SS-waves (SV-SV waves and SH-SH waves) are capable of inverting S-wave velocity ( VS) and density ( ρ) because they are sensitive to both parameters. SH-SH waves can be separated from multicomponent data sets more effectively than the SV-SV wave because the former is decoupled from the PP-wave in isotropic media. In addition, the SH-SH wave can be better modeled than the SV-SV wave in the case of strong velocity/impedance contrast because the SV-SV wave has multicritical angles, some of which can be quite small when velocity/ impedance contrast is strong. We derived an approximate equation of the SH-SH wave reflection coefficient as a function of VS and ρ in natural logarithm variables. The approximation has high accuracy, and it enables the inversion of VS and ρ in a direct manner. Both coefficients corresponding to VS and ρ are “model-parameter independent” and thus there is no need for prior estimate of any model parameter in inversion. Then, we developed an SH-SH wave inversion method, and demonstrated it by using synthetic data sets and a real SH-SH wave prestack data set from the west of China. We found that VS and ρ can be reliably estimated from the SH-SH wave of small angles.