Diffusion in Zr55Al10Ni10Cu25 Amorphous Alloy with a Wide Supercooled Liquid Region

1997 ◽  
Vol 143-147 ◽  
pp. 837-842 ◽  
Author(s):  
K. Nonaka ◽  
Y. Kimura ◽  
Kiyoshi Yamauchi ◽  
Hideo Nakajima ◽  
T. Zhang ◽  
...  
Keyword(s):  
Amorphous Alloy ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Liquid Region

PREPARATION AND CHARACTERIZATION OF AMORPHOUS ALLOY/POROUS SiCBi-CONTINUOUS STRUCTURE COMPOSITE

2009 ◽  
Vol 23 (06n07) ◽  
pp. 1294-1299 ◽  
Author(s):  
YONGLI CHEN ◽  
AIMIN WANG ◽  
HAIFENG ZHANG ◽  
ZHUANGQI HU
Keyword(s):  
Thermal Properties ◽  
Amorphous Alloy ◽  
Three Dimensional ◽  
Amorphous State ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Liquid Region ◽  
Continuous Structure ◽  
Porous Sic

A new kind of composite with a bi -continuous structure was produced by pressure infiltrating melt Zr 41.2 Ti 13.8 Cu 12.5 Ni 10 Be 22.5 into porous SiC which was made by powder metallurgy. Microstructure investigations of the composite show that the melt alloy was fully infiltrated into the voids of porous SiC and quenched into amorphous state. Both the amorphous alloy and the porous SiC exhibit a three-dimensional interconnected net structure. The study of thermal properties reveals that the addition of porous SiC reduces the width of supercooled liquid region of the composite. The bi -continuous composite presents 2% plastic strain and ultimate strength of 1250MPa.

scholarly journals Crystallization Behavior of Al70Fe12.5V12.5Nb5 Amorphous Alloy Formed by Mechanical Alloying

Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 383 ◽  
Author(s):  
Xuan Liu ◽  
Xingfu Wang ◽  
Yongli Si ◽  
Xiaokang Zhong ◽  
Fusheng Han
Keyword(s):  
Amorphous Alloy ◽  
Mechanical Alloying ◽  
Amorphous Alloys ◽  
Crystallization Behavior ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Glass Forming Ability ◽  
Liquid Region ◽  
Application Field ◽  
Glass Forming

In this study, the formation and crystallization of the Al70Fe12.5V12.5Nb5 amorphous alloys has been investigated. The addition of Nb enhances the supercooled liquid region and glass forming ability of the Al-Fe-V amorphous alloys. The Al70Fe12.5V12.5Nb5 amorphous alloy exhibits two distinct crystallization steps and a large supercooled liquid region at more than 100 K. Kissinger and Ozawa analyses showed that the two activation energies for crystallization (Ex) were estimated to be 366.3 ± 23.9 and 380.5 ± 23.9 kJ/mol. Large supercooled liquid regions are expected to gain an application field of Al-based amorphous alloys.

Preparation and Characterization of Fe36Co36B20Si4Nb4 Nanocrystalline/Amorphous Matrix Composite

2011 ◽  
Vol 391-392 ◽  
pp. 778-782
Author(s):  
Gang Li ◽  
Zhan Zhe Zhang
Keyword(s):  
Amorphous Alloy ◽  
Matrix Composite ◽  
Amorphous Matrix ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Liquid Region ◽  
Annealing Conditions ◽  
Nanocrystalline Particles ◽  
Nanocrystalline Phases

In this paper, we report a Fe-based nanocrystalline-amorphous matrix composite synthesised via partially crystallising an amorphous alloy. The microstructure of the composite was characterize. An amorphous rod of 2mm in diameter was initially prepared via injecting the melted Fe36Co36B20Si4Nb4 alloy into a copper mould in vacuum, which was confirmed to be completely amorphous by X-ray difraction（XRD）. Differential scanning calorimeteric（DSC）curve shown that the span △Tx of the supercooled liquid region and the reduced glass transition temperature（Tg/Tm）for the amorphous alloy are 40 K and 0.615, respectively. The composite composed of nanocrystalline particles homogeneously dispersed in an amorphous matrix was prepared by isothermal annealing. In this course, the amorphous Fe-based sample was held for different time at different temperature. The types of the nanocrystalline phases obtained in different annealing conditions were characterised by XRD and selected-area diffraction pattern（SAED）.The crystallization behavior of the amorphous Fe-based alloy was discussed.

Critical Cooling Rate of Y36Nd20Al24Co20 Bulk Amorphous Alloy

2014 ◽  
Vol 670-671 ◽  
pp. 86-89
Author(s):  
Shi Wen He
Keyword(s):  
Glass Transition ◽  
Amorphous Alloy ◽  
Cooling Rate ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Glass Forming Ability ◽  
Bulk Amorphous Alloy ◽  
Liquid Region ◽  
Critical Cooling Rate ◽  
Glass Forming

A new bulk amorphous alloy, Y36Nd20Al24Co20, with a diameter of 5 mm was successfully fabricated by the method of equiatomic substitution for the Y element in Y56Al24Co20amorphous alloy. The values of the supercooled liquid region ∆Tx(=Tx-Tg), the reduced glass transition temperature Trg(=Tg/Tl) and the parameter γ (=Tx/(Tg+Tl)) for Y36Nd20Al24Co20bulk amorphous alloy are 60K, 0.605 and 0.415, respectively. The critical cooling rate of the Y36Nd20Al24Co20bulk amorphous alloy was determined to be 40 K/s, providing an indication that this alloy has a high glass-forming ability.

Effect of Viscosity on the Microformability of Bulk Amorphous Alloy in Supercooled Liquid Region

2010 ◽  
Author(s):  
Ming Cheng ◽  
Shi-hong Zhang ◽  
Rui-xue Wang ◽  
F. Barlat ◽  
Y. H. Moon ◽  
...  
Keyword(s):  
Amorphous Alloy ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Bulk Amorphous Alloy ◽  
Liquid Region
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