methoxy radicals
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Hydrogen/Deuterium Transfer from Anisole to Methoxy Radicals: A Theoretical Study of a Deuterium-Labeled Drug Model

2022 ◽  
Author(s):  
Yuka Kimura ◽  
Yusuke Kanematsu ◽  
Hiroki Sakagami ◽  
David S. Rivera Rocabado ◽  
Tomomi Shimazaki ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Methoxy Radicals ◽  
Hydrogen Deuterium

scholarly journals ANTIOKSIDATIVNI KAPACITET ANTRAHINONA IZ BILJKE RUBIA CORDIFOLIA LINN

2021 ◽  
Author(s):  
Žiko Milanovic ◽  
◽  
Marko Antonijevic ◽  
Ana Kesic ◽  
Dusan Dimic ◽  
...  
Keyword(s):  
Gas Phase ◽  
Reaction Mechanisms ◽  
Dft Method ◽  
Probable Mechanism ◽  
Reaction Pathways ◽  
Antioxidant Action ◽  
Rubia Cordifolia ◽  
Methoxy Radicals ◽  
Favorable Reaction ◽  
Antioxidant Mechanisms

In this study, the antioxidant and antiradical capacities of anthraquinones from Rubia cordifolia Linn were determined using the DFT method. The thermodynamically most favorable reaction pathways of antioxidant mechanisms were defined, as well as the most favorable antiradical reaction mechanisms for the deactivation of methylperoxyl and methoxy radicals. The calculations were done in the gas phase. HAT is thermodynamically the most favorable mechanism of antioxidant action of the studied anthraquinones, while the most probable mechanism of deactivation of methylperoxyl and methoxy radicals is the SPLET mechanism.

Infrared absorption spectra of partially deuterated methoxy radicals CH2DO and CHD2O isolated in solid para-hydrogen

2017 ◽  
Vol 147 (15) ◽  
pp. 154305 ◽  
Author(s):  
Karolina A. Haupa ◽  
Britta A. Johnson ◽  
Edwin L. Sibert ◽  
Yuan-Pern Lee
Keyword(s):  
Absorption Spectra ◽  
Infrared Absorption ◽  
Para Hydrogen ◽  
Methoxy Radicals ◽  
Infrared Absorption Spectra

Isomerization of the methoxy radical revisited: the impact of water dimers

2016 ◽  
Vol 18 (40) ◽  
pp. 27728-27732 ◽  
Author(s):  
Pradeep Kumar ◽  
Partha Biswas ◽  
Biman Bandyopadhyay
Keyword(s):  
Lower Troposphere ◽  
Methoxy Radicals ◽  
Methoxy Radical ◽  
The Impact ◽  
Water Dimers

Investigations carried out at MP2 and CCSD(T) levels of theory show that water dimers can compete with formic and sulfuric acids in catalyzing isomerization of methoxy radicals in the lower troposphere.

Anodic Oxidation on a Boron-Doped Diamond Electrode Mediated by Methoxy Radicals

2012 ◽  
Vol 51 (22) ◽  
pp. 5443-5446 ◽  
Author(s):  
Takenori Sumi ◽  
Tsuyoshi Saitoh ◽  
Keisuke Natsui ◽  
Takashi Yamamoto ◽  
Mahito Atobe ◽  
...  
Keyword(s):  
Anodic Oxidation ◽  
Boron Doped Diamond ◽  
Methoxy Radicals ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode

Anodic Oxidation on a Boron-Doped Diamond Electrode Mediated by Methoxy Radicals

2012 ◽  
Vol 124 (22) ◽  
pp. 5539-5542 ◽  
Author(s):  
Takenori Sumi ◽  
Tsuyoshi Saitoh ◽  
Keisuke Natsui ◽  
Takashi Yamamoto ◽  
Mahito Atobe ◽  
...  
Keyword(s):  
Anodic Oxidation ◽  
Boron Doped Diamond ◽  
Methoxy Radicals ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Boron Doped Diamond Electrode

Temperature-Dependent Branching Ratios of Deuterated Methoxy Radicals (CH2DO•) Reacting With O2

2012 ◽  
Vol 116 (24) ◽  
pp. 6295-6302 ◽  
Author(s):  
Hongyi Hu ◽  
Theodore S. Dibble ◽  
Geoffrey S. Tyndall ◽  
John J. Orlando
Keyword(s):  
Branching Ratios ◽  
Temperature Dependent ◽  
Methoxy Radicals

Rates of Reactions Between Methoxycarbonyl, Methyl and Methoxy Radicals Formed in Flash Photolysis of Dimethyl Oxalate in Gas Phase

2010 ◽  
Vol 92 (10) ◽  
pp. 847-847 ◽  
Author(s):  
E. Hassinen ◽  
P. Riepponen ◽  
K. Blomqvist ◽  
K. Kalliorinne ◽  
J. Koskikallio
Keyword(s):  
Gas Phase ◽  
Flash Photolysis ◽  
Methoxy Radicals ◽  
Dimethyl Oxalate
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