Milankovitch Climate Cyclicity and its Effect on Relative Sea Level Changes and Organic Carbon Storage, Late Cretaceous Black Shales of Colombia and Venezuela

AAPG Bulletin ◽  
1993 ◽  
Vol 77 ◽  
Author(s):  
VILLAMIL, TOMAS and ERLE G. KAUFFMA
Keyword(s):  
Organic Carbon ◽  
Sea Level ◽  
Carbon Storage ◽  
Late Cretaceous ◽  
Black Shales ◽  
Sea Level Changes ◽  
Relative Sea Level ◽  
Organic Carbon Storage

scholarly journals Black shale deposition during Toarcian super-greenhouse driven by sea level

2013 ◽  
Vol 9 (6) ◽  
pp. 2703-2712 ◽  
Author(s):  
M. Hermoso ◽  
F. Minoletti ◽  
P. Pellenard
Keyword(s):  
Organic Carbon ◽  
Water Column ◽  
Sea Level ◽  
Carbon Isotope ◽  
Carbon Isotopes ◽  
Black Shale ◽  
Black Shales ◽  
Positive Trend ◽  
Sea Level Changes ◽  
Organic Carbon Burial

Abstract. One of the most elusive aspects of the Toarcian oceanic anoxic event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the end of the overarching positive trend in the carbon isotopes that characterises the T-OAE. In the present study, we have attempted to establish a sequence stratigraphic framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a combination of mineralogical (quartz and clay relative abundance) and geochemical (Si, Zr, Ti and Al) measurements. Combined with the evolution in redox sensitive elements (Fe, V and Mo), the data suggest that expression of anoxia was hampered in European epicontinental seas during most of the T-OAE (defined by the positive carbon isotope trend) due to insufficient water depth that prevented stratification of the water column. Only the first stratigraphic occurrence of black shales in Europe corresponds to the "global" event. This interval is characterised by >10% Total Organic Carbon (TOC) content that contains relatively low concentration of molybdenum compared to subsequent black shale horizons. Additionally, this first black shale occurrence is coeval with the record of the major negative Carbon Isotope Excursion (CIE), likely corresponding to a period of transient greenhouse intensification likely due to massive injection of carbon into the atmosphere–ocean system. As a response to enhanced weathering and riverine run-off, increased fresh water supply to the basin may have promoted the development of full anoxic conditions through haline stratification of the water column. In contrast, post T-OAE black shales during the serpentinum and bifrons Zones were restricted to epicontinental seas (higher Mo to TOC ratios) during a period of relative high sea level, and carbon isotopes returning to pre-T-OAE values. Comparing palaeoredox proxies with the inferred sequence stratigraphy for Sancerre suggests that episodes of short-term organic carbon enrichment were primarily driven by third-order sea level changes. These black shales exhibit remarkably well-expressed higher-frequency cyclicities in the oxygen availability in the water column whose nature has still to be determined through cyclostratigraphic analysis.

scholarly journals Black shale deposition during Toarcian super-greenhouse driven by sea level

2013 ◽  
Vol 9 (4) ◽  
pp. 4365-4384 ◽  
Author(s):  
M. Hermoso ◽  
F. Minoletti ◽  
P. Pellenard
Keyword(s):  
Organic Carbon ◽  
Water Column ◽  
Sea Level ◽  
Sequence Stratigraphy ◽  
Carbon Isotopes ◽  
Black Shale ◽  
Black Shales ◽  
Positive Trend ◽  
Sea Level Changes ◽  
Organic Carbon Burial

Abstract. One of the most elusive aspects of the Toarcian Oceanic Anoxic Event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the T-OAE (defined by the overarching positive trend in the carbon isotopes). In the present studied, we have attempted to establish a sequence stratigraphy framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a combination of mineralogical (quartz and clay relative abundance) and geochemical (Si, Zr, Ti and Al) measurements. Combined with the evolution in redox sensitive elements (Fe, V and Mo), the data suggest that expression of anoxia was hampered in European epicontinental seas during most of the T-OAE due to insufficient water depth that prevented stratification of the water column. Only the first stratigraphic occurrence of black shales in Europe corresponds to the "global" event. This interval is characterised by > 10% Total Organic Carbon (TOC) content that contains relatively low concentration of molybdenum compared to subsequent black shale horizons. Additionally, this first black shale occurrence is coeval with the record of the major negative Carbon Isotope Excursion (CIE), likely corresponding to a period of transient greenhouse intensification likely due to massive injection of carbon into the Atmosphere–Ocean system. As a response to enhanced weathering and riverine run-off, increased fresh water supply to the basin may have promoted the development of full anoxic conditions through haline stratification of the water column. In contrast, post T-OAE black shales were restricted to epicontinental seas (higher Mo to TOC ratios) during a period of relative high sea level, and carbon isotopes returning to pre-T-OAE values. Comparing palaeoredox proxies with the inferred sequence stratigraphy for Sancerre suggests that episodes of short-term organic carbon enrichment were primarily driven by third-order sea level changes. These black shales exhibit remarkably well-expressed higher-frequency cyclicities in the concentration of redox-sensitive elements such as iron or vanadium whose nature has still to be determined through cyclostratigraphic analysis.

scholarly journals A Two-Stage Approach to the Estimation of High-Resolution Soil Organic Carbon Storage with Good Extension Capability

Land ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 517
Author(s):  
Sunwei Wei ◽  
Zhengyong Zhao ◽  
Qi Yang ◽  
Xiaogang Ding
Keyword(s):  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Carbon Storage ◽  
Guangdong Province ◽  
Soil Samples ◽  
Estimation Accuracy ◽  
Ann Model ◽  
Soil Layers ◽  
Second Stage ◽  
Organic Carbon Storage

Soil organic carbon storage (SOCS) estimation is a crucial branch of the atmospheric–vegetation–soil carbon cycle study under the background of global climate change. SOCS research has increased worldwide. The objective of this study is to develop a two-stage approach with good extension capability to estimate SOCS. In the first stage, an artificial neural network (ANN) model is adopted to estimate SOCS based on 255 soil samples with five soil layers (20 cm increments to 100 cm) in Luoding, Guangdong Province, China. This method is compared with three common methods: The soil type method (STM), ordinary kriging (OK), and radial basis function (RBF) interpolation. In the second stage, a linear model is introduced to capture the regional differences and further improve the estimation accuracy of the Luoding-based ANN model when extending it to Xinxing, Guangdong Province. This is done after assessing the generalizability of the above four methods with 120 soil samples from Xinxing. The results for the first stage show that the ANN model has much better estimation accuracy than STM, OK, and RBF, with the average root mean square error (RMSE) of the five soil layers decreasing by 0.62–0.90 kg·m−2, R2 increasing from 0.54 to 0.65, and the mean absolute error decreasing from 0.32 to 0.42. Moreover, the spatial distribution maps produced by the ANN model are more accurate than those of other methods for describing the overall and local SOCS in detail. The results of the second stage indicate that STM, OK, and RBF have poor generalizability (R2 < 0.1), and the R2 value obtained with ANN method is also 43–56% lower for the five soil layers compared with the estimation accuracy achieved in Luoding. However, the R2 of the linear models built with the 20% soil samples from Xinxing are 0.23–0.29 higher for the five soil layers. Thus, the ANN model is an effective method for accurately estimating SOCS on a regional scale with a small number of field samples. The linear model could easily extend the ANN model to outside areas where the ANN model was originally developed with a better level of accuracy.

Estimating organic carbon storage in temperate wetland profiles in Northeast China

Geoderma ◽  
2008 ◽  
Vol 146 (1-2) ◽  
pp. 311-316 ◽  
Author(s):  
Wen-Ju Zhang ◽  
He-Ai Xiao ◽  
Cheng-Li Tong ◽  
Yi-Rong Su ◽  
Wan-sheng Xiang ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Carbon Storage ◽  
Northeast China ◽  
Temperate Wetland ◽  
Organic Carbon Storage
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