Gold-catalyzed formation of pyrrolo- and indolo-oxazin-1-one derivatives: The key structure of some marine natural products
2015 ◽
Vol 11
◽
pp. 897-905
◽
Keyword(s):
Various N-propargylpyrrole and indolecarboxylic acids were efficiently converted into 3,4-dihydropyrrolo- and indolo-oxazin-1-one derivatives by a gold(III)-catalyzed cyclization reaction. Some of the products underwent TFA-catalyzed double bond isomerization and some did not. Cyclization reactions in the presence of alcohol catalyzed by Au(I) resulted in the formation of hemiacetals after cascade reactions.
2018 ◽
2016 ◽
Vol 23
(4)
◽
pp. 360-382
◽
2018 ◽
Vol 25
(20)
◽
pp. 2304-2328
◽