Study on Nanocomposite Membranes with Enhanced Performance for Forward Osmosis

2014 ◽  
Vol 900 ◽  
pp. 191-196 ◽  
Author(s):  
Ning Ma ◽  
Cao Liu ◽  
Pei Jing Wang ◽  
Chu Yang Tang
Keyword(s):  
Thin Film ◽  
Water Permeability ◽  
Water Flux ◽  
Forward Osmosis ◽  
Nanoporous Materials ◽  
Nanocomposite Membranes ◽  
Membrane Performance ◽  
Thin Film Composite ◽  
Internal Concentration ◽  
Tfc Membrane

Nanocomposite membranes with enhanced performance were investigated for forward osmosis (FO) by incorporation of nanoporous materials. The incorporation of zeolite into both polysulfone (PSf) substrates and polyamide (PA) rejection layer of thin film composite (TFC) membrane (PSf-TFC) could effectively improve FO membrane performance. In the case of zeolite loading into PA layer, the resulted PSf based thin film nanocomposite (PSf-TFN) membrane showed improved but limited water permeability of the rejection layer, corresponding to ~1.76 times water flux higher than PSf-TFC membrane. Significantly, the polysulfone nanocomposite (PSfN) based TFC membrane (PSfN-TFC), which formed by embedding zeolite nanoparticles in PSf substrates, not only enhanced water permeability of the polyamide rejection layer but also reduced internal concentration polarization (ICP) effect, and thus improved FO membrane performance significantly, which corresponding to ~2.50 times water flux higher than PSf-TFC membrane.

scholarly journals Thin Film Composite Forward Osmosis Membrane with Single-Walled Carbon Nanotubes Interlayer for Alleviating Internal Concentration Polarization

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 260 ◽  
Author(s):  
Yuanyuan Tang ◽  
Shan Li ◽  
Jia Xu ◽  
Congjie Gao
Keyword(s):  
Thin Film ◽  
Concentration Polarization ◽  
Water Flux ◽  
Forward Osmosis ◽  
Feed Solution ◽  
Film Composite ◽  
Thin Film Composite ◽  
Internal Concentration ◽  
Tfc Membrane ◽  
Internal Concentration Polarization

This study reported a series of thin film composite (TFC) membranes with single-walled nanotubes (SWCNTs) interlayers for the forward osmosis (FO) application. Pure SWCNTs with ultrahigh length-to-diameter ratio and without any functional group were applied to form an interconnect network interlayer via strong π-π interactions. Compared to the TFC membrane without SWCNTs interlayer, our TFC membrane with optimal SWCNTs interlayer exhibited more than three times the water permeability (A) of 3.3 L m−2h−1bar−1 in RO mode with 500 mg L−1 NaCl as feed solution and nearly three-fold higher FO water flux of 62.8 L m−2 h−1 in FO mode with the deionized water as feed solution and 1 M NaCl as draw solution. Meanwhile, the TFC membrane with SWCNTs interlayer exhibited significantly reduced membrane structure parameters (S) to immensely mitigate the effect of internal concentration polarization (ICP) in support layer with micro-sized pores in favor of higher water flux. It showed that the pure SWCNTs interlayer could be an effective strategy to apply in FO membranes.

scholarly journals Preparation of thin-film composite membranes supported with electrospun nanofibers for desalination by forward osmosis

2020 ◽  
Vol 13 (2) ◽  
pp. 51-57
Author(s):  
Mustafa Al-Furaiji ◽  
Mohammed Kadhom ◽  
Khairi Kalash ◽  
Basma Waisi ◽  
Noor Albayati
Keyword(s):  
Thin Film ◽  
Water Flux ◽  
Applied Pressure ◽  
Forward Osmosis ◽  
Composite Membranes ◽  
Polymerization Reaction ◽  
Film Composite ◽  
Salt Rejection ◽  
Thin Film Composite ◽  
Tfc Membrane

Abstract. The forward osmosis (FO) process has been considered to be a viable option for water desalination in comparison to the traditional processes like reverse osmosis, regarding energy consumption and economical operation. In this work, a polyacrylonitrile (PAN) nanofiber support layer was prepared using the electrospinning process as a modern method. Then, an interfacial polymerization reaction between m-phenylenediamine (MPD) and trimesoyl chloride (TMC) was carried out to generate a polyamide selective thin-film composite (TFC) membrane on the support layer. The TFC membrane was tested in FO mode (feed solution facing the active layer) using the standard methodology and compared to a commercially available cellulose triacetate membrane (CTA). The synthesized membrane showed a high performance in terms of water flux (16 Lm −2 h−1) but traded the salt rejection (4 gm−2 h−1) compared with the commercial CTA membrane (water flux = 13 Lm−2 h−1 and salt rejection = 3 gm−2 h−1) at no applied pressure and room temperature. Scanning electron microscopy (SEM), contact angle, mechanical properties, porosity, and performance characterizations were conducted to examine the membrane.

scholarly journals Fabrication of a novel cyanoethyl cellulose substrate for thin-film composite forward osmosis membrane

2019 ◽  
Vol 1 (1) ◽  
pp. 18-32 ◽  
Author(s):  
Ke Zheng ◽  
Shaoqi Zhou
Keyword(s):  
Thin Film ◽  
Water Flux ◽  
Forward Osmosis ◽  
Feed Solution ◽  
Salt Flux ◽  
Sem Images ◽  
Film Composite ◽  
Thin Film Composite ◽  
Reverse Salt Flux ◽  
Cyanoethyl Cellulose

Abstract In this study, cyanoethyl cellulose (CEC) was used as a membrane material, and polyvinylpyrrolidone (PVP) was used as pore-forming agent to prepare the substrates for the thin-film composite (TFC) forward osmosis (FO) membrane for the first time. The experimental results demonstrate that the properties of the substrates were significantly improved after PVP was added. The scanning electron microscope (SEM) images show that a two-sublayer structure, a fringe-like top sublayer and macrovoids with sponge-like wall bottom sublayer, were formed after the addition of PVP. These improvements contributed to improved membrane performance during FO tests. Meanwhile, after adding PVP, the TFC membranes exhibited good water flux, and excellent specific reverse salt flux. For instance, the TFC-M2 exhibited 9.10/20.67 LMH water flux, 1.35/2.24 gMH reverse salt flux, and 0.15/0.11 g/L specific reverse salt flux in FO/pressure-retarded osmosis mode while using 1 M NaCl as the draw solution and deionized (DI) water as the feed solution.

IMPACTS OF HYDROPHILIC NANOFILLERS ON SEPARATION PERFORMANCE OF THIN FILM NANOCOMPOSITE REVERSE OSMOSIS MEMBRANE

2016 ◽  
Vol 78 (12) ◽  
Author(s):  
C. Y. Chong ◽  
G. S. Lai ◽  
W. J. Lau ◽  
N. Yusof ◽  
P. S. Goh ◽  
...  
Keyword(s):  
Thin Film ◽  
Water Permeability ◽  
Interfacial Polymerization ◽  
Pure Water ◽  
Water Flux ◽  
Water Desalination ◽  
Separation Performance ◽  
Salt Rejection ◽  
Tfc Membrane ◽  
Thin Film Nanocomposite

The membrane technology is still considered a costly method to produce potable water. In view of this, RO membrane with enhanced water permeability without trade-off in salt rejection is desirable as it could further reduce the cost for water desalination. In this study, thin film nanocomposite (TFN) membranes containing 0.05 or 0.10 w/v% hydrophilic nanofillers in polyamide layer were synthesized via interfacial polymerization of piperazine and trimesoyl chloride monomers. The resultant TFN membranes were characterized and compared with a control thin film composite (TFC) membrane. Results from the filtration experiments showed that TFN membranes exhibited higher water permeability, salt rejection and fouling resistance compared to that of the TFC membrane. Excessive amount of nanofillers incorporated in the membrane PA layer however negatively affected the cross-linking in the polymer matrix, thus deteriorating the membrane salt rejection. TFN membrane containing 0.05 w/v% of nanofillers showed better performances than the TFC membrane, recording a pure water flux of 11.2 L/m2∙h, and salt rejection of 95.4%, 97.3% and 97.5% against NaCl, Na2SO4 and MgSO4, respectively. 

scholarly journals Comparison of performance and biofouling resistance of thin-film composite forward osmosis membranes with substrate/active layer modified by graphene oxide

RSC Advances ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 6502-6509 ◽  
Author(s):  
Yuan Li ◽  
Yu Yang ◽  
Chen Li ◽  
Li-an Hou
Keyword(s):  
Thin Film ◽  
Graphene Oxide ◽  
Active Layer ◽  
Water Flux ◽  
Forward Osmosis ◽  
Film Composite ◽  
Thin Film Composite

The substrate modified by GO could greatly improve water flux, whereas the GO-functionalized active layer is favorable for biofouling mitigation.

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