In-Situ Measurement of Artificial Nuclides in Seabed Sediments Based on Monte Carlo Simulations and an Underwater HPGe Detector

2019 ◽  
Vol 53 (3) ◽  
pp. 16-22
Author(s):  
Jinzhao Zhang ◽  
Hongzhi Li ◽  
Xianguo Tuo

AbstractIn-situ measurement of marine sediment radioactivity does not destroy the stratification of radionuclides in the sediment. We develop a novel seabed sediment radioactive measurement technique using a High Purity Germanium (HPGe) detector. The overall measurement system is designed, and the detector energy calibration is performed. The efficiency is calculated based on Monte Carlo simulations using the MCNP5 code. We compared the efficiency and energy resolution with the NaI(Tl) detection through experiments. NaI(Tl) detection is incapable of identifying the 137Cs artificial nuclides in seabed sediments due to the energy resolution limit. Hence, underwater HPGe detection is utilized due to its high energy resolution, which enables the detection of artificial nuclides 137Cs. The proposed method is of great significance in evaluating marine radioactive pollution.

2015 ◽  
Vol 112 (52) ◽  
pp. 15803-15808 ◽  
Author(s):  
Ofer Hirsch ◽  
Kristina O. Kvashnina ◽  
Li Luo ◽  
Martin J. Süess ◽  
Pieter Glatzel ◽  
...  

The lanthanum-based materials, due to their layered structure and f-electron configuration, are relevant for electrochemical application. Particularly, La2O2CO3 shows a prominent chemoresistive response to CO2. However, surprisingly less is known about its atomic and electronic structure and electrochemically significant sites and therefore, its structure–functions relationships have yet to be established. Here we determine the position of the different constituents within the unit cell of monoclinic La2O2CO3 and use this information to interpret in situ high-energy resolution fluorescence-detected (HERFD) X-ray absorption near-edge structure (XANES) and valence-to-core X-ray emission spectroscopy (vtc XES). Compared with La(OH)3 or previously known hexagonal La2O2CO3 structures, La in the monoclinic unit cell has a much lower number of neighboring oxygen atoms, which is manifested in the whiteline broadening in XANES spectra. Such a superior sensitivity to subtle changes is given by HERFD method, which is essential for in situ studying of the interaction with CO2. Here, we study La2O2CO3-based sensors in real operando conditions at 250 °C in the presence of oxygen and water vapors. We identify that the distribution of unoccupied La d-states and occupied O p- and La d-states changes during CO2 chemoresistive sensing of La2O2CO3. The correlation between these spectroscopic findings with electrical resistance measurements leads to a more comprehensive understanding of the selective adsorption at La site and may enable the design of new materials for CO2 electrochemical applications.


2020 ◽  
Author(s):  
Anders Lindanger ◽  
Martino Marisaldi ◽  
Nikolai Østgaard ◽  
Andrey Mezentsev ◽  
Torstein Neubert ◽  
...  

<p>Terrestrial Gamma-ray Flashes (TGFs) are sub milliseconds bursts of high energy photons associated with lightning flashes in thunderstorms. The Atmosphere-Space Interactions Monitor (ASIM), launched in April 2018, is the first space mission specifically designed to detect TGFs. We will mainly focus on data from the High Energy Detector (HED) which is sensitive to photons with energies from 300 keV to > 30 MeV, and include data from the Low Energy Detector (LED) sensitive in 50 keV to 370 keV energy range. Both HED and LED are part of the Modular X- and Gamma-ray Sensor (MXGS) of ASIM.<br><br>The energy spectrum of TGFs, together with Monte Carlo simulations, can provide information on the production altitude and beaming geometry of TGFs. Constraints have already been set on the production altitude and beaming geometry using other spacecraft and radio measurements. Some of these studies are based on cumulative spectra of a large number of TGFs (e.g. [1]), which smooth out individual variability. The spectral analysis of individual TGFs has been carried out up to now for Fermi TGFs only, showing spectral diversity [2]. Crucial key factors for individual TGF spectral analysis are a large number of counts, an energy range extended to several tens of MeV, a good energy calibration as well as knowledge and control of any instrumental effects affecting the measurements.</p><p>We strive to put stricter constraints on the production altitude and beaming geometry, by comparing Monte Carlo simulations to energy spectra from single ASIM TGFs. We will present the dataset and method, including the correction for instrumental effects, and preliminary results on individual TGFs.</p><p>Thanks to ASIM’s large effective area and low orbital altitude, single TGFs detected by ASIM have much more count statistics than observations from other spacecrafts capable of detecting TGFs. ASIM has detected over 550 TGFs up to date (January 2020), and ~115 have more than 100 counts. This allows for a large sample for individual spectral analysis.</p><p>References:</p><ol><li>Dwyer, J. R., and D. M. Smith (2005), A comparison between Monte Carlo simulations of runaway breakdown and terrestrial gamma-ray flash observations, Geophys. Res. Lett., 32, L22804, doi:10.1029/2005GL023848.</li> <li>Mailyan et al. (2016), The spectroscopy of individual terrestrial gamma-ray flashes: Constraining the source properties, J. Geophys. Res. Space Physics, 121, 11,346–11,363, doi:10.1002/2016JA022702.</li> </ol>


2009 ◽  
Vol 145 (3-4) ◽  
pp. 300-306 ◽  
Author(s):  
Jagdeep Singh ◽  
Moniek Tromp ◽  
Olga V. Safonova ◽  
Pieter Glatzel ◽  
Jeroen A. van Bokhoven

2017 ◽  
Vol 7 (1) ◽  
Author(s):  
Yi-Tao Cui ◽  
Yoshihisa Harada ◽  
Hideharu Niwa ◽  
Tatsuya Hatanaka ◽  
Naoki Nakamura ◽  
...  

ChemInform ◽  
2006 ◽  
Vol 37 (38) ◽  
Author(s):  
Jeroen A. van Bokhoven ◽  
Catherine Louis ◽  
Jeffrey T. Miller ◽  
Moniek Tromp ◽  
Olga V. Safonova ◽  
...  

2006 ◽  
Vol 118 (28) ◽  
pp. 4767-4770 ◽  
Author(s):  
Jeroen A. van Bokhoven ◽  
Catherine Louis ◽  
Jeffrey T. Miller ◽  
Moniek Tromp ◽  
Olga V. Safonova ◽  
...  

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