Exsolution in alkali feldspar in ordinary chondrites: Ubiquitous evidence for rapid cooling at high temperatures

SummaryPhase relations at atmospheric pressure in the pseudobinary join KAlSi2O6 (Lc)-NaAlSi3O8(Ab) and in the pseudoternary join Lc-Ab-CaAl2Si2O8(An) indicate that leucite is in-compatible with Na-feldspar. In the former join leucite can exist with an alkali feldspar of maximum albite content Ab54. In the Lc-Ab-An join, leucite only coexists with ternary feldspars with high An contents (approximately An50). Under PH2O conditions leucites may only coexist with alkali feldspars even poorer in Ab than those found at atmospheric pressure. Rare occurrences of coexisting leucite and Na-feldspar in nature have probably not crystallized directly from a melt but may have formed by a process of alkali ion exchange; or they may be unstable assemblages. No support can be found for the suggestions based on thermochemical calculations that albite and leucite are compatible at high temperatures.

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The Anvil plutonic suite, Faro, Yukon Territory

Canadian Journal of Earth Sciences ◽

10.1139/e85-122 ◽

1985 ◽

Vol 22 (8) ◽

pp. 1204-1216 ◽

Cited By ~ 8

Author(s):

Lee C. Pigage ◽

Robert G. Anderson

Keyword(s):

Alkali Feldspar ◽

Biotite Granite ◽

Yukon Territory ◽

South Fork ◽

Calc Alkaline ◽

Rapid Cooling ◽

High K ◽

Intrusive Activity ◽

High Level ◽

Main Deformation

The Anvil plutonic suite consists of three phases: a peraluminous muscovite–biotite granite (Mount Mye phase) and two metaluminous to peraluminous hornblende–biotite granodiorite and minor granite intrusions (Orchay and Marjorie phases). The suite is massive or foliated, equigranular or seriate, and contains alkali-feldspar megacrysts. The Marjorie phase is characteristically porphyritic.Geochemical trends are irregular for the suite and for individual phases. High-K2O, low-CaO, and low-MgO compositions typify the silicic, calc-alkaline suite. Hornblende-bearing phases contain less SiO2, K2O, and Rb and more cafemic oxides, TiO2, Sr, Ba, and Y than the Mount Mye phase and are compositionally similar to coeval South Fork volcanics.Isochrons from some of the Orchay phase whole-rock samples (t = 99 ± 2.5 Ma; 87Sr/86Sri = 0.7161 ± 0.0001) and from whole rocks and minerals of the Mount Mye phase (t = 100 ± 2 Ma; 87Sr/86Sri = 0.7405 ± 0.0001) indicate they are coeval but not comagmatic, accounting for the lithologic, petrographic, and geochemical distinctions. Similar K–Ar isotopic ages (81–102 Ma) suggest rapid cooling and therefore high-level emplacement. Together, the isotopic ages provide a minimum (youngest) age for the main deformation of the surrounding metasediments and a maximum (oldest) age for movement along the Tintina Fault.A petrographically and geochemically distinct sample from the Orchay phase yielded a Rb–Sr isochron age of 61 ± 1.5 Ma and an initial 87Sr/86Sr ratio of 0.7090 ± 0.0001, implying intrusive activity in the Paleocene.Field relations, lithology, petrography, geochronometry, and geochemistry suggest that the Orchay and Marjorie phases are plutonic equivalents of the South Fork volcanics. Similarities in plutonic style characterize the extensive mid-Cretaceous igneous event in southeast Yukon.

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Electrical conductivity of alkali feldspar solid solutions at high temperatures and high pressures

Physics and Chemistry of Minerals ◽

10.1007/s00269-012-0546-4 ◽

2012 ◽

Vol 40 (1) ◽

pp. 51-62 ◽

Cited By ~ 20

Author(s):

Haiying Hu ◽

Heping Li ◽

Lidong Dai ◽

Shuangming Shan ◽

Chengming Zhu

Keyword(s):

Electrical Conductivity ◽

High Temperatures ◽

Solid Solutions ◽

High Pressures ◽

Alkali Feldspar

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Present and Future Capabilities of Acoustic Levitation and Positioning Devices

MRS Proceedings ◽

10.1557/proc-9-137 ◽

1981 ◽

Vol 9 ◽

Cited By ~ 2

Author(s):

Charles A. Rey ◽

Roy R. Whymark ◽

Thomas J. Danley ◽

Dennis R. Merkley

Keyword(s):

Physical Properties ◽

High Temperatures ◽

Shape Control ◽

Surface Shape ◽

Acoustic Levitation ◽

Containerless Processing ◽

Resonant Cavities ◽

Rapid Cooling ◽

Liquid Drops ◽

Positioning Devices

ABSTRACTThe techniques of acoustic positioning without the use of resonant cavities have been explored and developed over a number of years and the currently available capabilities are reviewed. The performance and characteristics of these nonresonant acoustic systems are described in regard to containerless processing with emphasis on the low-g environment. This includes manipulation and mixing of liquid drops, super-cooling phenomena, heating to temperatures of 1600°C or higher, rapid cooling solidification, and surface shape control. Some possible applications are measurements of physical properties of substances at high temperatures or of highly reactive specimens, and the formation of unique glasses and alloys of new compositions.

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In situ REM imaging of surface processes on ceramic bulk crystals from 300 to 1670 K in a conventional TEM

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100087616 ◽

1991 ◽

Vol 49 ◽

pp. 660-661

Author(s):

Z. L. Wang ◽

J. Bentley

Keyword(s):

High Temperatures ◽

Image Resolution ◽

Atomic Processes ◽

Crystal Surfaces ◽

Beam Radiation ◽

Surface Areas ◽

Transmission Electron ◽

Reflection Electron Microscopy ◽

Gas Reactions

Studying the behavior of surfaces at high temperatures is of great importance for understanding the properties of ceramics and associated surface-gas reactions. Atomic processes occurring on bulk crystal surfaces at high temperatures can be recorded by reflection electron microscopy (REM) in a conventional transmission electron microscope (TEM) with relatively high resolution, because REM is especially sensitive to atomic-height steps.Improved REM image resolution with a FEG: Cleaved surfaces of a-alumina (012) exhibit atomic flatness with steps of height about 5 Å, determined by reference to a screw (or near screw) dislocation with a presumed Burgers vector of b = (1/3)<012> (see Fig. 1). Steps of heights less than about 0.8 Å can be clearly resolved only with a field emission gun (FEG) (Fig. 2). The small steps are formed by the surface oscillating between the closely packed O and Al stacking layers. The bands of dark contrast (Fig. 2b) are the result of beam radiation damage to surface areas initially terminated with O ions.

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Domain coarsening by grain boundary migration in ordered Ni4Mo

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100144279 ◽

1986 ◽

Vol 44 ◽

pp. 560-561

Author(s):

K. Vasudevan ◽

H. P. Kao ◽

C. R. Brooks ◽

E. E. Stansbury

Keyword(s):

Grain Boundary ◽

Grain Boundaries ◽

Short Range ◽

Boundary Migration ◽

Grain Boundary Migration ◽

Rapid Cooling ◽

Temperature Range ◽

Fee Structure ◽

Domain Coarsening ◽

Boundary Reaction

The Ni4Mo alloy has a short-range ordered fee structure (α) above 868°C, but transforms below this temperature to an ordered bet structure (β) by rearrangement of atoms on the fee lattice. The disordered α, retained by rapid cooling, can be ordered by appropriate aging below 868°C. Initially, very fine β domains in six different but crystallographically related variants form and grow in size on further aging. However, in the temperature range 600-775°C, a coarsening reaction begins at the former α grain boundaries and the alloy also coarsens by this mechanism. The purpose of this paper is to report on TEM observations showing the characteristics of this grain boundary reaction.

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