scholarly journals One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid

2018 ◽  
Vol 14 ◽  
pp. 849-855 ◽  
Author(s):  
Natalia Soldatova ◽  
Pavel Postnikov ◽  
Olga Kukurina ◽  
Viktor V Zhdankin ◽  
Akira Yoshimura ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Facile Synthesis ◽  
One Pot ◽  
Iodonium Salts ◽  
Wide Applicability ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts ◽  
Aryl Iodides

A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination–oxidation sequence.

One-Pot Synthesis and Conformational Analysis of 6-Membered Cyclic Iodonium Salts

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
Bronsted Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Iodonium Salts ◽  
Efficient Approach ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>

scholarly journals Facile One-Pot Synthesis of Diaryliodonium Salts from Arenes and Aryl Iodides with Oxone

ChemistryOpen ◽  
2016 ◽  
Vol 6 (1) ◽  
pp. 18-20 ◽  
Author(s):  
Natalia Soldatova ◽  
Pavel Postnikov ◽  
Olga Kukurina ◽  
Viktor V. Zhdankin ◽  
Akira Yoshimura ◽  
...  
Keyword(s):  
One Pot ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts ◽  
Aryl Iodides

One-Pot Syntheses of Diaryliodonium Salts from Aryl Iodides Using Peracetic Acid as Green Oxidant

2011 ◽  
Vol 64 (5) ◽  
pp. 529 ◽  
Author(s):  
Toshifumi Dohi ◽  
Nobutaka Yamaoka ◽  
Itsuki Itani ◽  
Yasuyuki Kita
Keyword(s):  
Peracetic Acid ◽  
Hypervalent Iodine ◽  
One Pot ◽  
Iodine Species ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts ◽  
Aryl Iodides ◽  
First Time

The rate-accelerating effects of fluoroalcohol solvents for generating trivalent hypervalent iodine species and the conversion into diaryliodonium(iii) salts have been used for the first time to realize a facile and clean one-pot synthesis of diaryliodonium(iii) salts 3 from aryl iodides 1 and suitable arene partners 2 with peracetic acid (PAA). The use of PAA as a green and practical oxidant is significantly effective in fluoroalcohol solvents. The scope and limitations of the methodology are elucidated by investigation of a wide variety of representative substrates.

scholarly journals One-Pot Synthesis and Conformational Analysis of 6-Membered Cyclic Iodonium Salts

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
Bronsted Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Iodonium Salts ◽  
Efficient Approach ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>

Silica Sulfuric Acid: An Efficient and Reusable Catalyst for the One-Pot Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones.

ChemInform ◽  
2003 ◽  
Vol 34 (27) ◽  
Author(s):  
Peyman Salehi ◽  
Minoo Dabiri ◽  
Mohammad Ali Zolfigol ◽  
Mohammad Ali Bodaghi Fard
Keyword(s):  
Sulfuric Acid ◽  
Reusable Catalyst ◽  
Silica Sulfuric Acid ◽  
One Pot ◽  
One Pot Synthesis ◽  
The One

Facile Synthesis of Fe2O3Nanocrystals without Fe(CO)5Precursor and One-Pot Synthesis of Highly Fluorescent Fe2O3-CdSe Nanocomposites

2009 ◽  
Vol 21 (8) ◽  
pp. 869-873 ◽  
Author(s):  
Chung Yen Ang ◽  
Louise Giam ◽  
Zheng Ming Chan ◽  
Alex W. H. Lin ◽  
Hongwei Gu ◽  
...  
Keyword(s):  
Facile Synthesis ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals A Facile Synthesis of Polysubstituted Pyrroles by One-Pot Three-Component Reaction

2012 ◽  
Vol 9 (4) ◽  
pp. 2239-2244 ◽  
Author(s):  
Hossein Anaraki-Ardakani ◽  
Maziar Noei ◽  
Mina Karbalaei-Harofteh ◽  
Shahab Zomorodbakhsh
Keyword(s):  
Room Temperature ◽  
Facile Synthesis ◽  
One Pot ◽  
Pyrrole Derivatives ◽  
Dialkyl Acetylenedicarboxylates ◽  
One Pot Synthesis ◽  
Three Component Reaction ◽  
High Yields ◽  
Neutral Conditions

A new and efficient one-pot synthesis of polysubstituted pyrrole derivatives by three-component reaction between dialkyl acetylenedicarboxylates, triphenylphosphine, 2-aminopyridin derivatives in the presence of arylglyoxals is described. The reactions were performed in dichloromethane at room temperature and neutral conditions and afforded high yields of products.

ChemInform Abstract: One-Pot Synthesis and Applications of N-Heteroaryl Iodonium Salts.

ChemInform ◽  
2014 ◽  
Vol 45 (34) ◽  
pp. no-no
Author(s):  
Marcin Bielawski ◽  
Joel Malmgren ◽  
Leticia M. Pardo ◽  
Ylva Wikmark ◽  
Berit Olofsson
Keyword(s):  
One Pot ◽  
Iodonium Salts ◽  
One Pot Synthesis
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