scholarly journals Anthropogenic and natural controls on atmospheric <i>δ</i><sup>13</sup>C-CO<sub>2</sub> variations in the Yangtze River Delta: Insights from a carbon isotope modeling framework

2020 ◽  
Author(s):  
Cheng Hu ◽  
Jiaping Xu ◽  
Cheng Liu ◽  
Yan Chen ◽  
Dong Yang ◽  
...  

Abstract. The atmospheric CO2 mixing ratio and its δ13C-CO2 composition contain important CO2 sink and source information spanning from ecosystem to global scales. The observation and simulation for both CO2 and its carbon isotope ratio (δ13C-CO2) can be used to constrain regional emissions and better understand the anthropogenic and natural mechanisms that control δ13C-CO2 variations. Such work remains rare for urban environments, especially megacities. Here, we used near-continuous CO2 and δ13C-CO2 measurements, from September 2013 to August 2015, and inverse modeling to constrain the CO2 budget and investigate the main factors that dominated δ13C-CO2 variations for the Yangtze River Delta (YRD) region, one of the largest anthropogenic CO2 hotspots and densely populated regions in China. We used the WRF-STILT model framework with category-specified EDGAR v432 CO2 inventories to simulate hourly CO2 mixing ratios and δ13C-CO2, evaluated these simulations with observations, and constrained the anthropogenic CO2 emission categories. Our study shows that: (1) Top-down and bottom-up estimates of anthropogenic CO2 emissions agreed well (bias 

2021 ◽  
Vol 21 (13) ◽  
pp. 10015-10037
Author(s):  
Cheng Hu ◽  
Jiaping Xu ◽  
Cheng Liu ◽  
Yan Chen ◽  
Dong Yang ◽  
...  

Abstract. The atmospheric carbon dioxide (CO2) mixing ratio and its carbon isotope (δ13C-CO2) composition contain important CO2 sink and source information spanning from ecosystem to global scales. The observation and simulation for both CO2 and δ13C-CO2 can be used to constrain regional emissions and better understand the anthropogenic and natural mechanisms that control δ13C-CO2 variations. Such work remains rare for urban environments, especially megacities. Here, we used near-continuous CO2 and δ13C-CO2 measurements, from September 2013 to August 2015, and inverse modeling to constrain the CO2 budget and investigate the main factors that dominated δ13C-CO2 variations for the Yangtze River delta (YRD) region, one of the largest anthropogenic CO2 hotspots and densely populated regions in China. We used the WRF-STILT model framework with category-specified EDGAR v4.3.2 CO2 inventories to simulate hourly CO2 mixing ratios and δ13C-CO2, evaluated these simulations with observations, and constrained the total anthropogenic CO2 emission. We show that (1) top-down and bottom-up estimates of anthropogenic CO2 emissions agreed well (bias < 6 %) on an annual basis, (2) the WRF-STILT model can generally reproduce the observed diel and seasonal atmospheric δ13C-CO2 variations, and (3) anthropogenic CO2 emissions played a much larger role than ecosystems in controlling the δ13C-CO2 seasonality. When excluding ecosystem respiration and photosynthetic discrimination in the YRD area, δ13C-CO2 seasonality increased from 1.53 ‰ to 1.66 ‰. (4) Atmospheric transport processes in summer amplified the cement CO2 enhancement proportions in the YRD area, which dominated monthly δs (the mixture of δ13C-CO2 from all regional end-members) variations. These findings show that the combination of long-term atmospheric carbon isotope observations and inverse modeling can provide a powerful constraint on the carbon cycle of these complex megacities.


2018 ◽  
Vol 25 (23) ◽  
pp. 23157-23169 ◽  
Author(s):  
Cheng Hu ◽  
Shoudong Liu ◽  
Yongwei Wang ◽  
Mi Zhang ◽  
Wei Xiao ◽  
...  

Author(s):  
Shufeng She ◽  
Bifeng Hu ◽  
Xianglin Zhang ◽  
Shuai Shao ◽  
Yefeng Jiang ◽  
...  

Potentially toxic elements (PTEs) pollution in the agricultural soil of China, especially in developed regions such as the Yangtze River Delta (YRD) in eastern China, has received increasing attention. However, there are few studies on the long-term assessment of soil pollution by PTEs over large regions. Therefore, in this study, a meta-analysis was conducted to evaluate the current state and temporal trend of PTEs pollution in the agricultural land of the Yangtze River Delta. Based on a review of 118 studies published between 1993 and 2020, the average concentrations of Cd, Hg, As, Pb, Cr, Cu, Zn, and Ni were found to be 0.25 mg kg−1, 0.14 mg kg−1, 8.14 mg kg−1, 32.32 mg kg−1, 68.84 mg kg−1, 32.58 mg kg−1, 92.35 mg kg−1, and 29.30 mg kg−1, respectively. Among these elements, only Cd and Hg showed significant accumulation compared with their background values. The eastern Yangtze River Delta showed a relatively high ecological risk due to intensive industrial activities. The contents of Cd, Pb, and Zn in soil showed an increasing trend from 1993 to 2000 and then showed a decreasing trend. The results obtained from this study will provide guidance for the prevention and control of soil pollution in the Yangtze River Delta.


Land ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 804
Author(s):  
Bo Niu ◽  
Dazhuan Ge ◽  
Rui Yan ◽  
Yingyi Ma ◽  
Dongqi Sun ◽  
...  

In recent years, the impact of land-use systems on global climate change has become increasingly significant, and land-use change has become a hot issue of concern to academics, both within China and abroad. Urbanization, as an important socioeconomic factor, plays a vital role in promoting land-use transition, which also shows a significant spatial dependence on urbanization. This paper constructs a theoretical framework for the interaction relationship between urbanization and land-use transition, taking the Yangtze River Delta as an example, and measures the level of urbanization from the perspective of population urbanization, economic urbanization and social urbanization, while also evaluating the level of land-use morphologies from the perspective of dominant and recessive morphologies of land-use. We construct a PVAR model and coupled coordination model based on the calculated indexes for empirical analysis. The results show that the relationship between urbanization and land-use transition is not a simple linear relationship, but tends to be complex with the process of urbanization, and reasonable urbanization and land-use morphologies will promote further benign coupling in the system. By analyzing the interaction relationship between urbanization and land-use transition, this study enriches the study of land-use change and provides new pathways for thinking about how to promote high-quality urbanization.


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