scholarly journals Empirical Models to Characterize the Structural and Physiochemical Properties of Vacuum Gas Oils with Different Saturate Contents

Resources ◽  
2021 ◽  
Vol 10 (7) ◽  
pp. 71
Author(s):  
Dicho S. Stratiev ◽  
Ivelina K. Shishkova ◽  
Rosen K. Dinkov ◽  
Ivan P. Petrov ◽  
Iliyan V. Kolev ◽  
...  

Inter-criteria analysis was employed in VGO samples having a saturate content between 0.8 and 93.1 wt.% to define the statistically significant relations between physicochemical properties, empirical structural models and vacuum gas oil compositional information. The use of a logistic function and employment of a non-linear least squares method along with the aromatic ring index allowed for our newly developed correlation to accurately predict the saturate content of VGOs. The empirical models developed in this study can be used not only for obtaining the valuable structural information necessary to predict the behavior of VGOs in the conversion processes but can also be utilized to detect incorrectly performed SARA analyses. This work confirms the possibility of predicting the contents of VGO compounds from physicochemical properties and empirical models.

Author(s):  
M I Farakhov ◽  
A G Laptev ◽  
T M Farakhov ◽  
A A Akhmitshin
Keyword(s):  

Author(s):  
Tareq A. Al-Attas ◽  
Rahima A. Lucky ◽  
Mohammed Mozahar Hossain
Keyword(s):  
Gas Oil ◽  

Author(s):  
Anton Alvarez-Majmutov ◽  
Sandeep Badoga ◽  
Jinwen Chen ◽  
Jacques Monnier ◽  
Yi Zhang
Keyword(s):  
Gas Oil ◽  

2013 ◽  
Vol 27 (6) ◽  
pp. 3306-3315 ◽  
Author(s):  
Jinwen Chen ◽  
Hena Farooqi ◽  
Craig Fairbridge

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4122
Author(s):  
Sarah A. Alkhalaf ◽  
Ahmed R. Ramadan ◽  
Christian Obuekwe ◽  
Ashraf M. El Nayal ◽  
Nasser Abotalib ◽  
...  

We followed a comparative approach to investigate how heavy vacuum gas oil (HVGO) affects the expression of genes involved in biosurfactants biosynthesis and the composition of the rhamnolipid congeners in Pseudomonas sp. AK6U. HVGO stimulated biosurfactants production as indicated by the lower surface tension (26 mN/m) and higher yield (7.8 g/L) compared to a glucose culture (49.7 mN/m, 0.305 g/L). Quantitative real-time PCR showed that the biosurfactants production genes rhlA and rhlB were strongly upregulated in the HVGO culture during the early and late exponential growth phases. To the contrary, the rhamnose biosynthesis genes algC, rmlA and rmlC were downregulated in the HVGO culture. Genes of the quorum sensing systems which regulate biosurfactants biosynthesis exhibited a hierarchical expression profile. The lasI gene was strongly upregulated (20-fold) in the HVGO culture during the early log phase, whereas both rhlI and pqsE were upregulated during the late log phase. Rhamnolipid congener analysis using high-performance liquid chromatography-mass spectrometry revealed a much higher proportion (up to 69%) of the high-molecularweight homologue Rha–Rha–C10–C10 in the HVGO culture. The results shed light on the temporal and carbon source-mediated shifts in rhamonlipids’ composition and regulation of biosynthesis which can be potentially exploited to produce different rhamnolipid formulations tailored for specific applications.


Energy ◽  
2021 ◽  
pp. 122912
Author(s):  
Shuai Zhang ◽  
Qingyu Lei ◽  
Le Wu ◽  
Yuqi Wang ◽  
Lan Zheng ◽  
...  

2018 ◽  
Vol 88 (9) ◽  
pp. 1963-1969
Author(s):  
N. N. Tomina ◽  
P. S. Solmanov ◽  
N. M. Maksimov ◽  
A. V. Moiseev ◽  
A. A. Pimerzin ◽  
...  
Keyword(s):  
Gas Oil ◽  

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