scholarly journals Black shale deposition during Toarcian super-greenhouse driven by sea level

2013 ◽  
Vol 9 (4) ◽  
pp. 4365-4384 ◽  
Author(s):  
M. Hermoso ◽  
F. Minoletti ◽  
P. Pellenard
Keyword(s):  
Organic Carbon ◽  
Water Column ◽  
Sea Level ◽  
Sequence Stratigraphy ◽  
Carbon Isotopes ◽  
Black Shale ◽  
Black Shales ◽  
Positive Trend ◽  
Sea Level Changes ◽  
Organic Carbon Burial

Abstract. One of the most elusive aspects of the Toarcian Oceanic Anoxic Event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the T-OAE (defined by the overarching positive trend in the carbon isotopes). In the present studied, we have attempted to establish a sequence stratigraphy framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a combination of mineralogical (quartz and clay relative abundance) and geochemical (Si, Zr, Ti and Al) measurements. Combined with the evolution in redox sensitive elements (Fe, V and Mo), the data suggest that expression of anoxia was hampered in European epicontinental seas during most of the T-OAE due to insufficient water depth that prevented stratification of the water column. Only the first stratigraphic occurrence of black shales in Europe corresponds to the "global" event. This interval is characterised by > 10% Total Organic Carbon (TOC) content that contains relatively low concentration of molybdenum compared to subsequent black shale horizons. Additionally, this first black shale occurrence is coeval with the record of the major negative Carbon Isotope Excursion (CIE), likely corresponding to a period of transient greenhouse intensification likely due to massive injection of carbon into the Atmosphere–Ocean system. As a response to enhanced weathering and riverine run-off, increased fresh water supply to the basin may have promoted the development of full anoxic conditions through haline stratification of the water column. In contrast, post T-OAE black shales were restricted to epicontinental seas (higher Mo to TOC ratios) during a period of relative high sea level, and carbon isotopes returning to pre-T-OAE values. Comparing palaeoredox proxies with the inferred sequence stratigraphy for Sancerre suggests that episodes of short-term organic carbon enrichment were primarily driven by third-order sea level changes. These black shales exhibit remarkably well-expressed higher-frequency cyclicities in the concentration of redox-sensitive elements such as iron or vanadium whose nature has still to be determined through cyclostratigraphic analysis.

scholarly journals Black shale deposition during Toarcian super-greenhouse driven by sea level

2013 ◽  
Vol 9 (6) ◽  
pp. 2703-2712 ◽  
Author(s):  
M. Hermoso ◽  
F. Minoletti ◽  
P. Pellenard
Keyword(s):  
Organic Carbon ◽  
Water Column ◽  
Sea Level ◽  
Carbon Isotope ◽  
Carbon Isotopes ◽  
Black Shale ◽  
Black Shales ◽  
Positive Trend ◽  
Sea Level Changes ◽  
Organic Carbon Burial

Abstract. One of the most elusive aspects of the Toarcian oceanic anoxic event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the end of the overarching positive trend in the carbon isotopes that characterises the T-OAE. In the present study, we have attempted to establish a sequence stratigraphic framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a combination of mineralogical (quartz and clay relative abundance) and geochemical (Si, Zr, Ti and Al) measurements. Combined with the evolution in redox sensitive elements (Fe, V and Mo), the data suggest that expression of anoxia was hampered in European epicontinental seas during most of the T-OAE (defined by the positive carbon isotope trend) due to insufficient water depth that prevented stratification of the water column. Only the first stratigraphic occurrence of black shales in Europe corresponds to the "global" event. This interval is characterised by >10% Total Organic Carbon (TOC) content that contains relatively low concentration of molybdenum compared to subsequent black shale horizons. Additionally, this first black shale occurrence is coeval with the record of the major negative Carbon Isotope Excursion (CIE), likely corresponding to a period of transient greenhouse intensification likely due to massive injection of carbon into the atmosphere–ocean system. As a response to enhanced weathering and riverine run-off, increased fresh water supply to the basin may have promoted the development of full anoxic conditions through haline stratification of the water column. In contrast, post T-OAE black shales during the serpentinum and bifrons Zones were restricted to epicontinental seas (higher Mo to TOC ratios) during a period of relative high sea level, and carbon isotopes returning to pre-T-OAE values. Comparing palaeoredox proxies with the inferred sequence stratigraphy for Sancerre suggests that episodes of short-term organic carbon enrichment were primarily driven by third-order sea level changes. These black shales exhibit remarkably well-expressed higher-frequency cyclicities in the oxygen availability in the water column whose nature has still to be determined through cyclostratigraphic analysis.

scholarly journals Lower Wenlock black shales in the northern Holy Cross Mountains, Poland: sedimentary and geochemical controls on the Ireviken Event in a deep marine setting

2016 ◽  
Vol 154 (2) ◽  
pp. 247-264 ◽  
Author(s):  
JUSTYNA SMOLAREK ◽  
WIESŁAW TRELA ◽  
DAVID P. G. BOND ◽  
LESZEK MARYNOWSKI
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Water Column ◽  
Black Shale ◽  
Bottom Water ◽  
Black Shales ◽  
Redox Conditions ◽  
Pyrite Framboids ◽  
Redox History ◽  
Deposition Conditions

AbstractThe stratigraphic variability and geochemistry of Llandovery/Wenlock (L/W) Series boundary sediments in Poland reveals that hemipelagic sedimentation under an anoxic/euxinic water column was interrupted by low-density bottom currents or detached diluted turbid layers that resulted in intermittent seafloor oxygenation. Total organic carbon values and inorganic proxies throughout the Wilków 1 borehole section suggest variable redox conditions. U/Mo ratios > 1 throughout much of the Aeronian and Telychian stages, together with an absence of pyrite framboids, suggest oxygenated conditions prevailed. However, elevated total organic carbon near the Aeronian/Telychian boundary, together with increased U/Th and V/(V + Ni) ratios and populations of small pyrite framboids are consistent with the development of dysoxic/anoxic conditions at that time. U/Th, V/Cr and V/(V + Ni) ratios, as well as Uauthig and Mo concentrations, suggest that during the Ireviken black shale deposition, bottom-water conditions deteriorated from oxic during Telychian time to mostly suboxic/anoxic immediately prior to the L/W boundary, before a brief reoxygenation at the end of the Ireviken black shale sedimentation in the Sheinwoodian Stage. Rapid fluctuations in U/Mo during the Ireviken Event are characteristic of fluctuating redox conditions that culminated in an anoxic/euxinic seafloor in Sheinwoodian time. Following Ireviken black shale deposition, conditions once again became oxygen deficient with the development of a euxinic zone in the water column. The Aeronian to Sheinwoodian deep-water redox history was unstable, and rapid fluctuations of the chemocline across the L/W Series boundary probably contributed to the Ireviken Event extinctions, which affected mainly pelagic and hemipelagic fauna.

scholarly journals Secular variation in Late Cretaceous carbon isotopes: a new δ13C carbonate reference curve for the Cenomanian–Campanian (99.6–70.6 Ma)

2006 ◽  
Vol 143 (5) ◽  
pp. 561-608 ◽  
Author(s):  
IAN JARVIS ◽  
ANDREW S. GALE ◽  
HUGH C. JENKYNS ◽  
MARTIN A. PEARCE
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Sea Level Rise ◽  
Sea Level ◽  
Carbon Isotope ◽  
Carbon Isotopes ◽  
Reference Curve ◽  
Organic Carbon Burial ◽  
Isotope Stratigraphy ◽  
Using Data

Carbon stable-isotope variation through the Cenomanian–Santonian stages is characterized using data for 1769 bulk pelagic carbonate samples collected from seven Chalk successions in England. The sections show consistent stratigraphic trends and δ13C values that provide a basis for high-resolution correlation. Positive and negative δ13C excursions and inflection points on the isotope profiles are used to define 72 isotope events. Key markers are provided by positive δ13C excursions of up to +2‰: the Albian/Cenomanian Boundary Event; Mid-Cenomanian Event I; the Cenomanian/Turonian Boundary Event; the Bridgewick, Hitch Wood and Navigation events of Late Turonian age; and the Santonian/Campanian Boundary Event. Isotope events are isochronous within a framework provided by macrofossil datum levels and bentonite horizons. An age-calibrated composite δ13C reference curve and an isotope event stratigraphy are constructed using data from the English Chalk. The isotope stratigraphy is applied to successions in Germany, France, Spain and Italy. Correlation with pelagic sections at Gubbio, central Italy, demonstrates general agreement between biostratigraphic and chemostratigraphic criteria in the Cenomanian–Turonian stages, confirming established relationships between Tethyan planktonic foraminiferal and Boreal macrofossil biozonations. Correlation of the Coniacian–Santonian stages is less clear cut: magnetostratigraphic evidence for placing the base of Chron 33r near the base of the Upper Santonian is in good agreement with the carbon-iso-tope correlation, but generates significant anomalies regarding the placement of the Santonian and Campanian stage boundaries with respect to Tethyan planktonic foraminiferal and nannofossil zones. Isotope stratigraphy offers a more reliable criterion for detailed correlation of Cenomanian–Santonian strata than biostratigraphy. With the addition of Campanian δ13C data from one of the English sections, a composite Cenomanian–Campanian age-calibrated reference curve is presented that can be utilized in future chemostratigraphic studies.The Cenomanian–Campanian carbon-isotope curve is remarkably similar in shape to supposedly eustatic sea-level curves: increasing δ13C values accompanying sea-level rise associated with transgression, and falling δ13C values characterizing sea-level fall and regression. The correlation between carbon isotopes and sea-level is explained by variations in epicontinental sea area affecting organic-matter burial fluxes: increasing shallow sea-floor area and increased accommodation space accompanying sea-level rise allowed more efficient burial of marine organic matter, with the preferential removal of 12C from the marine carbon reservoir. During sea-level fall, reduced seafloor area, marine erosion of previously deposited sediments, and exposure of basin margins led to reduced organic-carbon burial fluxes and oxidation of previously deposited organic matter, causing falling δ13C values. Additionally, drowning of carbonate platforms during periods of rapid sea-level rise may have reduced the global inorganic relative to the organic carbon flux, further enhancing δ13C values, while renewed platform growth during late transgressions and highstands prompted increased carbonate deposition. Variations in nutrient supply, changing rates of oceanic turnover, and the sequestration or liberation of methane from gas hydrates may also have played a role in controlling carbon-isotope ratios.

scholarly journals Palaeoenvironmental evolution of the Southern Alps across the Faraoni Level equivalent: new data from the Trento Plateau (Upper Hauterivian, Dolomites, N. Italy)

2013 ◽  
Vol 63 (1) ◽  
pp. 89-104 ◽  
Author(s):  
Alexander Lukeneder ◽  
Patrick Grunert
Keyword(s):  
Sea Level ◽  
Oxygen Depletion ◽  
Southern Alps ◽  
Black Shales ◽  
Positive Trend ◽  
Southeastern Part ◽  
Faunal Turnover ◽  
Eastern Margin ◽  
Upper Hauterivian ◽  
C 30

Abstract Lukeneder, A. and Grunert, P. 2013. Palaeoenvironmental evolution of the Southern Alps across the Faraoni Level equivalent: new data from the Trento Plateau (Upper Hauterivian, Dolomites, N. Italy). Acta Geologica Polonica, 63 (1), 89-104. Warszawa. New stratigraphic and palaeoenvironmental data are presented for the northeastern part of the Trento Plateau (Puez area, Southern Alps, Italy). The studied section corresponds to the upper Hauterivian Balearites balearis and “Pseudothurmannia ohmi” ammonite zones and normal palaeomagnetic chron upper M5. A c. 30-cm-thick bed is identified as the equivalent of the Faraoni Level, based on its position within the Pseudothurmannia mortilleti Subzone, the composition of its ammonite fauna and the peak of a minor positive trend in the δ 13 C bulk record. Microfacies and geochemical proxies compare well with those of the southeastern part of the Trento Plateau and indicate palaeoceanographic continuity along the eastern margin of the plateau. The abundances of radiolarians and nannoconids suggest a turnover in the trophic structure from eutrophic conditions around the Faraoni Level equivalent to oligotrophic conditions. Low organic matter and sulphur content and frequent bioturbation indicate a well-oxygenated environment. Ammonite diversity and life-habitat groups document the influence of sea level on the plateau: while epi- and mesopelagic ammonites occur commonly during sea-level highstands, all life-habitat groups become reduced during a sea-level lowstand in the Spathicrioceras seitzi and P. ohmi subzones. The Faraoni event is heralded by a faunal turnover expressed as the diversification of epipelagic ammonites. Palaeoenvironmental conditions along the eastern margin of the Trento Plateau during the Faraoni event contrast with those of the organic-rich black shales in the west. A re-evaluation of the depositional model based on the new results suggests a general water depth of 300-500 m for the plateau. The severe reduction of mesopelagic ammonites during the sea-level lowstand indicates a shallowing towards the epi-/mesopelagic boundary. During the Faraoni event, the eastern areas of the Trento Plateau were located at the upper limit of the oxygen-minimum layer and were thus only occasionally affected by oxygen depletion, whereas the western areas were located well within the upper part of the oxygen-depleted layer.

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