Petroleum, petrochemical and natural gas industries. Materials selection and corrosion control for oil and gas production systems

2010 ◽  

Materials ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 1849 ◽  
Author(s):  
Adriana Velloso Alves de Souza ◽  
Francisca Rosário ◽  
João Cajaiba

Calcium carbonate scale is formed during oil and gas production. Tube-blocking tests (TBTs) are used to define the minimum inhibitory concentration (MIC) in order to prevent scale adhesion in the petroleum production system equipment. However, non-adhered crystals may favor heterogeneous nucleation to other deposits such as calcium naphthenates, causing a more severe scale problem, increasing production losses and treatment costs. The objective of the present work was to develop a new dynamic test methodology to determine the MIC for CaCO3 using a sintered metal filter. Organophosphorus inhibitors were selected for comparison with the conventional dynamic tube-blocking system. The results demonstrated that the use of the filter allowed an MIC of the inhibitors to be obtained considering the precipitation prevention. The inhibitor concentration in the conventional tube-blocking system does not prevent precipitation, acting only on adhesion and crystal growth on the capillary wall. Tests to evaluate the potential of calcium naphthenates formation in a naphthenate flow rig dynamic system demonstrated the influence of heterogeneous nucleation from non-adhered carbonate crystals, potentially aggravating deposition problems in oil and gas production systems.



Author(s):  
Rene Nsanzineza ◽  
Jana Milford

Across the U.S., electricity production from coal-fired generation is declining while use of renewables and natural gas is increasing. This trend is expected to continue in the future. In the Rocky Mountain region, this shift is expected to reduce emissions from electricity production while increasing emissions from the production and processing of oil and gas, with significant implications for the level, location, and timing of the air pollution emissions that are associated with these activities. In turn, these emissions changes will affect air quality in the region, with impacts on ground-level ozone of particular concern. This study aims to evaluate the tradeoffs in emissions from both power plants and oil and gas basins resulting from contrasting scenarios for shifts in electricity and oil and gas production through the year 2030. The study also incorporates federal and state-level regulations for CH4, NOx, and VOC emissions sources. These regulations are expected to produce significant emissions reductions relative to baseline projections, especially in the oil and gas production sector. Annual emissions from electricity production are estimated to decrease in all scenarios, due to a combination of using more natural gas power plants, renewables, emissions regulations, and retiring old inefficient coal power plants. However, reductions are larger in fall, winter, and spring than in summer, when ozone pollution is of greatest concern. Emissions from oil and gas production are estimated to either increase or decrease depending on the location, scenario, and the number of sources affected by regulations. The net change in emissions thus depends on pollutant, location, and time of year.





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