scholarly journals A discrete interaction numerical model for coagulation and fragmentation of marine detritic particulate matter (Coagfrag v.1)

2021 ◽  
Vol 14 (7) ◽  
pp. 4535-4554
Author(s):  
Gwenaëlle Gremion ◽  
Louis-Philippe Nadeau ◽  
Christiane Dufresne ◽  
Irene R. Schloss ◽  
Philippe Archambault ◽  
...  

Abstract. A simplified model, representing the dynamics of marine organic particles in a given size range experiencing coagulation and fragmentation reactions, is developed. The framework is based on a discrete size spectrum on which reactions act to exchange properties between different particle sizes. The reactions are prescribed according to triplet interactions. Coagulation combines two particle sizes to yield a third one, while fragmentation breaks a given particle size into two (i.e. the inverse of the coagulation reaction). The complete set of reactions is given by all the permutations of two particle sizes associated with a third one. Since, by design, some reactions yield particle sizes that are outside the resolved size range of the spectrum, a closure is developed to take into account this unresolved range and satisfy global constraints such as mass conservation. In order to minimize the number of tracers required to apply this model to an ocean general circulation model, focus is placed on the robustness of the model to the particle size resolution. Thus, numerical experiments were designed to study the dependence of the results on (i) the number of particle size bins used to discretize a given size range (i.e. the resolution) and (ii) the type of discretization (i.e. linear vs. nonlinear). The results demonstrate that in a linearly size-discretized configuration, the model is independent of the resolution. However, important biases are observed in a nonlinear discretization. A first attempt to mitigate the effect of nonlinearity of the size spectrum is then presented and shows significant improvement in reducing the observed biases.

2021 ◽  
Author(s):  
Gwenaëlle Gremion ◽  
Louis-Philippe Nadeau ◽  
Christiane Dufresne ◽  
Irene R. Schloss ◽  
Philippe Archambault ◽  
...  

Abstract. A simplified model, representing the dynamics of marine organic particles in a given size range experiencing coagulation and fragmentation reactions is developed. The framework is based on a discrete size spectrum on which reactions act to exchange properties between different particle sizes. The reactions are prescribed according to triplets interactions. Coagulation combines two particle sizes to yield a third one, while fragmentation breaks a given particle size into two (i.e. the inverse of the coagulation reaction). The complete set of reactions is given by all the permutations of two particle sizes associated with a third one. Since, by design, some reactions yield particle sizes that are outside the resolved size range of the spectrum, a closure is developed to take into account this unresolved range and satisfy global constraints such as mass conservation. In order to minimize the number of tracers required to apply this model to an Ocean General Circulation Model focus is placed on the robustness of the model to the particle size resolution. Thus, numerical experiments were designed to study the dependence of the results on i) the number of particle size bins used to discretize a given size range (i.e. the resolution) and ii) the type of discretization (i.e. linear vs nonlinear). The results demonstrate that in a linearly size discretized configuration, the model is independent of the resolution. However, important biases are observed in a nonlinear discretization. A first attempt to mitigate the effect of nonlinearity of the size spectrum is then presented and shows significant improvement in reducing the observed biases.


2009 ◽  
Vol 39 (3) ◽  
pp. 753-767 ◽  
Author(s):  
Max Yaremchuk ◽  
Julian McCreary ◽  
Zuojun Yu ◽  
Ryo Furue

Abstract The salinity distribution in the South China Sea (SCS) has a pronounced subsurface maximum from 150–220 m throughout the year. This feature can only be maintained by the existence of a mean flow through the SCS, consisting of a net inflow of salty North Pacific tropical water through the Luzon Strait and outflow through the Mindoro, Karimata, and Taiwan Straits. Using an inverse modeling approach, the authors show that the magnitude and space–time variations of the SCS thermohaline structure, particularly for the salinity maximum, allow a quantitative estimate of the SCS throughflow and its distribution among the three outflow straits. Results from the inversion are compared with available observations and output from a 50-yr simulation of a highly resolved ocean general circulation model. The annual-mean Luzon Strait transport is found to be 2.4 ± 0.6 Sv (Sv ≡ 106 m3 s−1). This inflow is balanced by the outflows from the Karimata (0.3 ± 0.5 Sv), Mindoro (1.5 ± 0.4), and Taiwan (0.6 ± 0.5 Sv) Straits. Results of the inversion suggest that the Karimata transport tends to be overestimated in numerical models. The Mindoro Strait provides the only passage from the SCS deeper than 100 m, and half of the SCS throughflow (1.2 ± 0.3 Sv) exits the basin below 100 m in the Mindoro Strait, a result that is consistent with a climatological run of a 0.1° global ocean general circulation model.


2008 ◽  
Vol 274 (3-4) ◽  
pp. 448-461 ◽  
Author(s):  
Mark Siddall ◽  
Samar Khatiwala ◽  
Tina van de Flierdt ◽  
Kevin Jones ◽  
Steven L. Goldstein ◽  
...  

2017 ◽  
Author(s):  
Hannah M. Horowitz ◽  
Daniel J. Jacob ◽  
Yanxu Zhang ◽  
Theodore S. Dibble ◽  
Franz Slemr ◽  
...  

Abstract. Mercury (Hg) is emitted to the atmosphere mainly as volatile elemental Hg0. Oxidation to water-soluble HgII controls Hg deposition to ecosystems. Here we implement a new mechanism for atmospheric Hg0 / HgII redox chemistry in the GEOS-Chem global model and examine the implications for the global atmospheric Hg budget and deposition patterns. Our simulation includes a new coupling of GEOS-Chem to an ocean general circulation model (MITgcm), enabling a global 3-D representation of atmosphere-ocean Hg0 / HgII cycling. We find that atomic bromine (Br) of marine organobromine origin is the main atmospheric Hg0 oxidant, and that second-stage HgBr oxidation is mainly by the NO2 and HO2 radicals. The resulting lifetime of tropospheric Hg0 against oxidation is 2.7 months, shorter than in previous models. Fast HgII atmospheric reduction must occur in order to match the ~ 6-month lifetime of Hg against deposition implied by the observed atmospheric variability of total gaseous mercury (TGM ≡ Hg0 + HgII(g)). We implement this reduction in GEOS-Chem as photolysis of aqueous-phase HgII-organic complexes in aerosols and clouds, resulting in a TGM lifetime of 5.2 months against deposition and matching both mean observed TGM and its variability. Model sensitivity analysis shows that the interhemispheric gradient of TGM, previously used to infer a longer Hg lifetime against deposition, is misleading because southern hemisphere Hg mainly originates from oceanic emissions rather than transport from the northern hemisphere. The model reproduces the observed seasonal TGM variation at northern mid-latitudes (maximum in February, minimum in September) driven by chemistry and oceanic evasion, but does not reproduce the lack of seasonality observed at southern hemisphere marine sites. Aircraft observations in the lowermost stratosphere show a strong TGM-ozone relationship indicative of fast Hg0 oxidation, but we show that this relationship provides only a weak test of Hg chemistry because it is also influenced by mixing. The model reproduces observed Hg wet deposition fluxes over North America, Europe, and China, including the maximum over the US Gulf Coast driven by HgBr oxidation by NO2 and HO2. Low Hg wet deposition observed over rural China is attributed to fast HgII reduction in the presence of high organic aerosol concentrations. We find that 80 % of global HgII deposition takes place over the oceans, reflecting the marine origin of Br and low concentrations of marine organics for HgII reduction, and most of HO2 and NO2 for second-stage HgBr oxidation.


Oceanography ◽  
2012 ◽  
Vol 25 (2) ◽  
pp. 20-29 ◽  
Author(s):  
Brian Arbic ◽  
James Richman ◽  
Jay Shriver ◽  
Patrick Timko ◽  
Joseph Metzger ◽  
...  

Ocean Science ◽  
2014 ◽  
Vol 10 (6) ◽  
pp. 967-975 ◽  
Author(s):  
A. J. G. Nurser ◽  
S. Bacon

Abstract. The first (and second) baroclinic deformation (or Rossby) radii are presented north of ~60° N, focusing on deep basins and shelf seas in the high Arctic Ocean, the Nordic seas, Baffin Bay, Hudson Bay and the Canadian Arctic Archipelago, derived from climatological ocean data. In the high Arctic Ocean, the first Rossby radius increases from ~5 km in the Nansen Basin to ~15 km in the central Canadian Basin. In the shelf seas and elsewhere, values are low (1–7 km), reflecting weak density stratification, shallow water, or both. Seasonality strongly impacts the Rossby radius only in shallow seas, where winter homogenization of the water column can reduce it to below 1 km. Greater detail is seen in the output from an ice–ocean general circulation model, of higher resolution than the climatology. To assess the impact of secular variability, 10 years (2003–2012) of hydrographic stations along 150° W in the Beaufort Gyre are also analysed. The first-mode Rossby radius increases over this period by ~20%. Finally, we review the observed scales of Arctic Ocean eddies.


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