scholarly journals Influence of the Structural-Phase State of a Copper Substrate upon Modification with Titanium Ions on the Thermal Cyclic Resistance of a Coating Based on Zr-Y-O

Metals ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 65
Author(s):  
Marina Vladimirovna Fedorischeva ◽  
Mark Kalashnikov ◽  
Irina Bozhko ◽  
Victor Sergeev

The results of investigation of the surface of a copper substrate modified with titanium ions are presented. The phase composition, the structure, and the morphology of the surface of the copper alloy modified by titanium ions have been investigated by X-ray, SEM, and TEM. It has been established that there are the intermetallic phases of the Cu-Ti equilibrium diagram in the surface layer during the treatment of copper by the titanium ions. A multilevel micro- and nanoporous structure is formed in the modified layer. It has been established that the structure-phase state and morphology of the surface layers of copper directly effects on the thermocycler resistance and adhesion of the Zr-Y-O coating. The thermocyclic resistance of the Zr-Y-O coating increases by an order of magnitude, the adhesion to the substrate is 2 times if the substrate surface is treated with titanium ions for 6 min.

2021 ◽  
pp. 5-9
Author(s):  
V. V. Akimov ◽  
◽  
A. M. Badamshin ◽  
S. N. Nesov ◽  
S. N. Povoroznyuk ◽  
...  

Using experimental methods of analysis, the morphology, elemental composition and chemical state of hard alloys of the «TiC-TiNi» system in the initial state and after various types of ion-beam treatment have been investigated. It is found that the effect of a continuous ion beam leads to an increase in the microhardness of the investigated alloys by 10–12 %. When samples are irradiated with a pulsed ion beam, as a result of destruction of surface layers, the microhardness value decreases by 20 %, as a result of which this type of modification is not preferable for alloys of the TiC-TiNi system


2021 ◽  
Vol 9 ◽  
pp. 34-52
Author(s):  
V. N. Pimenov ◽  
◽  
S.A. Maslyaev ◽  

The results of the analysis of damageability and modification of the structural-phase state of the surface layers of aluminum and its alloys by powerful flows of fast high-energy ions and high-temperature plasma in Plasma focus devices, as well as using pulsed laser radiation. Pure Al, an alloy of the Al – Mg – Li system, a duralumin alloy, and a composition of a ceramic coating Al2O3 on an Al substrate are considered. It is shown that in the regime of Al irradiation with a power density of q ≈ 106 – 107 W/cm2 in the nano- and microsecond range of pulse durations, ultrafast crystallization of melted surface layer occurs with the formation of a wavy surface relief and the structural fragments of sub-microcrystalline and nanoscale size. After the action of deuterium plasma flows on a duralumin alloy tube located along the axis of the Plasma focus device a modification of the structural-phase state of the alloy is observed: the initial two-phase state of an αAl-solid solution of copper in aluminum and inclusions of the second phase of CuAl2 became fine-grained and single-phase due to the dissolution of CuAl2 particles in the melt. Irradiation of an alloy of the Al – Mg – Li system containing (wt %) 2 % Li and 5 % Mg at q = 5·106 W/cm2, t = 50 – 100 ns after four pulsed impacts of fast ions and deuterium plasma led to the modification the structural-phase state of the surface layer of the alloy, associated with an increase in the content of magnesium oxide and a decrease in the crystal lattice parameter of the Al-based solid solution. The formation of spherical cavities due to the evaporation of lithium into the internal micropores of the surface layer was also found. The low damage and structural stability of Al2O3 ceramics on an Al substrate under beam-plasma impacts in plasma focus device with a radiation power density q ≤ 108 – 109 W/cm2 in the nano- and microsecond range of pulse duration is noted. At the same time, the Al2O3/Al composition was unstable to pulsed laser radiation in the free-running mode (q = 105 – 106 W/cm2, t = 0.7 ms) and Q-switch mode (q = 107 – 108 W/cm2, t = 80 ns). In both cases the coating peeled off from the substrate.


2019 ◽  
Vol 41 (12) ◽  
pp. 1611-1629 ◽  
Author(s):  
M. O. Vasylyev ◽  
◽  
B. M. Mordyuk ◽  
S. M. Voloshko ◽  
A. P. Burmak ◽  
...  

2007 ◽  
Vol 43 (3) ◽  
pp. 370-376
Author(s):  
O. I. Yas’kiv ◽  
I. M. Pohrelyuk ◽  
V. M. Fedirko ◽  
O. Yu. Bonchyk ◽  
T. M. Kravchyshyn

2019 ◽  
Vol 16 (32) ◽  
pp. 945-966
Author(s):  
V. V. OVCHINNIKOV ◽  
N. V. UCHEVATKINA ◽  
I. A. KURBATOVA ◽  
E. V. LUKYANENKO ◽  
S. V. YAKUTINA

The relevance of the article is due to the fact that the use of titanium alloys within friction joints is restrained by their low resistance to wear while traditional methods of increasing their wear resistance are ineffective. The objective of this work was to study the processes occurring on the surface of VT6 titanium alloy samples when implanting with copper and aluminum ions, as well as in friction. Elemental composition, structural-phase state, mechanical and tribological properties of VT6 titanium alloy surface layers modified by aluminum and copper ions during the high-intensity ion-implantation process was being researched. As can be seen from the undertaken studies, the mode of the high-intensity ion-implantation process makes it possible to obtain ion doped surface layers of VT6 alloy containing TiAl, Ti3Al, Ti3Cu, Ti2Cu, TiCu finely dispersed intermetallic phases and a solid solution of aluminum and copper in titanium of composition varying in depth. The thickness of the ion-doped layer, the average grain size of the intermetallic phases (from 18 to 55nm) and their conglomerates (from 45 to 280 nm) increases with the increase in implantation dose from 2⋅1017 to 1.2⋅1019 ion/cm2 while aluminum implantation (from 0.42 to 2.1 μm) is in progress. It has been shown that the implantation of aluminum and copper ions into VT6 alloy leads to a considerable increase in its microhardness and wearability. Based on the research results, a conclusion on the positive effect of a structural-phase state of ion-doped titanium layers on their mechanical and tribological properties of VT6 titanium alloy has been drawn.


2020 ◽  
pp. 371-375
Author(s):  
V.A. Kukareko ◽  
M.A. Belotserkovsky ◽  
A.N. Grigorchik ◽  
E.V. Astrashab

Comparative study of the structural-phase state and tribotechnical properties of gas-thermal coatings from steels 08Mn2Si, 40Cr13, 95Cr18, as well as the pseudoalloys 08Mn2Si + bronze SiMn3-1, 08Mn2Si + AlSi12, 40Cr13 + bronze SiMn3-1, 95Cr18 + brass 63Cu, 95Cr18 + Al99.9 is carried out. It is shown that gas-thermal coating made of 95Cr18 steel has the highest wear resistance under conditions of dry friction due to the occurrence of intense martensitic γ → α transformation in its surface layers during friction. It is established that the pseudoalloys 08Mn2Si + bronze SiMn3-1 and 08Mn2Si + AlSi12 have higher wear resistance compared to the coating made of 08Mn2Si steel, which is associated with low content of iron oxides in the coatings of falsely alloys. For coatings from pseudoalloys 95Cr18 + brass 63Cu and 95Cr18 + Al99.9 lower wear resistance is characteristic in comparison with coating of 95Cr18 steel. The reduced wear resistance of pseudoalloys based on 95Cr18 steel is associated with their relatively low strength characteristics compared to steel coating of wire tool steel.


2020 ◽  
Vol 10 (3) ◽  
pp. 243-248
Author(s):  
Mikhail Zhidkov ◽  
Nikita Smirnov ◽  
Jiajun Chen ◽  
Sergey Kudryashov ◽  
Maksim Yapryntsev

Author(s):  
V. E. Ovcharenko ◽  
Yu. F. Ivanov ◽  
A. A. Mohovikov ◽  
K. V. Ivanov ◽  
O. P. Solonenko ◽  
...  

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