Synthesis and Photoluminescence of Eu3+ Doped Sr2CeO4 via Carbonate Precursor

2005 ◽  
Vol 475-479 ◽  
pp. 1181-1184 ◽  
Author(s):  
Shi Kao Shi ◽  
Jun Min Li ◽  
Ji Zhou

Carbonate precursor of Eu3+ doped Sr2CeO4 is obtained from a mixed solution of strontium, cerium and europium nitrate using ammonium carbonate as precipitant. Calcining the carbonate precursor at different temperatures, the Eu3+ doped Sr2CeO4 phosphor is synthesized. The phase purity of the material is closely related with the calcination temperature, and the phosphor with high purity can be achieved after the precursor annealed at 1200°C. The photoluminescence performance for Eu3+ doped Sr2CeO4 depends on the concentration of Eu3+. The excitation and emission reveal efficient energy transfer from Ce4+ to Eu3+, making the emission light from blue-white to red-white, further to red as the Eu3+ concentration gradually changes from low concentration (1 mol%) to high concentration (10 mol%).

2020 ◽  
Vol 8 (26) ◽  
pp. 8953-8961 ◽  
Author(s):  
Bolong Zhang ◽  
Igor Lyskov ◽  
Lachlan J. Wilson ◽  
Randy P. Sabatini ◽  
Anjay Manian ◽  
...  

Samples containing both molecularly insulated and aggregated perylene diimides at high concentration (140 mM) in polymer matrix showed very high photoluminescence quantum yield (85%) as a result of efficient energy transfer.


Soft Matter ◽  
2021 ◽  
Author(s):  
Xinxian Ma ◽  
bo qiao ◽  
Jinlong Yue ◽  
JingJing Yu ◽  
yutao geng ◽  
...  

Based on a new designed acyl hydrazone gelator (G2), we developed an efficient energy transfer supramolecular organogel in glycol with two different hydrophobic fluorescent dyes rhodamine B (RhB) and acridine...


2004 ◽  
Vol 43 (15) ◽  
pp. 1976-1979 ◽  
Author(s):  
Freek J. M. Hoeben ◽  
Laura M. Herz ◽  
Clément Daniel ◽  
Pascal Jonkheijm ◽  
Albertus P. H. J. Schenning ◽  
...  

2012 ◽  
Vol 22 (21) ◽  
pp. 10816 ◽  
Author(s):  
Diana Savateeva ◽  
Dzmitry Melnikau ◽  
Vladimir Lesnyak ◽  
Nikolai Gaponik ◽  
Yury P. Rakovich

2008 ◽  
Vol 61 (8) ◽  
pp. 585 ◽  
Author(s):  
Simon Boyd ◽  
Kenneth P. Ghiggino ◽  
W. David McFadyen

The photochemistry of two anthracene-appended cobalt(iii) cyclam complexes is explored with a view to demonstrate a photoactivated ligand release process. The ligand exchange processes that occur in the complexes cis-[CoL(NO2)(ONO)]+ and trans-[CoL(NO2)(ONO)]+ in which L = 6-(anthracen-9-ylmethyl)-1,4,8,11-tetraazacyclotetradecane were monitored upon illumination of the anthracenyl chromophore at 360 nm in the presence of a large excess of thiocyanate. The trans-[CoL(NO2)(ONO)]+ complex underwent a ligand exchange reaction in the absence of light and displayed an enhancement of the reaction upon illumination. In contrast the cis-[CoL(NO2)(ONO)]+ complex was stable in the dark but displayed a significant quantum yield of photoactivated ligand release (Φ = 0.19). It is proposed that in cis-[CoL(NO2)(ONO)]+ the photoexcited anthracenyl chromophore undergoes efficient energy transfer to the cobalt(iii) cyclam before ligand exchange. Complexes based on the anthracenylcyclam–cobalt(iii) framework may be potentially useful candidates as photoactivated ligand release systems.


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