Chromate and Molybdate Inhibitors Effects on Corrosion Charateristic of API 5L Grade B in a Brine Water Solution Containing 8 % NaCl

Piping systems at gathering stations in the oil and gas industries often fail due to corrosion attacks from the brine water solution containing 8% NaCl that flows through the system. This solution is highly corrosive on the API 5L grade B steel pipes, thereby shortening its lifespan, with an increase in the frequency of pipe replacements. However, the corrosion resistance of API 5L grade B pipes can be improved by using chromate and molybdate inhibitors. Therefore, the objective of this research is to improve the corrosion resistance of the steel pipes using sodium chromate (Na2CrO4) and sodium molybdate (Na2MoO4) inhibitors with concentrations of 0.2, 0.4, 0.6, 0.8 and 1,0%. This research also aim to determine the optimum concentration of inhibitors to produce minimum corrosion rate, by testing the brine water solution containing 8% NaCl through the potentiodynamic polarization method. The results show that generally, the addition of sodium chromate and sodium molybdate inhibitors to the brine solution causes the steel pipes to be more resistant to corrosion. Furthermore, the sodium chromate inhibitor concentration of 0.6% produces the greatest corrosion potential of – 400 mV with the lowest rate of 0.38 mpy, while sodium molybdate concentration of 0.4% produces the highest corrosion potential of – 385 mV with the lowest rate of 0.34 mpy. The results of SEM observations at 0.4% sodium molybdate concentration showed that the corrosion inhibition/passivation effect of the inhibitor made the steel surface smoother, while the sodium chromate inhibitor at similar percentage failed to reach the optimal concentration to inhibit the corrosion process.

A Novel Method for Evaluation of Chromium Evaporation from Solid Oxide Fuel Cells Interconnects: A Feasibility Study

The evaporation of volatile chromium species from ferritic stainless steels (FSSs) used as interconnect is well-known as degradation source for planar solid oxide fuel cell (SOFC) stacks. This work presents a feasibility study to quantify chromium evaporation from FSSs. It is based on measuring carbon dioxide produced by an intermediate reaction. Cr evaporated is collected by sodium carbonate forming sodium chromate and carbon dioxide. Measuring the resulting carbon dioxide allowed to quantify online the amount of reacted chromium with the carbonates. The post-experiment quantification of sodium chromate confirmed the applicability of the proposed method.