scholarly journals Thermotropic Liquid Crystalline Behavior of Aliphatic Acid Esters of N,O-Hydroxypropyl Chitosans

Polymer Korea ◽  
2013 ◽  
Vol 37 (3) ◽  
pp. 276-287
Author(s):  
Hyo Gap Kim ◽  
Seung Yong Jung ◽  
Yung Dae Ma
1951 ◽  
Vol 43 (3) ◽  
pp. 684-688 ◽  
Author(s):  
C. J. Maim ◽  
J. W. Mench ◽  
D. L. Kendall ◽  
G. D. Hiatt

1982 ◽  
Vol 86 (10) ◽  
pp. 1908-1913 ◽  
Author(s):  
Ernst J. R. Sudholter ◽  
Jan B. F. N. Engberts ◽  
Wim H. De Jeu

Molecules ◽  
2019 ◽  
Vol 24 (5) ◽  
pp. 836 ◽  
Author(s):  
Meng-Qi Ling ◽  
Han Xie ◽  
Yu-Bo Hua ◽  
Jian Cai ◽  
Si-Yu Li ◽  
...  

Bottle aging is the final stage before wines are drunk, and is considered as a maturation time when many chemical changes occur. To get a better understanding of the evolution of wines’ flavor profile, the flavor compounds (phenolic and volatile compounds), dissolved oxygen (DO), and flavor characters (OAVs and chromatic parameters) of rosé and dry white wines bottled with different closures were determined after 18 months’ bottle aging. The results showed the main phenolic change trends of rosé wines were decreasing while the trends of white wines were increasing, which could be the reason for their unique DO changing behaviors. Volatile compounds could be clustered into fluctuating, increasing, and decreasing groups using k-means algorithm. Most volatile compounds, especially some long-chain aliphatic acid esters (octanoates and decanoates), exhibited a lower decrease rate in rosé wines sealed with natural corks and white wines with screw caps. After 18 months of bottle aging, wines treated with natural corks and their alternatives could be distinguished into two groups based on flavor compounds via PLS-DA. As for flavor characters, the total intensity of aroma declined obviously compared with their initial counterparts. Rosé wines exhibit visual difference in color, whereas such a phenomenon was not observed in white wines.


Carbon ◽  
2015 ◽  
Vol 81 ◽  
pp. 694-701 ◽  
Author(s):  
Seungwon Lee ◽  
Youngho Eom ◽  
Byung-Jun Kim ◽  
Isao Mochida ◽  
Seong-Ho Yoon ◽  
...  

2017 ◽  
Vol 21 (01) ◽  
pp. 16-23 ◽  
Author(s):  
Sibel Eken Korkut ◽  
Hale Ocak ◽  
Belkıs Bilgin-Eran ◽  
Dilek Güzeller ◽  
M. Kasım Şener

The novel metal free phthalocyanine and its copper complex which are octa-substituted at the peripheral positions with 4-(([Formula: see text]-3,7-dimethlyoctyloxy)phenoxy moieties were synthesized and characterized by FT-IR, 1H NMR and mass spectroscopy. Their mesomorphic properties were studied by polarizing optical microscopy. The spectroscopic properties and aggregation behaviors of the novel phthalocyanines were also investigated by UV-vis spectroscopy in different solvents with same concentration as well as in a wide range of concentrations of chloroform. Both compounds with chloroform and [Formula: see text]-dodecane clearly show the lyotropic columnar mesophase in a wide temperature range whereas thermotropic liquid crystalline behavior for both compounds is not observed. Both of these novel compounds show no aggregation in toluene, tetrahydrofuran, dichloromethane and chloroform.


1951 ◽  
Vol 43 (3) ◽  
pp. 688-691 ◽  
Author(s):  
C. J. Maim ◽  
J. W. Mench ◽  
D. L. Kendall ◽  
G. D. Hiatt
Keyword(s):  

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