scholarly journals Direct Observation of Supercritical Fluids in Nanospace by Means of High-Pressure NMR Spectroscopy

2006 ◽  
Vol 16 (2) ◽  
pp. 131-136
Author(s):  
Yusuke HIEJIMA ◽  
Mitsuhiro KANAKUBO
Author(s):  
Greg Derk ◽  
Grant A. Risha ◽  
Eric Boyer ◽  
Richard A. Yetter

2021 ◽  
Vol 5 (4) ◽  
pp. 2000275
Author(s):  
Pawan Kumar ◽  
Azadeh Kermanshahi‐pour ◽  
Satinder Kaur Brar ◽  
Marianne Su‐Ling Brooks

2010 ◽  
Vol 364 (1-2) ◽  
pp. 149-156 ◽  
Author(s):  
Xiaofei Huang ◽  
Gregory R. Guillen ◽  
Eric M.V. Hoek

2003 ◽  
Vol 58 (12) ◽  
pp. 727-734 ◽  
Author(s):  
Hirokazu Kobayashi ◽  
Takahiro Ueda ◽  
Keisuke Miyakubo ◽  
Taro Eguchi

The pressure dependence of the 129Xe chemical shift tensor confined in the Tris(o-phenylenedioxy) cyclotriphosphazene (TPP) nanochannel was investigated by high-pressure 129Xe NMR spectroscopy. The observed 129Xe spectrum in the one-dimensional TPP nanochannel (0.45 nm in diameter) exhibits a powder pattern broadened by an axially symmetric chemical shift tensor. As the pressure increases from 0.02 to 7.0 MPa, a deshielding of 90 ppm is observed for the perpendicularcomponent of the chemical shift tensor δ⊥, whereas a deshielding of about 30 ppm is observed for the parallel one, δ‖. This suggests that the components of the chemical shift tensor, δ‖ and δ⊥, are mainly dominated by the Xe-wall and Xe-Xe interaction, respectively. Furthermore, the effect of helium, which is present along with xenon gas, on the 129Xe chemical shift is examined in detail. The average distance between the Xe atoms in the nanochannel is estimated to be 0.54 nm. This was found by using δ⊥ at the saturated pressure of xenon, and comparing the increment of the chemicalshift value in δ⊥ to that of a β -phenol/Xe compound.


2018 ◽  
Vol 115 (2) ◽  
pp. 341-352 ◽  
Author(s):  
Isaline Herrada ◽  
Philippe Barthe ◽  
Marisa Vanheusden ◽  
Karine DeGuillen ◽  
Léa Mammri ◽  
...  

Author(s):  
Ulrich Tallarek ◽  
Dagmar van Dusschoten ◽  
Henk Van As ◽  
Georges Guiochon ◽  
Ernst Bayer

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