Fire Safety Evaluation of High-Pressure Ammonia Storage Systems

Ammonia combustion is a promising energy source as a carbon free fuel without greenhouse gas emissions. However, since the auto-ignition temperature is 651 degrees Celsius and the range of flammability limit is not wide compared to other fuels, fundamental studies on ammonia fires have rarely been conducted so far. Therefore, this study aims to numerically estimate fire spread characteristics when ammonia fuel in a high-pressure state leaks to the outside, especially focusing on the flammability limit according to oxygen concentration. Three kinds of reaction mechanism for numerical analysis were adopted to compare the flame structure, flammability limit, and combustion characteristics. Plank-mean absorption coefficients of nitrogen species were taken for the radiation model, in addition to the optically thin model. The effect of radiation heat loss could be identified from the maximum flame temperature trend at a low strain rate. It was confirmed that the pyrolysis of ammonia in the preheated zone results in hydrogen production, and the generated hydrogen contributes to heat release rate in the flame zone. It is found that the contribution of hydrogen would be an important role in the flammability limit of ammonia combustion. Finally, Karlovitz and Peclet numbers showed well the extinction behaviors of ammonia combustion as a result of LOC (Limit Oxygen Concentration) analysis as a function of global strain rate.

Numerical and experimental study on knocking combustion in turbocharged direct-injection engines for a wide range of operating conditions

A combined experimental and numerical study is conducted on knocking combustion in turbocharged direct-injection spark-ignition engines. The experimental study is based on parameter variations in the intake-manifold temperature and pressure, as well as the air-fuel equivalence ratio. The transition between knocking and non-knocking operating conditions is studied by conducting a spark timing sweep for each operating parameter. By correlating combustion and global knock quantities, the global knock trends of the mean cycles are identified. Further insight is gained by a detailed analysis based on single cycles. The extensive experimental data is then used as an input to support numerical investigations. Based on 0D knock modeling, the global knock trends are investigated for all operation points. Taking into consideration the influence of nitric oxide on auto-ignition significantly improves the knock model prediction. Additionally, the origin of the observed cyclic variability of knock is investigated. The crank angle at knock onset in 1000 consecutive single cycles is determined using a multi-cycle 0D knock simulation based on detailed single-cycle experimental data. The overall trend is captured well by the simulation, while fluctuations are underpredicted. As one potential reason for the remaining differences of the 0D model predictions local phenomena are investigated. Therefore, 3D CFD simulations of selected operating points are performed to explore local inhomogeneities in the mixture fraction and temperature. The previously developed generalized Knock Integral Method (gKIM), which considers the detailed kinetics and turbulence-chemistry interaction of an ignition progress variable, is improved and applied. The determined influence of spark timing on the mean crank angle at knock onset agrees well with experimental data. In addition, spatially resolved information on the expected position of auto-ignition is analyzed to investigate causes of knocking combustion.

Strategies to Form Homogeneous Mixture and Methods to Control Auto-Ignition of HCCI Engine

Homogeneous charge compression ignition (HCCI) engine has emerged as a promising combustion technology. Theoretically, an HCCI engine can reduce both NOx and soot emissions significantly down to almost zero levels. This is possible as a result of two fundamental processes that occur in the HCCI engine, i.e. the homogeneous mixture and its autoignition characteristics. Neither spark plug nor injector is used in the HCCI engine. The autoignition of the homogeneous mixture is solely influenced by its chemical reactions inside the combustion chamber. However, this is where the problems start to occur. At low loads or too lean mixtures, misfire may occur, thus increasing the HC and CO emissions. At high loads or too rich mixtures, soot emissions and knocking tendency may increase. Moreover, an undesirable pressure rise due to knocking will increase the combustion temperature and potentially increase the probability of NOx formation. Therefore, the operating range of HCCI engine is very limited only to part loads. Controlling its combustion phasing play an important role to extend the narrow operating range of the HCCI engine. Despite numerous review articles have been published, classification of the approaches to achieve HCCI combustion in diesel engines were rarely presented clearly. Therefore, this review article aims to provide a concise and comprehensive classification of HCCI combustion so that the role and position of each strategy found in the literature could be understood distinctively. In short, two important questions must be solved to have successful HCCI combustion; (1) how to form a homogeneous mixture? and (2) how to control its auto-ignition?