Develop an integrating coagulation and RO systems to treat highly turbid water using synthesized coagulants

In the present study coagulation process was used as pretreatment for the RO membrane with turbid raw water collected from Bisalpur Dam, Rajasthan, India. To optimize coagulation performance, three kinds of coagulants, namely, Alum (commercially available), synthesized inorganic polymeric coagulant-medium basicity (IPC-M), and inorganic polymeric coagulant-ultra high basicity (IPC-UH) were examined for turbidity removal with varying operating parameters. It was observed that in the optimum pH range of 6–7, the IPC-UH resulted as the best performing coagulant with 0.99 mg/L equivalent Al2O3 dose revealing 2 NTU residual turbidity and residual aluminium of 0.001 mg/L. Moreover, Langelier saturation index and Ryznar stability index values were evaluated at optimum conditions of all the three coagulants proclaiming negligible scaling potential. Furthermore, the coagulant-treated water (100 L) was fed to the RO membrane, and the performance was noted in terms of flux, pressure, and TDS. It was observed that IPC-UH has the lowest reduction in permeate flux of 0.78 L/min/m2 compared to commercially available coagulant alum (0.90 L/min/m2). Also, the increased feed pressure was observed for all the coagulants treated water with the lowest value of 2.3 kg/cm2 for IPC-UH, which was 2.5 kg/cm2 for Alum (commercially available coagulant). Henceforth, integration of coagulation before the RO system resulted in effective pretreatment of turbid water with very minute scaling.

Hollow-Fiber RO Membranes Fabricated via Adsorption of Low-Charge Poly(vinyl alcohol) Copolymers

We report a new type of alkaline-stable hollow-fiber reverse osmosis (RO) membrane with an outside-in configuration that was established via adsorption of positively charged poly(vinyl alcohol) copolymers containing a small amount of quaternary ammonium moieties. Anionic sulfonated poly(arylene ether sulfone nitrile) hollow-fiber membranes were utilized as a substrate upon which the cationic copolymer layer was self-organized via electrostatic interaction. While the adsorption of the low-charge copolymer on the membrane support proceeded in a Layer-by-Layer (LbL) fashion, it was found that the adsorbed amount by one immersion step was enough to form a defect-free separation layer with a thickness of around 20 nm after cross-linking of vinyl alcohol units with glutaraldehyde. The resultant hollow-fiber membrane showed excellent desalination performances (NaCl rejection of 98.3% at 5 bar and 1500 mg/L), which is comparable with commercial low-pressure polyamide RO membranes, as well as good alkaline resistance. The separation performance could be restored by repeating the LbL treatment after alkaline degradation. Such features of LbL membranes may contribute to extending RO membrane lifetimes.

Enhancing chlorine resistance in polyamide membranes with surface & structure modification strategies

Higher efficient reverse osmosis (RO) membrane development is a significant issue due to the payoff among salt rejection and water flux and permissive chlorine attacking and fouling potential. Weak chlorine resistance is a distinctive challenge for composite polyamide thin-film reverse osmosis membranes. A commercial aromatic membrane was modified by grafting nitrogen-doped graphene oxide quantum dots (N-GOQDs) to enhance chlorine resistance, embedding two-dimensional MXene Ti3C2Tx, introducing synthetically reductive thioether units and oxidized graphitic carbon nitride (OGCN). In this work, salt rejection, chlorine resistance, and water flux increased compared to the pristine membrane. Comprehensive arrangement of desalination performance and chlorine resistance achieved by varying time and concentrations of prepared chemicals. For instance, improved chlorine resistance, after 12 hours of grafting time by N-GOQDs dopped membrane was 32.8%, after 6 hours of exposure time by MXene Ti3C2Tx membrane was 27.4%, after 1 hour of exposure time by thioether membrane was 28.1% and after 40 hours of doping time by OGCN membrane was 31.3%. N-GOQDs dopped membrane showed a good chlorine resistant property, but on the other hand, thioether nano units showed other properties more effectively, including water flux, salt rejection, and less reaction time.

Understanding the operational problems and fouling characterization of RO membrane used for brackish water treatment via membrane autopsy

An autopsy of spiral wound RO membrane operated in brackish water treatment was conducted to understand the origin and extent of foulants and fouling mechanisms. Structural and chemical characterization was determined by visual inspection and instrumental analysis such as SEM-EDS and XRD. It was observed that the membrane surfaces were completely covered with a gray/brown pollutant layer in all membrane sheets. SEM images proved accumulation of mineral pollutants on membrane surface. Also, the high levels of Al and Si which was attributed to aluminum silicates originating from feed water were determined on membrane surfaces. Additionally, the XRD analysis results showed that the foulant sample collected from membrane surfaces include halloysite, SiO2 and LiCl components. Fujiwara result proved that no damage was occurred on the membrane surface due to oxidation. Consequently, a fouling control strategy for RO-based brackish water treatment plants was also recommended to increase the membrane life.

A Separation and Desalination Process for Farmland Saline-Alkaline Water

Salination poses serious hazards to farmland soil. For the purpose of solving soil salination, desalination of water sources, and other problems faced by arid areas, a separation and desalination process for farmland saline-alkaline water is proposed; a separation and desalination device based on this process is also presented and tested. Results indicate that water associated with the pretreatment device satisfied the working conditions of the composite nanofiltration (NF)-reverse osmosis (RO) membrane system. The composite NF-RO membrane system produced a better filtering effect than either the NF membrane or the RO membrane. When used for filtering saline-alkaline water, the composite NF-RO membrane system achieved a desalination rate of 96.06%, a total hardness removal rate of 98.93%, and a Cl- removal rate of 99.32%, adhering to the standard for irrigation water quality. The flashing-condensation process realized a fresh water recovery rate greater than 70%. During brine evaporation using solar salt making processes, the primary compound of crystals precipitated was NaCl (with a relative content of 93%), suggesting that the precipitates have the potential values of industrial salts. These findings offer new technical references for solving the problem of farmland irrigation water faced by saline-alkaline areas worldwide.