scholarly journals Hybrid Solar Cell using Conjugated Chlorophyll from Pandanus Amaryllifolius as Photosensitizers

2019 ◽  
Vol 8 (4) ◽  
pp. 10142-10147

Solar energy is one in all few sources to renewable power and it is considerably critical in our each day lifestyles usage thus resulted to ensure the practicality and usefulness of the devices which regularly used to capture and manipulate solar energy. In this work, studies the effect of conjugated chlorophyll (iCHLO) on power conversion efficiency with relation of iCHLO where optical and electrical properties were investigated. These hybrid solar cells consist of combination of organic (Poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate) and iCHLO) and inorganic (Titanium Dioxide, TiO2) materials. These hybrid solar cells were fabricated bilayer of ITO/TiO2/PEDOT: PSS/iCHLO/Al. Chlorophyll compound (CHLO) was extracted from the Pandanus amaryllifolius leaves. CHLO undergoes conjugate process by oxidation polymerization using Ferric Chloride (FeCl3) as catalyst. Different percentage of FeCl3 was varied by 5%, 10% and 15% of CHLO molecular weight. Result shows that UV-Vis absorption spectra of CHLO was absorbed in the range of 400 nm – 600 nm (CHLO-PA) and 240 nm - 360 nm (iCHLO-PA). The highest power conversion efficiency (PCE) was obtained at 1.33% and electrical conductivity is 0.135 Scm1 for ITO/TiO2/PEDOT: PSS/iCHLO-PA 10% hybrid solar cell.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
S. Wageh ◽  
Mahfoudh Raïssi ◽  
Thomas Berthelot ◽  
Matthieu Laurent ◽  
Didier Rousseau ◽  
...  

AbstractPoly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) mixed with single-wall nanotubes (SWNTs) (10:1) and doped with (0.1 M) perchloric acid (HClO4) in a solution-processed film, working as an excellent thin transparent conducting film (TCF) in organic solar cells, was investigated. This new electrode structure can be an outstanding substitute for conventional indium tin oxide (ITO) for applications in flexible solar cells due to the potential of attaining high transparency with enhanced conductivity, good flexibility, and good durability via a low-cost process over a large area. In addition, solution-processed vanadium oxide (VOx) doped with a small amount of PEDOT-PSS(PH1000) can be applied as a hole transport layer (HTL) for achieving high efficiency and stability. From these viewpoints, we investigate the benefit of using printed SWNTs-PEDOT-PSS doped with HClO4 as a transparent conducting electrode in a flexible organic solar cell. Additionally, we applied a VOx-PEDOT-PSS thin film as a hole transporting layer and a blend of PTB7 (polythieno[3,4-b] thiophene/benzodithiophene): PC71BM (phenyl-C71-butyric acid methyl ester) as an active layer in devices. Zinc oxide (ZnO) nanoparticles were applied as an electron transport layer and Ag was used as the top electrode. The proposed solar cell structure showed an enhancement in short-circuit current, power conversion efficiency, and stability relative to a conventional cell based on ITO. This result suggests a great carrier injection throughout the interfacial layer, high conductivity and transparency, as well as firm adherence for the new electrode.


2021 ◽  
Vol 120 ◽  
pp. 111434
Author(s):  
Arif Allah Rakha ◽  
Monas Shahzad ◽  
Abdul Ghaffar ◽  
Khalid Javed ◽  
Aneel Pervez ◽  
...  

2015 ◽  
Vol 19 (01-03) ◽  
pp. 175-191 ◽  
Author(s):  
Ganesh D. Sharma ◽  
Galateia E. Zervaki ◽  
Kalliopi Ladomenou ◽  
Emmanuel N. Koukaras ◽  
Panagiotis P. Angaridis ◽  
...  

Two porphyrin dyads with the donor-π-acceptor molecular architecture, namely ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which consist of a zinc-metalated porphyrin unit and a free-base porphyrin unit covalently linked at their peripheries to a central triazine group, substituted either by a glycine in the former or a N-piperidine group in the latter, have been synthesized via consecutive amination substitution reactions of cyanuric chloride. The UV-vis absorption spectra and cyclic-voltammetry measurements of the two dyads, as well as theoretical calculations based on Density Functional Theory, suggest that they have suitable frontier orbital energy levels for use as sensitizers in dye-sensitized solar cells. Dye-sensitized solar cells based on ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ) have been fabricated, and they were found to exhibit power conversion efficiency values of 5.44 and 4.15%, respectively. Photovoltaic measurements (J–V curves) and incident photon to current conversion efficiency spectra of the two solar cells suggest that the higher power conversion efficiency value of the former solar cell is a result of its enhanced short circuit current, open circuit voltage, and fill factor values, as well as higher dye loading. This is ascribed to the existence of two carboxylic acid anchoring groups in ( ZnP )-[triazine-gly]-( H 2 PCOOH ), compared to one carboxylic acid group in ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which leads to a more effective binding onto the TiO 2 photoanode. Electrochemical impedance spectra show evidence that the ( ZnP )-[triazine-gly]-( H 2 PCOOH ) based solar cell exhibits a longer electron lifetime and more effective suppression of charge recombination reactions between the injected electrons and electrolyte.


2022 ◽  
Author(s):  
Ehsan Elahi ◽  
Ghulam Dastgeer ◽  
Abdul Subhan Siddiqui ◽  
Supriya A. Patil ◽  
Muhammad Waqas Iqbal ◽  
...  

With perovskite materials, rapid progress in power conversion efficiency (PCE) to reach 25% has gained a significant amount of attention from the solar cell industry.


RSC Advances ◽  
2019 ◽  
Vol 9 (36) ◽  
pp. 20670-20676 ◽  
Author(s):  
Ju Hwan Kang ◽  
Yu Jung Park ◽  
Myung Joo Cha ◽  
Yeonjin Yi ◽  
Aeran Song ◽  
...  

Non-conjugated polyelectrolytes are empolyed as interfacial layers at the electrodes of solar cells and transistor devices to improve the power conversion efficiency (PCE) and device performance.


RSC Advances ◽  
2018 ◽  
Vol 8 (61) ◽  
pp. 35162-35169
Author(s):  
Murugan Vinoth ◽  
Sundaramoorthy Arunmetha ◽  
Mathu Sridharpanday ◽  
Subramani Karthik ◽  
Venkatachalam Rajendran

In this study, the hybrid solar cells (HSCs) were fabricated with high-purity nano Si from nano SiO2 precursor extracted from natural minerals, that is, quartz sand.


2018 ◽  
Vol 42 (3) ◽  
pp. 1626-1633 ◽  
Author(s):  
M. L. Keshtov ◽  
S. A. Kuklin ◽  
A. R. Khokhlov ◽  
I. O. Konstantinov ◽  
N. V. Nekrasova ◽  
...  

The increase in the fluorine atoms in the copolymer improves the power conversion efficiency of the polymer solar cell.


RSC Advances ◽  
2015 ◽  
Vol 5 (1) ◽  
pp. 621-627 ◽  
Author(s):  
Viney Saini ◽  
Shawn E. Bourdo ◽  
Omar Abdulrazzaq ◽  
Enkeleda Dervishi ◽  
Ganesh K. Kannarpady ◽  
...  

There exists an optimum silicon substrate charge carrier concentration that can provide maximum power conversion efficiency for SWCNT–silicon hybrid solar cells.


Author(s):  
Chin-Yi Liu ◽  
Uwe R. Kortshagen

Hybrid solar cells based on blends of a conjugated polymer, poly-3(hexylthiophene) (P3HT), and silicon nanocrystals (Si NCs) have been developed and characterized. The properties of composite Si NCs/P3HT films which were spun from 1, 2-dichlorobenzene were studied. Under A.M. 1.5 direct illumination conditions (100mW/cm2), devices made with 50wt% 3–5nm Si NCs showed 1.33% power conversion efficiency (PCE) and had a 30% incident-photon-to-current conversion efficiency at 470 nm.


2015 ◽  
Vol 8 (1) ◽  
pp. 303-316 ◽  
Author(s):  
Abd. Rashid bin Mohd Yusoff ◽  
Dongcheon Kim ◽  
Hyeong Pil Kim ◽  
Fabio Kurt Shneider ◽  
Wilson Jose da Silva ◽  
...  

We propose that 1 + 1 + 1 triple-junction solar cells can provide an increased efficiency, as well as a higher open circuit voltage, compared to tandem solar cells.


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