AbstractPrimary mineral phenocrysts from eight different late Quaternary pyroclastic deposits were fractionated for neutron-activation analysis with the purpose of characterizing each of the deposits on the basis of trace and minor element compositions. In hornblende separates, contents of several rare earth and transition elements were found to be distinctive for the Mazama, Glacier Peak, and several St. Helens deposits. In magnetites, abundances of transition elements are characteristic and serve as good discriminants for the pyroclastic deposits examined in this investigation. Contents of transition and rare earth elements in hyperthenes also appear useful in distinguishing volcanic ash deposits. Trace and minor element abundances in plagioclase phenocrysts did not appear adequate for identification of pyroclastics due to elemental depletion and similarity of contents for feldspar separates. It was found that contents of Sm and Yb in hornblende phenocrysts would serve to distinguish between several pyroclastic deposits from the Pacific Northwest.