Role of Anionic Chromium Species in Leather Tanning

Chrome tanned leathers are definitely unique in comparison with leather made from any other known tanning agents, especially in terms of thermal stability, cost and its reactive mechanism with collagen fibers. In our current studies, self basifying chrome tanning materials masked with different percentages of organic acid were prepared and applied after the de-liming stage of leather processing. This eliminated the need for pickling and basification steps. Tanned leathers resisted shrinkage up to 103 and 105±2°C while conventional chrome tanned leathers resisted up to 108±2°C. Also, interaction of anionic chrome species in tanning was studied. It was observed that the percentage of anionic species in the experimental chrome tanning material was higher than conventional chrome tanning material and the shrinkage temperature achieved by application of experimental tanning material proves that anionic species do involve in tanning. Tanned leathers were crusted and analysed for strength and organoleptic properties.

Trivalent chromium isotopes in the eastern tropical North Pacific oxygen-deficient zone

Changes in chromium (Cr) isotope ratios due to fractionation between trivalent [Cr(III)] and hexavalent [Cr(VI)] are being utilized by geologists to infer oxygen conditions in past environments. However, there is little information available on Cr in the modern ocean to ground-truth these inferences. Transformations between the two chromium species are important processes in oceanic Cr cycling. Here we present profiles of hexavalent and trivalent Cr concentrations and stable isotope ratios from the eastern tropical North Pacific (ETNP) oxygen-deficient zone (ODZ) which support theoretical and experimental studies that predict that lighter Cr is preferentially reduced in low-oxygen environments and that residual dissolved Cr becomes heavier due to removal of particle-reactive Cr(III) on sinking particles. The Cr(III) maximum dominantly occurs in the upper portion of the ODZ, implying that microbial activity (dependent on the sinking flux of organic matter) may be the dominant mechanism for this transformation, rather than a simple inorganic chemical conversion between the species depending on the redox potential.

Dermatologic Toxicities and Biological Activities of Chromium

Chromium is a versatile metal with various industrial applications and biological activities. However, as a transition metal, this element forms several species, i.e. oxidation states of −4 to +6, with different degrees of toxicities that affect ecosystems and organisms including human beings. The skin is the outermost organ that usually interacts directly with chromium species in nature. These contact and interaction induce the formation of several acute and chronic negative effects including contact dermatitis, skin cancer, allergy, etc. In this chapter, toxicity and biological activity of several chromium species, such as chromium zero-valent, trivalent, hexavalent, will be reviewed to obtain better comprehension in chromium toxicity. Sources and routes of exposure, toxicity and possible treatment, and biological activity on the skin are arranged and explained systematically.

A Novel Method for Evaluation of Chromium Evaporation from Solid Oxide Fuel Cells Interconnects: A Feasibility Study

The evaporation of volatile chromium species from ferritic stainless steels (FSSs) used as interconnect is well-known as degradation source for planar solid oxide fuel cell (SOFC) stacks. This work presents a feasibility study to quantify chromium evaporation from FSSs. It is based on measuring carbon dioxide produced by an intermediate reaction. Cr evaporated is collected by sodium carbonate forming sodium chromate and carbon dioxide. Measuring the resulting carbon dioxide allowed to quantify online the amount of reacted chromium with the carbonates. The post-experiment quantification of sodium chromate confirmed the applicability of the proposed method.

Deep eutectic solvent decomposition-based microextraction for chromium determination in aqueous environments by atomic absorption spectrometry with electrothermal atomization

A sensitive, rapid, and simple procedure for the determination of traces of chromium species in natural and waste waters after microextraction using quasi-hydrophobic deep eutectic solvent based on tetrabutylammonium bromide...