An Uneven Chain-like Ferromagnetic Copper(II) Coordination Polymer Displaying Metamagnetic Behavior and Long-Range Magnetic Ordering
Keyword(s):
Ferromagnetic coupling exists in an uneven chain-like copper(II) complex with both end-on azido and syn-syn carboxylato bridges, (Cu3(L)2(N3)4(H2O)3)n (1, HL = 6-hydroxynicotinic acid). It is the first example of one-dimensional (1D) chain-like copper(II) coordination polymer showing both metamagnetic behavior and long-range magnetic ordering (Tc = 6.7 K), thanks to the interchain hydrogen bonds, which make a three-dimensional (3D) supramolecular array of the entire molecular structure and mediate the interchain antiferromagnetic interaction.
2020 ◽
Vol 76
(5)
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pp. 599-604
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2012 ◽
Vol 68
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pp. m1131-m1131
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2013 ◽
Vol 69
(10)
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pp. 1140-1143
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2012 ◽
Vol 68
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pp. m41-m44
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2019 ◽
Vol 75
(9)
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pp. 1243-1249
2014 ◽
Vol 70
(7)
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pp. 702-706
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2018 ◽
Vol 74
(10)
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pp. 1128-1132
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