Similarity Analysis of the Chemical Kinetic Mechanism on the Ignition Delay in Shock Tubes and Homogeneous Charge Compression Ignition (HCCI) Engines

2017 ◽  
Author(s):  
Weiwei Fan ◽  
Ming Jia ◽  
Yachao Chang ◽  
Yaopeng Li
Keyword(s):  
Ignition Delay ◽  
Homogeneous Charge Compression Ignition ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Similarity Analysis ◽  
Compression Ignition ◽  
Shock Tubes ◽  
Hcci Engines ◽  
Chemical Kinetic Mechanism ◽  
Homogeneous Charge

A Numerical Study on the Low Limit Auto-Ignition Temperature of Syngas and Modification of Chemical Kinetic Mechanism

2019 ◽  
Author(s):  
Seung Eon Jang ◽  
Jin Park ◽  
Sang Hyeon Han ◽  
Hong Jip Kim ◽  
Ki Sung Jung ◽  
...  
Keyword(s):  
Low Temperature ◽  
Temperature Region ◽  
Ignition Delay ◽  
Delay Time ◽  
Ignition Delay Time ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Numerical Results ◽  
Auto Ignition ◽  
Chemical Kinetic Mechanism

Abstract In this study, the auto ignition with low limit temperature of syngas has been numerically investigated using a 2-D numerical analysis. Previous study showed that auto ignition was observed at above 860 K in co-flow jet experiments using syngas and dry air. However, the auto ignition at this low temperature range could not be predicted with existing chemical mechanisms. Inconsistency of the auto ignition temperature between the experimental and numerical results is thought to be due to the inaccuracy of the chemical kinetic mechanism. The prediction of ignition delay time and sensitivity analysis for each chemical kinetic mechanism were performed to verify the reasons of the inconsistency between the experimental and numerical results. The results which were calculated using the various mechanisms showed significantly differences in the ignition delay time. In this study, we intend to analyze the reason of discrepancy to predict the auto ignition with low pressure and low temperature region of syngas and to improve the chemical kinetic mechanism. A sensitive analysis has been done to investigate the reaction steps which affected the ignition delay time significantly, and the reaction rate of the selected reaction step was modified. Through the modified chemical kinetic mechanism, we could identify the auto ignition in the low temperature region from the 2-D numerical results. Then CEMA (Chemical Explosive Mode Analysis) was used to validate the 2-D numerical analysis with modified chemical kinetic mechanism. From the validation, the calculated λexp, EI, and PI showed reasonable results, so we expect that the modified chemical kinetic mechanism can be used in various low temperature region.

Theoretical Investigation of Autoignition of Combustible Gas Mixtures in Rapid Compression Machines

2002 ◽  
Author(s):  
Shaoping Shi ◽  
Daniel Lee ◽  
Sandra McSurdy ◽  
Michael McMillian ◽  
Steven Richardson ◽  
...  
Keyword(s):  
Experimental Data ◽  
Theoretical Investigation ◽  
Ignition Delay ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Reaction Scheme ◽  
Independent Manner ◽  
Elementary Reactions ◽  
Chemical Kinetic Mechanism ◽  
Rapid Compression

In any theoretical investigation of ignition processes in natural gas reciprocating engines, physical and chemical mechanisms must be adequately modeled and validated in an independent manner. The Rapid Compression Machine (RCM) has been used in the past as a tool to validate both autoignition models as well as turbulent mixing effects. In this study, two experimental cases were examined. In the first experimental case, the experimental measurements of Lee and Hochgreb (1998a) were chosen to validate the simulation results. In their experiments, hydrogen/oxygen/argon mixtures were used as reactants. In the simulations, a reduced chemical kinetic mechanism consisting of 10 species and 19 elementary reactions coupled to a CFD software, Fluent 6, was used to simulate the autoignition. The ignition delay from the simulation agreed very well with that from the experimental data of Lee and Hochgreb, (1998b). In the second case, experimental data derived from an RCM with two opposed, pneumatically driven pistons (Brett et al., 2001) were used to study the autoignition of methane/oxygen/argon mixtures. The reduced chemical kinetic mechanism DRM22, derived from the GRI-Mech reaction scheme coupled to Fluent 6, was applied in the simulations. The DRM22 scheme included 22 species and 104 reactions. When methane/oxygen/argon mixture were simulated for the RCM, the ignition delay deviated about 15% from the experimental results. The simulation approaches as well as the validation results are discussed in detail in this paper. The paper also discusses an evaluation of reduced reaction models available in the literature for subsequent Fluent modeling.

scholarly journals Analysis of Homogeneous Charge Compression Ignition (HCCI) Engines for Cogeneration Applications

2005 ◽  
Vol 128 (1) ◽  
pp. 16-27 ◽  
Author(s):  
Salvador M. Aceves ◽  
Joel Martinez-Frias ◽  
Gordon M. Reistad
Keyword(s):  
Diesel Engines ◽  
High Efficiency ◽  
Homogeneous Charge Compression Ignition ◽  
Utilization Efficiency ◽  
Small Scale ◽  
Compression Ignition ◽  
Hcci Engines ◽  
Si Engines ◽  
Prime Movers ◽  
Homogeneous Charge

This paper presents an evaluation of the applicability of homogeneous charge compression ignition (HCCI) engines for small-scale cogeneration (<1MWe) in comparison to five previously analyzed prime movers. The five comparator prime movers include stoichiometric spark-ignited (SI) engines, lean burn SI engines, diesel engines, microturbines, and fuel cells. The investigated option, HCCI engines, is a relatively new type of engine that has some fundamental differences with respect to other prime movers. The prime movers are compared by calculating electric and heating efficiency, fuel consumption, nitrogen oxide (NOx) emissions, and capital and fuel costs. Two cases are analyzed. In case 1, the cogeneration facility requires combined power and heating. In case 2, the requirement is for power and chilling. The results show that HCCI engines closely approach the very high fuel utilization efficiency of diesel engines without the high emissions of NOx and the expensive diesel fuel. HCCI engines offer a new alternative for cogeneration that provides a combination of low cost, high efficiency, low emissions, and flexibility in operating temperatures that can be optimally tuned for cogeneration systems. HCCI is the most efficient engine technology that meets the strict 2007 CARB NOx standards for cogeneration engines, and merits more detailed analysis and experimental demonstration.

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