ◽

Cited By ~ 1

Author(s):

H.-C. Zur Loye ◽

P. Núñez ◽

M. A. Rzeznik

Keyword(s):

Magnetic Properties ◽

Magnetic Susceptibility ◽

Rietveld Refinement ◽

Diffraction Data ◽

X Ray Diffraction ◽

Magnetic Susceptibility Data ◽

One Dimensional ◽

X Ray ◽

Susceptibility Data ◽

The One

AbstractThe one-dimensional compounds Sr3MgPtO6, Sr3MgIrO6, Sr3MgRhO6, Sr3GdRhO6, have been synthesized and structurally characterized by Rietveld refinement of powder X-ray diffraction data. All four compounds are isostructural with the rhombohedral K4CdCl6-type structure. The structure consists of infinite one-dimensional chains of alternating face-shared MO6 octahedra (M = Pt, Ir, Rh) and M′O6 (M′ = Gd, Mg) trigonal prisms. The strontium cations are located in a distorted square antiprismatic environment. Magnetic susceptibility data show that both Sr3MgIrO6 and Sr3MgRhO6 obey the Curie-Weiss law with θ = −6(1) K, and θ= −15(3)K, respectively. Sr3GdRhO6 obeys the Curie law with μeff = 7.80 B.M, consistent with an oxidation state of +3 for both rhodium and gadolinium.

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Synthesis, crystal structure, and magnetic properties of the complex [(CH3)3NH]2 [Co(NCS)4]

Zeitschrift für Naturforschung B ◽

10.1515/znb-2018-0069 ◽

2018 ◽

Vol 73 (8) ◽

pp. 571-575

Author(s):

Yang Jie ◽

Huang Yuan ◽

Zhong YouQuan ◽

Fang Ting ◽

Hao Fan ◽

...

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Infrared Spectroscopy ◽

Magnetic Measurements ◽

X Ray Diffraction ◽

Magnetic Susceptibility Data ◽

X Ray ◽

Susceptibility Data ◽

Ferromagnetic Interactions

AbstractA new complex [(CH3)3NH]2[Co(NCS)4], in which zero-dimensional [Co(NCS)4]n2− anions are balanced by 2n [(CH3)3NH]+ cations, was synthesized. The complex has been characterized by single X-ray diffraction, infrared spectroscopy, elemental analysis, and magnetic measurements. Magnetic susceptibility data indicate ferromagnetic interactions among the CoII ions.

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Syntheses, Crystal Structures and Magnetic Properties of Cr(NCNH2)4Cl2 and Mn(NCNH2)4Cl2

Zeitschrift für Naturforschung B ◽

10.5560/znb.2012-0234 ◽

2012 ◽

Vol 67 (11) ◽

pp. 1205-1211 ◽

Cited By ~ 2

Author(s):

Xiaojuan Tang ◽

Manfred Speldrich ◽

Andrei L. Tchougréeff ◽

Richard Dronskowski

Keyword(s):

Magnetic Properties ◽

Magnetic Susceptibility ◽

Quantum Theory ◽

Transition Metal Ions ◽

Chloride Ions ◽

Many Body ◽

X Ray Diffraction ◽

Magnetic Susceptibility Data ◽

X Ray ◽

Susceptibility Data

The two isotypic compounds Cr(NCNH2)4Cl2 and Mn(NCNH2)4Cl2 have been synthesized and characterized by X-ray diffraction. They crystallize in the cubic space group Im3̄m (Z = 6) with a = 12:643(2) Å for Cr(NCNH2)4Cl2 and a = 12:821(1) Å for Mn(NCNH2)4Cl2. The divalent transition metal ions are octahedrally coordinated by four H2NCN molecules in equatorial and two chloride ions in axial positions. The magnetic susceptibility data of the four Curie-paramagnetic compounds Cr(NCNH2)4Cl2, Mn(NCNH2)4Cl2, Co(NCNH2)4Cl2, and Ni(NCNH2)4Cl2 have been analyzed in greater detail, including many-body quantum theory.

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Collective Magnetic Behavior of 11 nm Photo-Switchable CsCoFe Prussian Blue Analogue Nanocrystals: Effect of Dilution and Light Intensity

Magnetochemistry ◽

10.3390/magnetochemistry7070099 ◽

2021 ◽

Vol 7 (7) ◽

pp. 99

Author(s):

Linh Trinh ◽

Eric Rivière ◽

Sandra Mazerat ◽

Laure Catala ◽

Talal Mallah

Keyword(s):

Magnetic Susceptibility ◽

Light Intensity ◽

Prussian Blue ◽

Magnetic Behavior ◽

Magnetic Interaction ◽

Light Irradiation ◽

Prussian Blue Analogue ◽

Magnetic Susceptibility Data ◽

Susceptibility Data

The collective magnetic behavior of photoswitchable 11 nm cyanide-bridged nanoparticles based of the Prussian blue analogue CsCoFe were investigated when embedded in two different matrices with different concentrations. The effect of the intensity of light irradiation was studied in the less concentrated sample. Magnetization studies and alternating magnetic susceptibility data are consistent with a collective magnetic behavior due to interparticle dipolar magnetic interaction for the two compounds, even though the objects have a size that place them in the superparamagnetic regime.

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Magnetic Properties of Liquid Crystals Incorporating Metal Centres

MRS Proceedings ◽

10.1557/proc-175-249 ◽

1989 ◽

Vol 175 ◽

Cited By ~ 5

Author(s):

Wolfgang Haase ◽

Stefan Gehring ◽

Bettina Borchers

Keyword(s):

Magnetic Properties ◽

Magnetic Susceptibility ◽

Liquid Crystals ◽

Molecular Interactions ◽

Magnetic Susceptibility Data ◽

Susceptibility Data ◽

Magnetic Effects ◽

Diamagnetic Anisotropy

AbstractMagnetic susceptibility data (300–520 K) of monomeric and dimeric mesogenic copper(II) compounds are presented. Different magnetic effects arising from the paramagnetic Cu(II)-centres and the diamagnetic anisotropy of the mesogenic groups are observed and discussed with respect to possible inter molecular interactions.

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Ferromagnetic interactions in a dicyanamide-bridged multinuclear metal-organic framework [Pr3NH]+ [Mn(dca)3]−·H2O

Zeitschrift für Naturforschung B ◽

10.1515/znb-2019-0015 ◽

2019 ◽

Vol 74 (6) ◽

pp. 485-489

Author(s):

Yuan Huang ◽

Xiu-feng Yu ◽

Zhen Rong ◽

Yi-chun Ai ◽

Kun Qian ◽

...

Keyword(s):

Magnetic Susceptibility ◽

Magnetic Measurements ◽

Metal Organic Framework ◽

Three Dimensional ◽

X Ray Diffraction ◽

Magnetic Susceptibility Data ◽

X Ray ◽

Susceptibility Data ◽

Metal Organic ◽

Ferromagnetic Interactions

AbstractA new complex [Pr3NH]+ [Mn(dca)3]− · H2O (dicyanamide = dca−) was synthesized, in which the Mn2+ cations are bridged by end-to-end dca anions to form three-dimensional [Mn(dca)3]nn− networks and tripropylammonium cations reside in the cavities of these networks. The complex has been characterized by single-crystal X-ray diffraction, infrared spectroscopy, elemental analysis, and magnetic measurements. Magnetic susceptibility data indicate ferromagnetic interactions among the MnII ions.

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Crystal Structure and Magnetic Properties of (2,2'-Dipyridyl)-(2-acetylphenolato)copper(II) Perchlorate

Zeitschrift für Naturforschung B ◽

10.1515/znb-2002-1009 ◽

2002 ◽

Vol 57 (10) ◽

pp. 1129-1132 ◽

Cited By ~ 3

Author(s):

A. Elmali ◽

Y. Elerman ◽

I. Svoboda

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Magnetic Moment ◽

Basal Plane ◽

Effective Magnetic Moment ◽

Mixed Ligand ◽

Magnetic Susceptibility Data ◽

Susceptibility Data ◽

Dimeric Unit

The mixed-ligand dinuclear complex (2,2'-dipyridyl)-(2-acetylphenolato)copper(II) perchlorate was synthesized and its crystal structures determined. The structure consists of a dimeric unit involving a planar Cu2O2 group. The coordination sphere of the Cu atom can be described as an alongated octahedron where the basal plane is formed by the two N atoms of the 2,2'-dipyridyl molecule and the two O atoms of the acetophenon anion. Two apical Cu - O contacts complete the 4+2 coordination of the Cu atoms. They correspond to one of the O atoms of the perchlorate anion and to the O atom of the second unit. Magnetic susceptibility data obey the Curie-Weiss law with θ = -8.1(2) K. The decreasing of the effective magnetic moment from 1.94(8) μB at 300 K to 1.86(8) μB at 70 K and the negative Weiss constant indicate weak antiferromagnetic interactions between the two copper atoms in the dimeric units.

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THE EFFECT OF PARTIAL ATOMIC SUBSTITUTION ON ELECTRIC AND MAGNETIC PROPERTIES OF (Bi,Pb):2223 SINTERED SUPERCONDUCTORS

International Journal of Modern Physics B ◽

10.1142/s0217979203022763 ◽

2003 ◽

Vol 17 (26) ◽

pp. 4675-4681 ◽

Cited By ~ 1

Author(s):

A. V. POP ◽

M. POP ◽

I. I. GERU

Keyword(s):

Magnetic Properties ◽

Magnetic Susceptibility ◽

Electrical Resistance ◽

Ac Susceptibility ◽

Partial Substitution ◽

Superconducting Transition ◽

Ac Magnetic Susceptibility ◽

Atomic Concentration ◽

Susceptibility Data ◽

Atomic Substitution

The effect of partial substitution of Ca by x = 0.02 La on the electrical and magnetically properties of two (Bi,Pb):2223 superconductor ceramic S1 and S2 (with different Pb and Sr atomic concentration) were investigated by using electrical resistance and AC magnetic susceptibility measurements. The parameters from linear resistivity data in the normal state and superconducting transition are sensitive to the compounds stoechiomerty. The intergrain critical current density JcJ(T) dependence near Tc obtained from immaginary AC susceptibility data agrees with the assumption of SNS intergrain junctions.

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