Phytosterol Profiling of Apiaceae Family Seeds Spices Using GC-MS

Phytosterols are nutritionally vital phytoconstituent owing to their cholesterol (low-density plasma lipoprotein-cholesterol, LDL-C)-lowering, anti-inflammatory, and antioxidant properties. Among the widely used spices and herbs, the seeds spices of the Apiaceae family represented the healthiest fatty acid profile. Thus, to explore the other health-beneficial lipids, the present study was aimed to analyze the phytosterol profile of eight seed spices of the Apiaceae family, utilizing gas chromatography (GC)-mass spectrometry (MS). The sterols contents calculated on an oil (mg/100 g of oil) and spice weight (mg/100 g spices; dry weight) basis varied significantly among the seed spices (p < 0.05; Turkey HSD). The β-sitosterol and stigmasterol were the most dominating sterols among the studied spices, together accounted for 40.3 (Ajwain) to 69.8% (celery) of total sterols in the seed oil. Among the studied spices, the oil extracted from caraway seeds showed the highest total sterols (602.2 mg/100 g of oil). Interestingly, based on spice weight, fennel seeds also showed the similar highest number of total sterols (134.2 mg/100 g in fennel and 133.3 mg/100 g in caraway), owing to the high contents of oil (25.9%) in fennel seeds. Overall, celery, caraway, fennel, and anise seeds oil are rich sources of health-beneficial phytosterols.

AZIMUTHAL SURFACE WAVES IN LOW-DENSITY PLASMA LOADED, COAXIAL HELIX TRAVELING-WAVE-TUBE-LIKE WAVEGUIDES

The dispersion properties of flute electromagnetic waves propagating across an external axial static magnetic field in traveling-wave-tube-like waveguides with low-density plasma filling are investigated. The cylindrical structure consists of a central dielectric rod, placed inside a plasma coaxial layer with a metallic helix sheath on its outer interface, and a metal screen separated from the helix by another dielectric layer.

ICMEs and low plasma density in the solar wind observed at L1

&lt;p&gt;Different regimes of the solar wind have been observed at L1 during and after the passage of ICMEs, particularly anomalies with very low plasma density. From the observations at L1 (ACE) we identified different possible cases. A first case was explained by the evacuation of the plasma due over expansion of the ICME (May 2002). The second case on July 2002 is intriguing.In July 2002, three halo fast speed ICMEs, with their origin in the central part of the Sun, have surprisingly a poor impact on the magnetosphere (Dst &gt; -28 nT).&amp;#160;&amp;#160; Analyzing the characteristics of the first ICME at L1, we conclude that the spacecraft crosses the ICME with a large impact (Bx component in GSE coordinates is dominant). The plasma density is low, just behind this first ICME. Next, we explore the generic conditions of low density formation in the EUHFORIA simulations.The very low density plasma after the sheath could be explained by the spacecraft crossing, on the side of the flux rope, while behind the front shock. We investigate two possible interpretations. The shock was able to compress and accelerate so much the plasma that a lower density is left behind. This can also be due to an effect of the sheath magnetic field which extends the flux rope &amp;#160;effect on the sides of it, &amp;#160;&amp;#160;&amp;#160;so a decrease of plasma density could occur like behind a moving object (here the sheath field). The following ICME, with also a low density, could be an intrinsic case with the formation in the corona of a cavity. Finally, we present some runs of EUHFORIA which fit approximately these data and argue in favor of the possible interpretations detailed above.&lt;/p&gt;

Rotational spectroscopy of the HCCO and DCCO radicals in the millimeter and submillimeter range

Context. The ketenyl radical HCCO has recently been detected in the interstellar medium (ISM) for the first time. Further astronomical detections of HCCO will help us understand its gas-grain chemistry, and subsequently revise the oxygen-bearing chemistry towards dark clouds. Moreover, its deuterated counterpart DCCO has never been observed in the ISM. A broad spectroscopic investigation is still lacking for both HCCO and DCCO, although they exhibit a significant astrophysical relevance. Aims. In this work we aim to measure the pure rotational spectra of the ground state of HCCO and DCCO in the millimeter and submillimeter region, considerably extending the frequency range covered by previous studies. Methods. The spectral acquisition was performed using a frequency-modulation absorption spectrometer between 170 and 650 GHz. The radicals were produced in a low-density plasma generated from a select mixture of gaseous precursors. We were able to detect and assign more than 100 rotational lines for each isotopolog. Results. The new lines have significantly enhanced the previous data set allowing the determination of highly precise rotational and centrifugal distortion parameters. In our analysis we took into account the interaction between the ground electronic state and a low-lying excited state (Renner–Teller pair) which enables the prediction and assignment of rotational transitions with Ka up to 4. Conclusions. The present set of spectroscopic parameters provides highly accurate, millimeter, and submillimeter rest-frequencies of HCCO and DCCO for future astronomical observations. We also show that towards the pre-stellar core L1544, ketenyl peaks in the region where c-C3H2 peaks, suggesting that HCCO follows a predominant hydrocarbon chemistry, as already proposed by recent gas-grain chemical models.

Generation of high-temperature and low-density plasma with strong spectral intensity by changing the distance between the focusing lens and target surface in femtosecond laser-induced breakdown spectroscopy

This paper exhibits the generation of high-temperature and low-density plasma with strong spectral intensity by changing the distance between focusing lens and target surface in femtosecond laser-induced breakdown spectroscopy.