Synthesis and Crystal Structure of Phosphorus Vandium Heteropolyacid Sodium
Keyword(s):
phosphorus vandium heteropolyacid sodium, H78N12NaO116P2V30, is prepared by the hydrothermal method. Cubic, Fm-3m. a =b = c = 20.022(2) Å α=β=γ= 90. V=10680.0(17) Å3. Z=4. R1 =0.0388, wR2 =0.1200. T=298(2) K. The V atoms are linked with O atom bridge. The molecular structure is stabilized by the O-H...O and O-H...N intermolecular and intramolecular hydrogen-bond interaction.
2013 ◽
Vol 1012
◽
pp. 20-26
◽
2019 ◽
Vol 17
(38)
◽
pp. 8690-8694
◽
2015 ◽
Vol 136
◽
pp. 338-346
◽
2003 ◽
Vol 217
(9-2003)
◽
pp. 1085-1096
◽
2014 ◽
Vol 131
◽
pp. 72-81
◽
1993 ◽
pp. 2071-2072
◽
Keyword(s):
2007 ◽
Vol 63
(3)
◽
pp. o1407-o1408