Ag-Doped Sol-Gel Derived Novel Composite Materials for Dental Applications

2011 ◽  
Vol 493-494 ◽  
pp. 637-642 ◽  
Author(s):  
Xanthippi Chatzistavrou ◽  
Konstantinos M. Paraskevopoulos ◽  
Vehid Salih ◽  
Aldo Roberto Boccaccini ◽  
Toshihiro Kasuga

The aim of this work was to improve a newly developed family of glass-ceramic composite materials by incorporating silver ions in the ceramic structure, thus developing new Ag-doped materials with the ability of showing antibacterial activity for dental applications. Two different sol-gel methodologies were applied for the fabrication of colorless, homogenous and chemically durable materials which can slowly release silver ion for relatively long periods. Both methods led to the successful development of Ag-doped glass-ceramics with silver ions incorporated in the structure that can slowly release in buffer solution, during a period of 45 days. The potential, application of these materials involve the development of bioactive surfaces on dental substrates which can seal the marginal gap creating a bacterial free environment finally supporting the success of dental restorations.

2008 ◽  
Vol 396-398 ◽  
pp. 153-156 ◽  
Author(s):  
Xanthippi Chatzistavrou ◽  
E. Hatzistavrou ◽  
Nikolaos Kantiranis ◽  
Lambrini Papadopoulou ◽  
Eleana Kontonasaki ◽  
...  

The aim of this study was the fabrication using a sol-gel technique of a new glass-ceramic with potential use in dental applications. The characterization of the composition and microstructural properties of the produced material confirmed the similarity between the new sol-gel derived glass-ceramic and a commercial leucite based fluorapatite dental glass-ceramic. The produced material has potential application in dental restorations and it is expected to exhibit better control of composition, microstructure and properties due to the intrinsic advantages of the sol-gel preparation method.


Author(s):  
X. Chatzistavrou ◽  
E. Kontonasaki ◽  
K.M. Paraskevopoulos ◽  
P. Koidis ◽  
A.R. Boccaccini

Author(s):  
A S Chaynikova ◽  
N E Shchegoleva ◽  
S Y Modin ◽  
A A Akopian ◽  
D V Grashchenkov ◽  
...  

2010 ◽  
Vol 30 (5) ◽  
pp. 730-739 ◽  
Author(s):  
X. Chatzistavrou ◽  
D. Esteve ◽  
E. Hatzistavrou ◽  
E. Kontonasaki ◽  
K.M. Paraskevopoulos ◽  
...  

2012 ◽  
Vol 1417 ◽  
Author(s):  
Xanthippi Chatzistavrou ◽  
Eleana Kontonasaki ◽  
Athina Bakopoulou ◽  
Anna Theocharidou ◽  
Afroditi Sivropoulou ◽  
...  

ABSTRACTThe aim of this work was to develop a new Ag-doped bioactive material with antibacterial behavior, optimizing the properties of the new fabricated composite material in the system SiO2 58.6 -P2O5 7.2 -Al2O3 4.2 -CaO 24.9 -Na2O 2.1 -K2O 3 (wt%). Two systems with different concentrations in Ag2O (Ba with 2.1 and Bb with 4.2 wt%) were prepared by the sol-gel method and compared to the respective silver-free control composite (CONTROL). The microstructural characteristics of the developed compositions were characterized by different techniques as UV/VIS spectroscopy, X-ray diffraction analysis (XRD) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM-EDS). The antibacterial properties of the Ag-doped glass-ceramics were tested against the bacterial colony Staphylococcus aureus (S. aureus) which is very characteristic oral bacteria and the material-cell interaction was monitored in a primary culture of Human Gingival Fibroblasts (HGFs). Our study shows the successful incorporation of the silver ions in the ceramic structure and the preparation of new Ag-doped composite materials with cell-proliferation-inductive, as well as antibacterial properties indicating their potential application dental tissue restoration strategies.


Author(s):  
Ke Li ◽  
Jiancun Rao ◽  
Congqin Ning

AbstractThe novel dental ceramics can be fabricated at lower temperatures when sol-gel derived lithium disilicate glass ceramics (LDGC) was used as an additive for yttria stabilized tetragonal zirconia polycrystalline (Y-TZP) ceramics. The effect of LDGC on the sintering, mechanical, and translucent properties of Y-TZP ceramics was investigated in the present study. The results showed that the LDGC additive effectively improved the densification of Y-TZP at 1100 °C, which was much lower than the sintering temperature for pure Y-TZP. When sintered at 1100 °C, the Y-TZP with 1 wt% LDGC reached a relative density of 95.45%, and prossessed a flexural strength of 482.4 MPa and a fracture toughness of 5.94 MPa·m1/2. Moreover, its translucency was also improved. While, the addition of LDGC could result in an escape of yttrium atoms from the grain lattice of zirconia, which induced the tetragonal-monoclinic transformation of zirconia and abnormal growth of monoclinic grains. The escaped yttrium atoms diffused into the intergranular glass phase. The results indicated that the novel Y-TZP-LDGC ceramics has a great potential to be used for all-ceramic restorations.


ChemInform ◽  
1989 ◽  
Vol 20 (9) ◽  
Author(s):  
T. HAMASAKI ◽  
K. EGUCHI ◽  
Y. KOYANAGI ◽  
A. MATSUMOTO ◽  
T. UTSUNOMIYA ◽  
...  

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