Study on Biomedical Prospects of Extractives of Pinus massoniana Lamb

2011 ◽  
Vol 55-57 ◽  
pp. 161-165
Author(s):  
Dang Quan Zhang ◽  
Qing Zhi Ma ◽  
Qi Mei Liu ◽  
Wan Xi Peng ◽  
Huai Yun Zhang ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Pinus Massoniana ◽  
Chemical Components ◽  
Caryophyllene Oxide ◽  
Alpha Pinene ◽  
Long Time ◽  
Industrial Materials ◽  
Analytical Result ◽  
Main Components

Pinus massoniana Lamb has been used to heal some specific diseases in the Chinese Folk for a long time. In order to explore the wide utilization in biomedicine and spicery, the chemical components of helium extractives from the fresh wood of Pinus massoniana Lamb was studied by TD-GC/MS. The results showed that the main components were 1,4-Methanoazulene, decahydro-4,8, 8-trimethyl-9-methylene- (29.98%), 1,4-Methanoazulen-9-ol, decahydro-1,5,5,8a-tetramethyl- (10.32%), 1R-.alpha.-Pinene (8.33%), 1,2,4-Methenoazulene, decahydro-1, 5,5,8a-tetramethyl- (4.72%), Borneol (2.99%), Thujopsene (2.80%), 1-Phenanthrenecarboxaldehyde, 7-ethenyl-1,2,3,4,4a,4b, 5,6,7,9,10,10a- dodecahydro-1,4a,7-trimethyl- (2.53%), Bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1R)- (2.52%), Caryophyllene oxide (2.40%), Tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl- (2.32%), 1,3-Benzodioxole, 5-(2-propenyl)- (2.274%), Acetic acid (2.07%), Eucalyptol (1.70%), Eucalyptol (1.70%), Benzaldehyde, 4-hydroxy- (1.61%), etc. The analytical result suggested that the helium extractives from the fresh wood of Pinus massoniana Lamb could be used as industrial materials of biomedicines and spicery.

Deep Analysis on Bioindustry Prospects of 40°С Volatiles of Cinnamomum camphora Branches

2011 ◽  
Vol 480-481 ◽  
pp. 266-271
Author(s):  
Qi Mei Liu ◽  
Dang Quan Zhang ◽  
Kuan Peng ◽  
Wan Xi Peng
Keyword(s):  
Acetic Acid ◽  
Ethyl Ester ◽  
Chemical Compounds ◽  
Chemical Components ◽  
Cinnamomum Camphora ◽  
Propenoic Acid ◽  
Long Time ◽  
Industrial Materials ◽  
Analytical Result ◽  
Main Components

Cinnamomum camphora has been used to heal some specific diseases in the Chinese Folk for a long time. In order to explore the wide utilization in biomedicine and spicery, the chemical components of helium volatiles from the fresh branches of C. camphora were studied by TD-GC/MS. The analytical result by TD-GC/MS showed that 50 peaks were obtained from the helium volatiles from the fresh branches of C. camphora and 46 chemical compounds representing 99.993% of the total areas were identified. The results showed that the main components were as: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)- (9.620%), 3-Cyclohexene-1- methanol, .alpha.,.alpha.4-trimethyl- (9.425%), 1,3-Benzodioxole, 5-(2-propenyl)- (8.223%), Bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3-pentenyl)-, (1S-exo)- (7.541%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (6.884%), Bicyclo[3.1.1] hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)- (6.050%), Bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1S)- (4.678%), 1,3-Benzodioxole, 5-(2-propenyl)- (4.500%), Naphthalene, 1,2,3,5,6,8a- hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- (4.491%), 3-Cyclohexen-1-ol, 4-methyl-1- (1-methylethyl)-, (R)- (4.254%), Copaene (4.120%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7- (4-methyl-3-pentenyl)-, (-)- (4.097%), Acetic acid, 1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester (3.574%), Borneol 3.334%), 3-(4-N,N-Dimethylaminophenyl)propenoic acid, 2- (diethoxyphosphinyl)-, ethyl ester (2.809%), Eucalyptol (2.096%), 1,6,10-Dodecatriene, 7,11- dimethyl-3-methylene-, (Z)- (1.885%), (-)-Isosativene (1.664%), 1,6,10-Dodecatrien-3-ol, 3,7,11-trimethyl- (1.407%), Cyclohexene, 1-methyl-4-(5-methyl-1-methylene-4-hexenyl)-, (S)- (1.218%), 1,4-Methanoazulene, decahydro-4,8,8-trimethyl-9-methylene-, [1S-(1.alpha.,3a.beta., 4.alpha.,8a.beta.)]- (1.174%), .alpha.-Caryophyllene (1.156%), etc. The analytical result suggested that the helium volatiles from the fresh branches of C. camphora can be applicable to biomedicine and spicery industrial materials.

80°С-Based TD-GC/MS Analysis of Chemical Components from Branches of Cinnamomum camphora

2011 ◽  
Vol 480-481 ◽  
pp. 466-471
Author(s):  
Qi Mei Liu ◽  
Wan Xi Peng
Keyword(s):  
Acetic Acid ◽  
Food Industry ◽  
Chemical Compounds ◽  
Chemical Components ◽  
Cinnamomum Camphora ◽  
Ms Analysis ◽  
Industrial Materials ◽  
Analytical Result ◽  
Main Components

The analytical result by 80°С-based TD-GC/MS showed that 65 peaks were obtained from the helium volatiles from the fresh branches of Cinnamomum camphora and 60 chemical compounds were identified. The results showed that the main components were as: 1,3-Benzodioxole, 5-(2-propenyl)- (12.629%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (10.302%), 3-Cyclohexene-1-methanol, .alpha.,.alpha.4-trimethyl- (9.084%), Bicyclo[2.2.1] heptan-2-one, 1,7,7-trimethyl-, (1R)- (7.406%), Nerolidol (6.695%), Bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3-pentenyl)-, (1S-exo)- (6.017%), Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (.+/-.)- (4.885%), Bicyclo[3.1.1]hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)- (4.680%), Naphthalene, 1,2,3,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- (4.139%), 3-Cyclohexen-1-ol, 4-methyl-1-(1-methylethyl)-, (R)- (3.538%), Copaene (2.749%), Bicyclo[2.2.1] heptan-2-ol, 1,7,7-trimethyl-, (1S-endo)- (2.643%), Acetic acid, 1,7,7-trimethyl-bicyclo [2.2.1]hept-2-yl ester (2.536%), Cyclohexane, bromo- (2.530%), 1,6,10-Dodecatriene, 7,11- dimethyl-3-methylene-, (E)- (1.725%), Naphthalene, 1,2,3,4,4a,5,6,8a-octahydro-7-methyl-4- methylene-1-(1-methylethyl)-, (1.alpha.,4a.beta.,8a.alpha.)- (1.265%), Bicyclo[4.4.0]dec-1-ene, 2-isopropyl-5-methyl-9-methylene- (1.174%), (-)-Isosativene (1.149%), 11-Tetradecen-1-ol acetate (1.118%), .alpha.-Cadinol (1.061%), etc. The analytical result suggested that the helium volatiles from the fresh branches of C. camphora could be used as industrial materials of biomedicines, spicery and food industry.

Determination of Bioactive Components of 60°С Volatiles from Cinnamomum camphora Branches by TD-GC/MS

2011 ◽  
Vol 230-232 ◽  
pp. 852-856
Author(s):  
Qing Li ◽  
Dang Quan Zhang ◽  
Qi Mei Liu ◽  
Kuan Peng
Keyword(s):  
Chemical Compounds ◽  
Chemical Components ◽  
Cinnamomum Camphora ◽  
Bioactive Components ◽  
Industrial Materials ◽  
Analytical Result ◽  
Main Components

The chemical components of helium volatiles from the fresh branches of Cinnamomum camphora were studied by TD-GC/MS. The analytical result by 60°С-based TD-GC/MS showed that 55 peaks were obtained from the helium volatiles from the fresh branches of Cinnamomum camphora and 53 chemical compounds were identified. The results showed that the main components were as: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)- (15.4328%), 1,3-Benzodioxole, 5-(2-propenyl)- (14.881%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (12.694%), p-menth-1-en-8-ol (9.832%), Bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3- pentenyl)-, (1S-exo)- (6.143%), 1,6,10-Dodecatrien-3-ol, 3,7,11-trimethyl- (5.365%), Bicyclo[3.1.1] hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)- (4.527%), Naphthalene, 1,2,3,5,6,8a- hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- (4.129%), 3-Cyclohexen-1-ol, 4-methyl-1- (1-methylethyl)- (2.965%), Borneol (2.627%), Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, (1S-endo)- (2.586%), Copaene (2.534%), 1,6,10-Dodecatriene, 7,11-dimethyl-3-methylene-, (Z)- (1.612%), (-)-Isosativene (1.121%), etc. The analytical result suggested that the helium volatiles from the fresh branches of Cinnamomum camphora could be used as industrial materials of biomedicines and spicery.

Analysis on Function Components and Biohealth Function of Pinus massoniana Lamb Biomass

2011 ◽  
Vol 55-57 ◽  
pp. 157-160
Author(s):  
Zhong Feng Zhang ◽  
Ming Long Zhang ◽  
Feng Juan Wu ◽  
Wan Xi Peng
Keyword(s):  
Pinus Massoniana ◽  
Main Function ◽  
Caryophyllene Oxide ◽  
Alpha Pinene ◽  
Long Time

Pinus massoniana resources have been used as meidicine for a long time. Therefore, the 120°С volatiles of Pinus massoniana biomass were identified by TD-GC/MS. The main function components of Pinus massoniana Lamb biomass at 120°С were 1,4-methanoazulene, decahydro-4,8, 8-trimethyl-9-methylene-(36.04%), 1,4-methanoazulen-3-ol, decahydro-1,5,5,8a-tetramethyl-(13.95%), .alpha.-pinene(9.36%), 1,2,4-methenoazulene,decahydro-1,5,5,8a-tetramethyl-(5.95%), tricyclo[5.4.0.0(2,8)]undec-9-ene, 52,6,6,9-tetramethyl-(3.74%), caryophyllene oxide(2.9%), tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl-(2.87%), bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1r)- (2.82%), p-menth-1-en-8-ol(1.92%), 1,3-benzodioxole, 5-(2-propenyl)- (1.4%), (+)-longicamphenylone(1.39%), eucalyptol(1.21%), etc. It showed that the volatiles of Pinus massoniana Lamb biomass at 120°С had some biohealth function.

Assessment on Environmental Friendly Characteristics of Pinus Biomass for Building Materials

2011 ◽  
Vol 55-57 ◽  
pp. 166-169
Author(s):  
Xu Zhang ◽  
Ri Qing Zhang
Keyword(s):  
Acetic Acid ◽  
Building Materials ◽  
Pinus Massoniana ◽  
Caryophyllene Oxide ◽  
Alpha Pinene ◽  
Environmental Friendly

In order to evaluate environmental friendly characteristics, the volatiles of Pinus massoniana biomass were adsorbed and determined by TD-GC-MS. And the main constituents of volatiles at 190°С were 1,4-methanoazulene, decahydro-4,8, 8-trimethyl-9-methylene-(30.62%), 1,4-methanoazulen-9-ol, decahydro-1,5,5,8a-tetramethyl-(10.46%), 1r-.alpha.-pinene(7.44%), 1,6,10-dodecatriene, 7,11-dimethyl-3-methylene-, (e)- (4.88%), tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl-(4.31%), bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1r)- (3.23%), borneol (3.08%), 1,3-benzodioxole, 5-(2-propenyl)- (2.85%), caryophyllene oxide(2.70%), 1-phenanthrene -carboxaldehyde, 7-ethenyl-1,2,3,4,4a,4b,5,6,7,9,10,10a-dodecahydro-1,4a,7- trimethyl- (2.30%), acetic acid(2.22%), etc. So the Pinus biomass was safe at 190°С carbonization.

Determination of Bioactive Components of Waste Leaves from Chinese Hackberry by GC/MS

2011 ◽  
Vol 230-232 ◽  
pp. 930-934
Author(s):  
Gong Xiu He ◽  
Dang Quan Zhang ◽  
Qi Mei Liu ◽  
Kuan Peng
Keyword(s):  
Water Stress ◽  
Value Added ◽  
Chemical Components ◽  
Bioactive Components ◽  
Freeze Dried ◽  
History Of ◽  
Celtis Sinensis ◽  
Analytical Result ◽  
Main Components

Chinese Hackberry (Celtis sinensis) tree has high adaptability to environment and tolerance to water stress, and a long history of utilization and plantation in many countries. However, researches on Chinese Hackberry were mostly focused on the biomass analyses and utilizations of its wood, and lacked those to analyze the chemical components of extractives of Chinese Hackberry leaves, which was very important to recover and utilize the polluting waste Chinese Hackberry leaves. Therefore, the chemical components of benzene/ethanol extractives of Chinese Hackberry leaves were analyzed by method of GC/MS in order to identify top value-added bioactive components from waste leaves of Chinese Hackberry tree. The analytical result showed that the main components of benzene/ethanol extractives of freeze-dried Chinese Hackberry leaves by GC/MS analysis were identified 10 components (106 peaks) as: Sesquirosefuran (48.57%), Thiophene, 2-ethyltetrahydro- (20.01 %), Hexatriacontane (8.67%), Octadecane (8.60%), 1-Eicosanol Pregn-4-en-3-one, 20-hydroxy-, (20R)- (4.52%), 1-Amino-2-(hydroxymethyl)anthraquinone (3.63%), 1,3-Diphenyl-(4H)1,2,4-triazoline- (1.92%), Tricyclo[4.3.1.13,8]undecane-1-carboxylic acid (1.69%), Eucalyptol (1.60%), etc. As the first report here, our result by GC/MS showed that the benzene-methanol extractive of freeze-dried Chinese Hackberry leaves can be developed into top value-added materials of spicery, biomedicines, and biofuel.

Study on Biomedical Prospects of Benzene-Alcohol Extractives of Bamboo Leaves

2011 ◽  
Vol 467-469 ◽  
pp. 1706-1710 ◽  
Author(s):  
Zhong Feng Zhang ◽  
Xian Yan Zhou ◽  
Qing Zhi Ma
Keyword(s):  
Vitamin E ◽  
Decanoic Acid ◽  
Chemical Components ◽  
Phenylpropionic Acid ◽  
Bamboo Leaves ◽  
Long Time ◽  
Main Components

Bamboo leaves has been used to heal some diseases in the Chinese Folk for a long time. In order to explore the wide biomedicine utilization, the chemical components of benzene-alcohol extractives from the fresh bamboo leaves was studied by Py-GC/MS. The results indicated that the main components were decanoic acid, 1,2,3-propanetriyl ester(5.6%), 9-octadecyne(3.21%), tricosane (2.88%), .gamma.-sitosterol(2.81%), phenylpropionic acid,.alpha.-amin o-2-fluoro-4-hydroxy-5- methoxy-(2.76%), stigmastan-3,5-diene(2.69%), 4h-benzo[f]pyrrolo[1,2-a][1,4]diaz epine, 4-(2-phenyl -propyl)-5,6- dihydro-(2.67%), vitamin e(2.51%), nonacosane(2.25%), tetratetracontane (2.25%), .beta.-tocopherol(2.04%), etc. So the benzene-alcohol extractives of bamboo leaves could be used as biomedicines.

Analysis of Biomedical Prospect of Leaves from Liriodendron Chinense (Hemsl.) Sarg by GC/MS

2011 ◽  
Vol 480-481 ◽  
pp. 1341-1345 ◽  
Author(s):  
Dang Quan Zhang ◽  
Huai Yun Zhang ◽  
Lin Lin Guo ◽  
Kuan Peng
Keyword(s):  
Methyl Formate ◽  
Value Added ◽  
Chemical Components ◽  
Butanoic Acid ◽  
Freeze Dried ◽  
Liriodendron Chinense ◽  
History Of ◽  
Analytical Result ◽  
Main Components ◽  
Tulip Tree

Liriodendron chinense (Hemsl.) Sarg (Chinese tulip tree) has a long history of utilization and plantation, but the chemical components of benzene/ethanol extractives of Liriodendron chinense (Hemsl.) Sarg leaves were unrevealed. The analytical result by method of GC/MS showed that the chemical components of benzene/ethanol extractives of freeze-dried Liriodendron chinense were identified as 55 constituent, and the main components are as: 2-Propenenitrile, 2-chloro- (13.75%), 1-Mercapto-2-heptadecanon (13.10 %), 1-Mercapto-2-heptadecanon (12.77%), Ethanol, 2-butoxy- (12.03%), 1-Docosanol (10.74%), Guanidine, (4-aminobutyl)- (5.05%), 5,10-Pentadecadiyn-1-ol, acetate (4.82%), 1,2,4-Butanetriol (3.13%), Thiophene, 2-ethyltetrahydro- (2.09%), 1-Eicosanol (2.00%), 1-Butanol, 3-methyl-, formate (1.60%), Butanoic acid (1.60%), .alpha.-D-Xylofuranoside, methyl 3,5-di-O-methyl- (1.30%), Phenol, 2,6-dimethoxy-4-(2-propenyl)- (1.29%),5.alpha.-Pregnane-12,20-dione (1.12%), Cyclopentanol (0.82%), etc. As the first report here, our result by GC/MS showed that the benzene-methanol extractive of freeze-dried leaves from Liriodendron chinense (Hemsl.) Sarg can be developed into top value-added materials of medicines and spicery.

Analysis on Pyrolysis Products of Phyllostachys heterocycla in Heat Charring

2011 ◽  
Vol 704-705 ◽  
pp. 592-595
Author(s):  
Zhong Feng Zhang ◽  
Xian Yan Zhou ◽  
Qing Zhi Ma
Keyword(s):  
Acetic Acid ◽  
Formic Acid ◽  
Dimethyl Ether ◽  
Carbon Disulfide ◽  
Added Value ◽  
Chemical Components ◽  
Pyrolysis Products ◽  
Propenoic Acid ◽  
Phyllostachys Heterocycla ◽  
Main Components

Phyllostachys heterocyclabegins to be used for black bamboo with high added value. However, the pyrolysis products were severely wasted. Therefore, the chemical components fromPhyllostachys heterocyclawere identified by TD-GC/MS after concentration. The main constituents of 150°С volatiles were acetic acid (46.75%), carbon disulfide (4.90%), 2-furanmethanol (4.10%), benzofuran, 2,3-dihydro-(3.63%), formic acid (3.27%), 2-propanone, 1-hydroxy-(2.80%), 2-propenoic acid, 2-hydroxyethyl ester (2.64%), dimethyl ether (2.15%), .beta.-pinene (1.84%), camphor (1.71%), etc. The main constituents of 180°С volatiles were acetic acid (20.66%), benzofuran, 2,3-dihydro-(14.49%), furfural (8.86%), formic acid (8.37%), 2-furanmethanol (4.17%), 4h-pyran-4-one, 2,3-dihydro-3,5-dihydroxy-6-methyl-(3.74%), 2(5h)-furanone (2.83%), 2-propanone, 1-hydroxy-(2.74%), etc. The main components of pyrolysis products of Phyllostachys heterocycla in heat charring could also be used as bioenergy materials, but were not only abundant and healthy to human.

Analysis of Top Value-Added Utilization of Waste Leaves from Rosewood Tree by GC/MS

2011 ◽  
Vol 480-481 ◽  
pp. 278-282
Author(s):  
Zhi Xiang He ◽  
Dang Quan Zhang ◽  
Qing Li
Keyword(s):  
Water Stress ◽  
Value Added ◽  
Chemical Components ◽  
Bioactive Components ◽  
Acid Methyl ◽  
Freeze Dried ◽  
History Of ◽  
Analytical Result ◽  
Main Components ◽  
Industrial Solvents

Rosewood tree has high adaptability to environment and tolerance to water stress, and a long history of utilization and plantation in many countries. However, researches on Rosewood were mostly focused on the biomass analyses and utilizations of its wood, and lacked those to analyze the chemical components of extractives of Rosewood leaves, which was very important to recover and utilize the polluting waste Rosewood leaves. Therefore, the chemical components of benzene/ethanol extractives of Rosewood leaves were analyzed by method of GC/MS in order to identify top value-added bioactive components from waste leaves of Rosewood tree. The analytical result showed that the main components of benzene/ethanol extractives of freeze-dried Rosewood leaves by GC/MS analysis were identified 16 constituent (16 peaks) as: Ethanol, 2-butoxy- (40.36%), 2-O-Methyl-D-mannopyranosa (18.22 %), Hydrazine, 1,1-dipropyl- (6.09%), 1-Docosanol (5.59%), 1-Eicosanol (5.28%), Oxirane, hexadecyl- (3.63%), trans-2,4,5-Trimethoxy-.beta.-methyl- (3.50%), Bicyclo[3.1.1]heptane, 2,6,6-trimethyl- (2.53%), 9,12,15-Octadecatrienoic acid, methyl- (2.43%), Tetratetracontane (2.31%), Hexadecane, 1-(ethenyloxy)- (2.27%), Cholan-24-oic acid, 7,12-bis(acetyloxy)-3-ethoxy-, methyl ester, (3.alpha.,5.beta.)- (2.10%), Hexatriacontane (2.02%), Phytol (1.76%), Octadecane, 1-chloro (1.08%), etc. As the first report here, our result by GC/MS showed that the benzene-methanol extractive of freeze-dried Rosewood leaves can be developed into top value-added materials of medicines, biofuel, and industrial solvents.

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