scholarly journals Operation of the Airmodus A11 nano Condensation Nucleus Counter at various inlet pressures, various operation temperatures and design of a new inlet system

2015 ◽  
Vol 8 (8) ◽  
pp. 8483-8508 ◽  
Author(s):  
J. Kangasluoma ◽  
A. Franchin ◽  
J. Duplissy ◽  
L. Ahonen ◽  
F. Korhonen ◽  
...  

Abstract. Measuring sub-3 nm particles outside of controlled laboratory conditions is a challenging task, as many of the instruments are operated at their limits and are subjected to changing ambient conditions. In this study, we advance the current understanding on the operation of Airmodus A11 nano Condensation Nucleus Counter (nCNC), which consists of a A10 Particle Size Magnifier (PSM) and A20 condensation particle counter (CPC). We explore the effect of the inlet line pressure on the measured particle concentration. We identify two different regions inside the instrument where supersaturation of working fluid can take place. We show the possibility of varying the cut-off of the instrument from 1 to 6 nm, a wider size range than the one usually covered by the PSM. We also present a new inlet system, which allows automated measurements of the background, minimizes the diffusion losses in the sampling line and is equipped with an electrostatic filter to remove ions. Finally, our view of the guidelines for optimal use of the Airmodus nCNC are provided.

2016 ◽  
Vol 9 (7) ◽  
pp. 2977-2988 ◽  
Author(s):  
Juha Kangasluoma ◽  
Alessandro Franchin ◽  
Jonahtan Duplissy ◽  
Lauri Ahonen ◽  
Frans Korhonen ◽  
...  

Abstract. Measuring sub-3 nm particles outside of controlled laboratory conditions is a challenging task, as many of the instruments are operated at their limits and are subject to changing ambient conditions. In this study, we advance the current understanding of the operation of the Airmodus A11 nano Condensation Nucleus Counter (nCNC), which consists of an A10 Particle Size Magnifier (PSM) and an A20 Condensation Particle Counter (CPC). The effect of the inlet line pressure on the measured particle concentration was measured, and two separate regions inside the A10, where supersaturation of working fluid can take place, were identified. The possibility of varying the lower cut-off diameter of the nCNC was investigated; by scanning the growth tube temperature, the range of the lower cut-off was extended from 1–2.5 to 1–6 nm. Here we present a new inlet system, which allows automated measurement of the background concentration of homogeneously nucleated droplets, minimizes the diffusion losses in the sampling line and is equipped with an electrostatic filter to remove ions smaller than approximately 4.5 nm. Finally, our view of the guidelines for the optimal use of the Airmodus nCNC is provided.


2019 ◽  
Author(s):  
Jose Julio Gutierrez Moreno ◽  
Marco Fronzi ◽  
Pierre Lovera ◽  
alan O'Riordan ◽  
Mike J Ford ◽  
...  

<p></p><p>Interfacial metal-oxide systems with ultrathin oxide layers are of high interest for their use in catalysis. In this study, we present a density functional theory (DFT) investigation of the structure of ultrathin rutile layers (one and two TiO<sub>2</sub> layers) supported on TiN and the stability of water on these interfacial structures. The rutile layers are stabilized on the TiN surface through the formation of interfacial Ti–O bonds. Charge transfer from the TiN substrate leads to the formation of reduced Ti<sup>3+</sup> cations in TiO<sub>2.</sub> The structure of the one-layer oxide slab is strongly distorted at the interface, while the thicker TiO<sub>2</sub> layer preserves the rutile structure. The energy cost for the formation of a single O vacancy in the one-layer oxide slab is only 0.5 eV with respect to the ideal interface. For the two-layer oxide slab, the introduction of several vacancies in an already non-stoichiometric system becomes progressively more favourable, which indicates the stability of the highly non-stoichiometric interfaces. Isolated water molecules dissociate when adsorbed at the TiO<sub>2</sub> layers. At higher coverages the preference is for molecular water adsorption. Our ab initio thermodynamics calculations show the fully water covered stoichiometric models as the most stable structure at typical ambient conditions. Interfacial models with multiple vacancies are most stable at low (reducing) oxygen chemical potential values. A water monolayer adsorbs dissociatively on the highly distorted 2-layer TiO<sub>1.75</sub>-TiN interface, where the Ti<sup>3+</sup> states lying above the top of the valence band contribute to a significant reduction of the energy gap compared to the stoichiometric TiO<sub>2</sub>-TiN model. Our results provide a guide for the design of novel interfacial systems containing ultrathin TiO<sub>2</sub> with potential application as photocatalytic water splitting devices.</p><p></p>


1983 ◽  
Vol 14 (3) ◽  
pp. 387-391 ◽  
Author(s):  
James Charles Wilson ◽  
Edmund D. Blackshear ◽  
Jong Ho Hyun

2016 ◽  
Vol 37 (3) ◽  
pp. 109-138 ◽  
Author(s):  
Henryk Bieliński

AbstractThe current paper presents the experimental validation of the generalized model of the two-phase thermosyphon loop. The generalized model is based on mass, momentum, and energy balances in the evaporators, rising tube, condensers and the falling tube. The theoretical analysis and the experimental data have been obtained for a new designed variant. The variant refers to a thermosyphon loop with both minichannels and conventional tubes. The thermosyphon loop consists of an evaporator on the lower vertical section and a condenser on the upper vertical section. The one-dimensional homogeneous and separated two-phase flow models were used in calculations. The latest minichannel heat transfer correlations available in literature were applied. A numerical analysis of the volumetric flow rate in the steady-state has been done. The experiment was conducted on a specially designed test apparatus. Ultrapure water was used as a working fluid. The results show that the theoretical predictions are in good agreement with the measured volumetric flow rate at steady-state.


Author(s):  
Patricia B. Keady ◽  
Veryl L. Denler ◽  
Gilmore J. Sem ◽  
Mark R. Stolzenburg ◽  
Peter H. McMurry

2020 ◽  
Vol 44 (7) ◽  
pp. 2986-2995 ◽  
Author(s):  
Lidan Lan ◽  
Fei Liu ◽  
Yi Dan ◽  
Long Jiang

A facile fabrication method was developed for the one-pot synthesis of 1,3,5-triformylbenzene (TFB)-4,4′4′′-triaminotriphenylamine (TPA) and 1,3,5-triformylbenzene-terephthalaldehyde (TA) under ambient conditions via a Schiff-base reaction.


2005 ◽  
Vol 36 (11) ◽  
pp. 1322-1337 ◽  
Author(s):  
M. Hermann ◽  
S. Adler ◽  
R. Caldow ◽  
F. Stratmann ◽  
A. Wiedensohler

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