scholarly journals Supplementary material to "Simulation-aided characterization of a versatile water condensation particle counter for atmospheric airborne research"

Author(s):  
Fan Mei ◽  
Steven Spielman ◽  
Susanne Hering ◽  
Jian Wang ◽  
Mikhail Pekour ◽  
...  
2009 ◽  
Vol 43 (8) ◽  
pp. 767-780 ◽  
Author(s):  
Hossein Saghafifar ◽  
Andreas Kürten ◽  
Joachim Curtius ◽  
Sarah-Lena von der Weiden ◽  
Smaeyl Hassanzadeh ◽  
...  

2021 ◽  
Author(s):  
Fan Mei ◽  
Steven Spielman ◽  
Susanne Hering ◽  
Jian Wang ◽  
Mikhail Pekour ◽  
...  

Abstract. Capturing the vertical profiles and horizontal variations of atmospheric aerosols often requires accurate airborne measurements. With the advantage of avoiding health and safety concerns related to the use of butanol or other chemicals, a water-based condensation particle counter (wCPC) has emerged to provide measurements under various environments. However, the airborne deployment of wCPC is relatively rare due to the lack of characterization of wCPC performance. This study investigates the performance of a commercial "versatile" water CPC (vWCPC Model 3789, TSI) under low-pressure conditions. The effect of conditioner temperature on wCPC performance at low pressure is examined through numerical simulation and laboratory experiments. We show that the default instrument temperature setting of 30 °C for the conditioner is not suitable for airborne measurement and that the optimal conditioner temperature for low-pressure operation is 27 °C. Additionally, we show that insufficient droplet growth becomes more significant under the low-pressure operation. The variation in the chemical composition can contribute up to 20 % uncertainty in the counting efficiency of the wCPC, but this variation is independent of pressure.


2017 ◽  
Vol 10 (6) ◽  
pp. 2271-2281 ◽  
Author(s):  
Juha Kangasluoma ◽  
Susanne Hering ◽  
David Picard ◽  
Gregory Lewis ◽  
Joonas Enroth ◽  
...  

Abstract. In this study we characterized the performance of three new particle counters able to detect particles smaller than 3 nm during the Helsinki condensation particle counter (CPC) workshop in summer 2016: the Aerosol Dynamics Inc. (ADI; Berkeley, USA) versatile water condensation particle counter (vWCPC), TSI 3777 nano enhancer (TSI Inc., Shoreview, USA) and modified and boosted TSI 3010-type CPC from Université Blaise Pascal called a B3010. The performance of all CPCs was first measured with charged tungsten oxide test particles at temperature settings which resulted in supersaturation low enough to not detect any ions produced by a radioactive source. Due to similar measured detection efficiencies, additional comparison between the 3777 and vWCPC were conducted using electrically neutral tungsten oxide test particles and with positively charged tetradodecylammonium bromide. Furthermore, the detection efficiencies of the 3777 and vWCPC were measured with boosted temperature settings yielding supersaturation which was at the onset of homogeneous nucleation for the 3777 or confined within the range of liquid water for the ADI vWCPC. Finally, CPC-specific tests were conducted to probe the response of the 3777 to various inlet flow relative humidities, of the B3010 to various inlet flow rates and of the vWCPC to various particle concentrations. For the 3777 and vWCPC the measured 50 % detection diameters (d50s) were in the range of 1.3–2.4 nm for the tungsten oxide particles, depending on the particle charging state and CPC temperature settings, between 2.5 and 3.3 nm for the organic test aerosol, and in the range of 3.2–3.4 nm for tungsten oxide for the B3010.


2021 ◽  
Vol 155 ◽  
pp. 105772
Author(s):  
Yiliang Liu ◽  
Michel Attoui ◽  
Yueyang Li ◽  
Jianmin Chen ◽  
Qing Li ◽  
...  

2019 ◽  
Author(s):  
Oriol Planas ◽  
Feng Wang ◽  
Markus Leutzsch ◽  
Josep Cornella

The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mimicking the canonical organometallic steps associated to a transition metal, is an elusive and unprecedented approach in the field of homogeneous catalysis. Herein we present a catalytic protocol based on bismuth, a benign and sustainable main-group element, capable of performing every organometallic step in the context of oxidative fluorination of boron compounds; a territory reserved to transition metals. A rational ligand design featuring hypervalent coordination together with a mechanistic understanding of the fundamental steps, permitted a catalytic fluorination protocol based on a Bi(III)/Bi(V) redox couple, which represents a unique example where a main-group element is capable of outperforming its transition metal counterparts.<br>A main text and supplementary material have been attached as pdf files containing all the methodology, techniques and characterization of the compounds reported.<br>


2021 ◽  
Author(s):  
Anna K. Tobler ◽  
Alicja Skiba ◽  
Francesco Canonaco ◽  
Griša Močnik ◽  
Pragati Rai ◽  
...  

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