Potentially Toxic Elements in Ultramafic Soils: A Study from Metamorphic Ophiolites of the Voltri Massif (Western Alps, Italy)

Ultramafic soils are characterized by severe edaphic conditions induced by a low content of essential nutrients, an adverse Ca/Mg ratio, a low water-holding capacity, and high contents of geogenic potentially toxic elements (PTEs), in particular Cr, Ni, and Co. These metals commonly exceed the content limits set by environmental agencies and governments, representing serious environmental risks for ecosystems and human health. In alpine environments, ultramafic soils are characterized by modest thickness and poor horizon differentiation. Several studies on ultramafic soils have shown that their properties may be directly related to the characteristics of the parent rocks, but most of these studies deal with soil chemistry, metal availability, isotopic composition, and pedological characterization. The aim of this research is to investigate how much the geotectonic characteristics of ultramafic bedrocks, such as the degree of serpentinization, metamorphic imprint, and deformation, may affect the mineralogical and chemical variations of ultramafic soils, including the occurrence and potential mobility of the PTEs. Using a multiscale and multi-analytical approach, we fully characterize the properties and mineralogical composition of soil profiles with different ultramafic parent rocks, i.e., partially serpentinized peridotite, massive serpentinites, and foliated serpentinites, sampled within the Voltri Massif High Pressure–Low Temperature (HP–LT) metaophiolite (Western Alps, Italy). Our results, related to soils located at comparable latitude, altitude, landscape position, and pedological environment, outline that the degree of serpentinization, the metamorphic imprint, and the deformation history of the ultramafic parent rocks are key factors influencing soil evolution, mineralogy, and chemistry, as well as PTEs distribution and mobility. Moreover, this study shows that the high content of Cr, Ni, and Co in the studied ultramafic soils has to be considered of geogenic origin and highlights the need for new approaches and methods to obtain indications on the potential contamination of natural or anthropogenic soils.

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Accumulation of Potentially Toxic Elements in Viola L. (Sect. Melanium Ging.) from the Ultramafic and Non-ultramafic Soils of the Balkan Peninsula

Water Air & Soil Pollution ◽

10.1007/s11270-021-04992-w ◽

2021 ◽

Vol 232 (2) ◽

Author(s):

Gordana Tomović ◽

Sanja Đurović ◽

Uroš Buzurović ◽

Marjan Niketić ◽

Đorđije Milanović ◽

...

Keyword(s):

Toxic Elements ◽

Balkan Peninsula ◽

Potentially Toxic Elements ◽

Ultramafic Soils

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Applications of SEM/EDXA in cement clinker investigation

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100177489 ◽

1990 ◽

Vol 48 (4) ◽

pp. 870-871

Author(s):

Arezki Tagnit-Hamou ◽

Shondeep L. Sarkar

Keyword(s):

Mineralogical Composition ◽

Physicochemical Characteristics ◽

Cement Clinker ◽

Accurate Information ◽

Phase Identification ◽

History Of ◽

Bulk Chemical ◽

Resolution Imaging ◽

Proven Method ◽

Instantaneous Chemical

All the desired properties of cement primarily depend on the physicochemical characteristics of clinker from which the cement is produced. The mineralogical composition of the clinker forms the most important parameter influencing these properties.Optical microscopy provides reasonably accurate information pertaining to the thermal history of the clinker, while XRDA still remains the proven method of phase identification, and bulk chemical composition of the clinker can be readily obtained from XRFA. Nevertheless, all these microanalytical techniques are somewhat limited in their applications, and SEM/EDXA combination fills this gap uniquely by virtue of its high resolution imaging capability and possibility of instantaneous chemical analysis of individual phases.Inhomogeneities and impurities in the raw meal, influence of kiln conditions such as sintering and cooling rate being directly related to the microstructure can be effectively determined by SEM/EDXA. In addition, several physical characteristics of cement, such as rhcology, grindability and hydraulicity also depend on the clinker microstructure.

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Key objects of potentially toxic elements impact of hydrocarbons on the environment

Environmental Protection in Oil and Gas Complex ◽

10.33285/2411-7013-2020-6(297)-47-54 ◽

2020 ◽

pp. 47-54

Author(s):

S.P. Yakutseni ◽

Keyword(s):

Toxic Elements ◽

Potentially Toxic Elements

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Direct dating reveals the early history of opium poppy in western Europe

Scientific Reports ◽

10.1038/s41598-020-76924-3 ◽

2020 ◽

Vol 10 (1) ◽

Author(s):

Aurélie Salavert ◽

Antoine Zazzo ◽

Lucie Martin ◽

Ferran Antolín ◽

Caroline Gauthier ◽

...

Keyword(s):

Western Europe ◽

Western Alps ◽

Western Mediterranean ◽

Opium Poppy ◽

Radiocarbon Dates ◽

Macrobotanical Remains ◽

History Of ◽

Temperate Europe ◽

Radiocarbon Chronology ◽

Botanical Remains

AbstractThis paper aims to define the first chrono-cultural framework on the domestication and early diffusion of the opium poppy using small-sized botanical remains from archaeological sites, opening the way to directly date minute short-lived botanical samples. We produced the initial set of radiocarbon dates directly from the opium poppy remains of eleven Neolithic sites (5900–3500 cal BCE) in the central and western Mediterranean, northwestern temperate Europe, and the western Alps. When possible, we also dated the macrobotanical remains originating from the same sediment sample. In total, 22 samples were taken into account, including 12 dates directly obtained from opium poppy remains. The radiocarbon chronology ranges from 5622 to 4050 cal BCE. The results show that opium poppy is present from at least the middle of the sixth millennium in the Mediterranean, where it possibly grew naturally and was cultivated by pioneer Neolithic communities. Its dispersal outside of its native area was early, being found west of the Rhine in 5300–5200 cal BCE. It was introduced to the western Alps around 5000–4800 cal BCE, becoming widespread from the second half of the fifth millennium. This research evidences different rhythms in the introduction of opium poppy in western Europe.

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Current Status and Temporal Trend of Potentially Toxic Elements Pollution in Agricultural Soil in the Yangtze River Delta Region: A Meta-Analysis

International Journal of Environmental Research and Public Health ◽

10.3390/ijerph18031033 ◽

2021 ◽

Vol 18 (3) ◽

pp. 1033

Author(s):

Shufeng She ◽

Bifeng Hu ◽

Xianglin Zhang ◽

Shuai Shao ◽

Yefeng Jiang ◽

...

Keyword(s):

Yangtze River ◽

Agricultural Soil ◽

Toxic Elements ◽

Temporal Trend ◽

Meta Analysis ◽

Yangtze River Delta ◽

Potentially Toxic Elements ◽

River Delta ◽

The Yangtze River ◽

The Yangtze River Delta

Potentially toxic elements (PTEs) pollution in the agricultural soil of China, especially in developed regions such as the Yangtze River Delta (YRD) in eastern China, has received increasing attention. However, there are few studies on the long-term assessment of soil pollution by PTEs over large regions. Therefore, in this study, a meta-analysis was conducted to evaluate the current state and temporal trend of PTEs pollution in the agricultural land of the Yangtze River Delta. Based on a review of 118 studies published between 1993 and 2020, the average concentrations of Cd, Hg, As, Pb, Cr, Cu, Zn, and Ni were found to be 0.25 mg kg−1, 0.14 mg kg−1, 8.14 mg kg−1, 32.32 mg kg−1, 68.84 mg kg−1, 32.58 mg kg−1, 92.35 mg kg−1, and 29.30 mg kg−1, respectively. Among these elements, only Cd and Hg showed significant accumulation compared with their background values. The eastern Yangtze River Delta showed a relatively high ecological risk due to intensive industrial activities. The contents of Cd, Pb, and Zn in soil showed an increasing trend from 1993 to 2000 and then showed a decreasing trend. The results obtained from this study will provide guidance for the prevention and control of soil pollution in the Yangtze River Delta.

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