scholarly journals Development of standard measurement techniques and standard reference materials for heat capacity and heat of vaporization of jet fuels

1988 ◽  
Author(s):  
Jane E Callanan
2012 ◽  
Vol 5 (8) ◽  
pp. 1869-1887 ◽  
Author(s):  
D. Baumgardner ◽  
O. Popovicheva ◽  
J. Allan ◽  
V. Bernardoni ◽  
J. Cao ◽  
...  

Abstract. Soot, which is produced from biomass burning and the incomplete combustion of fossil and biomass fuels, has been linked to regional and global climate change and to negative health problems. Scientists measure the properties of soot using a variety of methods in order to quantify source emissions and understand its atmospheric chemistry, reactivity under emission conditions, interaction with solar radiation, influence on clouds, and health impacts. A major obstacle currently limiting progress is the absence of established standards or reference materials for calibrating the many instruments used to measure the various properties of soot. The current state of availability and practicability of soot standard reference materials (SRMs) was reviewed by a group of 50 international experts during a workshop in June of 2011. The workshop was convened to summarize the current knowledge on soot measurement techniques, identify the measurement uncertainties and limitations related to the lack of soot SRMs, and identify attributes of SRMs that, if developed, would reduce measurement uncertainties. The workshop established that suitable SRMs are available for calibrating some, but not all, measurement methods. The community of users of the single-particle soot-photometer (SP2), an instrument using laser-induced incandescence, identified a suitable SRM, fullerene soot, but users of instruments that measure light absorption by soot collected on filters did not. Similarly, those who use thermal optical analysis (TOA) to analyze the organic and elemental carbon components of soot were not satisfied with current SRMs. The workshop, and subsequent, interactive discussions, produced a number of recommendations for the development of new SRMs, and their implementation, that would be suitable for the different soot measurement methods.


2012 ◽  
Vol 5 (2) ◽  
pp. 2315-2362 ◽  
Author(s):  
D. Baumgardner ◽  
O. Popovicheva ◽  
J. Allan ◽  
V. Bernardoni ◽  
J. Cao ◽  
...  

Abstract. Soot, which is produced from biomass burning and the incomplete combustion of fossil and biomass fuels, has been linked to regional and global climate change and to negative health problems. Scientists measure soot using a variety of methods in order to quantify source emissions and understand its atmospheric chemistry, reactivity under emission conditions, interaction with solar radiation, influence on clouds, and health impacts. A major obstacle currently limiting progress is the absence of established standards or reference materials for calibrating the many instruments used to measure the various properties of soot. The current state of availability and practicability of soot standard reference materials (SRMs) was reviewed by a group of 50 international experts during a workshop in June of 2011. The workshop was convened to summarize the current knowledge on soot measurement techniques, identify the measurement uncertainties and limitations related to the lack of SRMs, and identify attributes of SRMs that, if developed, would reduce measurement uncertainties. The workshop established that suitable SRMs are available for calibrating some, but not all, measurement methods. The community of single-particle sootphotometer (SP2) users identified a suitable SRM, fullerene soot, but users of instruments that measure light absorption by soot collected on filters did not. Similarly, those who use thermal optical analysis (TOA) to analyze the organic and elemental carbon components of soot were not satisfied with current SRMs. The workshop produced recommendations for the development of new SRMs that would be suitable for the different soot measurement methods.


2010 ◽  
Vol 3 (2) ◽  
pp. 1743-1773
Author(s):  
O. Popovicheva ◽  
R. Subramanian ◽  
D. Baumgardner ◽  
G. Kok ◽  
R. Cary ◽  
...  

Abstract. The lack of standard reference materials for calibrating, troubleshooting and intercomparing instruments that measure the properties of black carbon, commonly referred to as soot, has been a major obstacle that hinders improved understanding of how climate and health is impacted by this ubiquitous component of the atmosphere. A different approach is offered here as a means of constructing precisely controlled material with fractions of organic carbon (OC) on the surface of elemental carbon (EC) whose structure reflects that of combustion particles found in the atmosphere. The proposed soot reference material (SRM) uses elemental carbon as a basis substrate for surface coatings of organic compounds that are representative of main classes of organics identified in the coverage of soot produced by fossil fuel burning. A number of methods are used to demonstrate the quality and stability of the reference EC and SRM. Comparison of the nominal fraction of OC deposited on the EC substrate with the fraction measured with thermal/optical analysis (TOA) shows excellent agreement. Application of this type of reference material for evaluating the different methods of carbon analysis may help resolve differences that currently exist between comparable measurement techniques when trying to separate OC and EC from ambient samples.


2011 ◽  
Vol 106 (2) ◽  
pp. 347-354 ◽  
Author(s):  
Eveline De Robertis ◽  
Gabriela F. Moreira ◽  
Raigna A. Silva ◽  
Carlos A. Achete

2004 ◽  
Vol 378 (5) ◽  
pp. 1251-1264 ◽  
Author(s):  
Stephen A. Wise ◽  
Dianne L. Poster ◽  
Michele M. Schantz ◽  
John R. Kucklick ◽  
Lane C. Sander ◽  
...  

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