scholarly journals Solubility of Ru, Rh and Ir in Spinel and Olivine: can the Nugget Effect be Avoided?

2020 ◽  
Author(s):  
Irina Zhukova ◽  
Hugh O’Neill ◽  
Ian Campbell ◽  
Marco Fiorentini
Keyword(s):  
2021 ◽  
pp. 1-16
Author(s):  
Scott McKean ◽  
Simon Poirier ◽  
Henry Galvis-Portilla ◽  
Marco Venieri ◽  
Jeffrey A. Priest ◽  
...  

Summary The Duvernay Formation is an unconventional reservoir characterized by induced seismicity and fluid migration, with natural fractures likely contributing to both cases. An alpine outcrop of the Perdrix and Flume formations, correlative with the subsurface Duvernay and Waterways formations, was investigated to characterize natural fracture networks. A semiautomated image-segmentation and fracture analysis was applied to orthomosaics generated from a photogrammetric survey to assess small- and large-scale fracture intensity and rock mass heterogeneity. The study also included manual scanlines, fracture windows, and Schmidt hammer measurements. The Perdrix section transitions from brittle fractures to en echelon fractures and shear-damage zones. Multiple scales of fractures were observed, including unconfined, bedbound fractures, and fold-relatedbed-parallel partings (BPPs). Variograms indicate a significant nugget effect along with fracture anisotropy. Schmidt hammer results lack correlation with fracture intensity. The Flume pavements exhibit a regionally extensive perpendicular joint set, tectonically driven fracturing, and multiple fault-damage zones with subvertical fractures dominating. Similar to the Perdrix, variograms show a significant nugget effect, highlighting fracture anisotropy. The results from this study suggest that small-scale fractures are inherently stochastic and that fractures observed at core scale should not be extrapolated to represent large-scale fracture systems; instead, the effects of small-scale fractures are best represented using an effective continuum approach. In contrast, large-scale fractures are more predictable according to structural setting and should be characterized robustly using geological principles. This study is especially applicable for operators and regulators in the Duvernay and similar formations where unconventional reservoir units abut carbonate formations.


2021 ◽  
Vol 51 ◽  
Author(s):  
Diogo Neia Eberhardt ◽  
Robélio Leandro Marchão ◽  
Pedro Rodolfo Siqueira Vendrame ◽  
Marc Corbeels ◽  
Osvaldo Guedes Filho ◽  
...  

ABSTRACT Tropical Savannas cover an area of approximately 1.9 billion hectares around the word and are subject to regular fires every 1 to 4 years. This study aimed to evaluate the influence of burning windrow wood from Cerrado (Brazilian Savanna) deforestation on the spatial variability of soil chemical properties, in the field. The data were analysed by using geostatistical methods. The semivariograms for pH(H2O), pH(CaCl2), Ca, Mg and K were calculated according to spherical models, whereas the phosphorus showed a nugget effect. The cross semi-variograms showed correlations between pH(H2O) and pH(CaCl2) with other variables with spatial dependence (exchangeable Ca and Mg and available K). The spatial variability maps for the pH(H2O), pH(CaCl2), Ca, Mg and K concentrations also showed similar patterns of spatial variability, indicating that burning the vegetation after deforestation caused a well-defined spatial arrangement. Even after 20 years of use with agriculture, the spatial distribution of pH(H2O), pH(CaCl2), Ca, Mg and available K was affected by the wood windrow burning that took place during the initial deforestation.


2020 ◽  
Vol 8 (4) ◽  
pp. 1338-1357
Author(s):  
Yang Yu ◽  
Ning Zhang ◽  
Daniel W. Apley ◽  
Wenxin Jiang

1993 ◽  
Vol 172 (3) ◽  
pp. 249-256 ◽  
Author(s):  
J. THIOULOUSE ◽  
J. P. ROYET ◽  
H. PLOYE ◽  
F. HOULLIER

2013 ◽  
Vol 33 (4) ◽  
pp. 636-646 ◽  
Author(s):  
Cicero da S. Costa ◽  
Elvira M. R. Pedrosa ◽  
Mario M. Rolim ◽  
Hugo R. B. Santos ◽  
Aluízio T. Cordeiro Neto

Areas under vinasse application have been associated to favorable physical conditions for root development, aeration, infiltration and water movement in soil profile. This study aimed to evaluate changes on physical attributes of soil under sugarcane straw after vinasse application in two sugarcane growing areas (Area 1 and Area 2) under mechanized management in the state of Paraíba, Brazil. In each area, the samples were collected in the 0-0.20, 0.20-0.40 and 0.40-0.60m layers of the soil, in 36 points, distributed in a 10×10m mesh, one day before and 40 days after vinasse application. The data were submitted to multivariate analysis with repeated measures and geostatistics. The vinasse application decreased soil density and increased total porosity in both Areas and increased organic matter in Area 2. In Area 1 occurred pure nugget effect for the fractions of sand, silt and clay, independent of soil layer. In Area 2, this effect was verified mostly at superficial layers, except for the fraction of clay that presented a moderate degree of spatial dependence.


Mathematics ◽  
2021 ◽  
Vol 9 (19) ◽  
pp. 2466
Author(s):  
Francisco Gerardo Benavides-Bravo ◽  
Roberto Soto-Villalobos ◽  
José Roberto Cantú-González ◽  
Mario A. Aguirre-López ◽  
Ángela Gabriela Benavides-Ríos

Variogram models are a valuable tool used to analyze the variability of a time series; such variability usually entails a spherical or exponential behavior, and so, models based on such functions are commonly used to fit and explain a time series. Variograms have a quasi-periodic structure for rainfall cases, and some extra steps are required to analyze their entire behavior. In this work, we detailed a procedure for a complete analysis of rainfall time series, from the construction of the experimental variogram to curve fitting with well-known spherical and exponential models, and finally proposed a novel model: quadratic–exponential. Our model was developed based on the analysis of 6 out of 30 rainfall stations from our case study: the Río Bravo–San Juan basin, and was constructed from the exponential model while introducing a quadratic behavior near to the origin and taking into account the fact that the maximal variability of the process is known. Considering a sample with diverse Hurst exponents, the stations were selected. The results obtained show robustness in our proposed model, reaching a good fit with and without the nugget effect for different Hurst exponents. This contrasts to previous models, which show good outcomes only without the nugget effect.


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