Ba2B5O8(OH)2(NO3)·3H2O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate

2022 ◽  
Author(s):  
Huaiyu Hu ◽  
Junben Huang ◽  
Zhiyong Guo ◽  
Min Zhang ◽  
Zhihua Yang ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Two Dimensional ◽  
Space Group ◽  
Metal Borate

The first alkaline earth metal borate-nitrate, namely, Ba2B5O8(OH)2(NO3)·3H2O (BBNOH), has been synthesized by the hydrothermal method. BBNOH crystallizes in the space group of P21/c and exhibits two-dimensional (2D) 2∞[B5O8(OH)2]3-borate anion...

scholarly journals Alkali metal–alkaline earth metal borate crystal LiBa3(OH)(B9O16)[B(OH)4] as a new deep-UV nonlinear optical material

2016 ◽  
Vol 4 (35) ◽  
pp. 8189-8196 ◽  
Author(s):  
Chao Wu ◽  
Junling Song ◽  
Longhua Li ◽  
Mark G. Humphrey ◽  
Chi Zhang
Keyword(s):  
Alkali Metal ◽  
Hydrothermal Method ◽  
Nonlinear Optical ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Nonlinear Optical Material ◽  
Facile Hydrothermal Method ◽  
Deep Uv ◽  
Metal Borate

A new deep-UV nonlinear optical borate, with the formula LiBa3(OH)(B9O16)[B(OH)4] is synthesized using a facile hydrothermal method.

Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb9Ba24(BO3)19

2020 ◽  
Vol 44 (10) ◽  
pp. 3882-3887 ◽  
Author(s):  
Xiaowen Niu ◽  
Li Wang
Keyword(s):  
Crystal Structure ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Mixed Alkali ◽  
Metal Borate

Rb9Ba24(BO3)19 features an intricate 3D Ba–O framework with three types of infinite channels where the Rb+ cations and isolated BO3 units are located.

scholarly journals Die Kristallstrukturen von Strontium- und Bariumhexacyanoferrat(III)-Hexamethylentetramin-Hydraten. Strukturmodell für Additionsverbindungen der Alkali- und Erdalkalimetallhexacyanoferrate mit Hexamethylentetramin / The Crystal Structures of Hydrates of Strontium and Barium Hexacyanoferrate(III) with Hexamethylenetetramine. Structural Model for Adducts of the Hexacyanoferrates of Alkaline and Alkaline Earth Metals with Hexamethylenetetramine

1989 ◽  
Vol 44 (5) ◽  
pp. 519-525 ◽  
Author(s):  
Hans-Jürgen Meyer ◽  
Joachim Pickardt
Keyword(s):  
Aqueous Solutions ◽  
Crystal Structures ◽  
General Formula ◽  
Alkaline Earth ◽  
Structural Model ◽  
Earth Metal ◽  
Alkaline Earth Metals ◽  
Alkaline Earth Metal ◽  
Monoclinic Space Group ◽  
Space Group

By reaction of methanolic solutions of hexamethylenetetramine with aqueous solutions of hexacyanoferrates(III) of strontium and barium resp., crystals of the compounds were obtained. Sr3[Fe(CN)6]2 · 3 C6H12N4 · 18 H2O, tetragonal, space group P42/nmc, Z = 4, a = 1931.8(4), c = 1579.9(4) pm, 1358 reflections. R = 0.066. Ba3[Fe(CN)6]2 · 2 C6H12N4 · 11 Η2Ο. monoclinic. space group P21/n, Ζ = 2, a = 1148.0(4), b = 1369.7(4), c = 1584.5(4) pm, γ = 95.79(3)°, 2583 reflections, R = 0.057. The crystal structures of these adducts are compared with those of other hexamethylenetetramine adducts of alkaline and alkaline earth metal hexacyanoferrates of the general formula M,[Fe(CN)6]y · zC6H12N4 · vH2O recently investigated by us. A structural model for the adducts is presented.

Syntheses, Structures, and Properties of Two-Dimensional Alkaline Earth Metal Complexes with Flexible Tripodal Tricarboxylate Ligands

2005 ◽  
Vol 5 (1) ◽  
pp. 177-182 ◽  
Author(s):  
Hui-Fang Zhu ◽  
Zheng-Hua Zhang ◽  
Wei-Yin Sun ◽  
Taka-aki Okamura ◽  
Norikazu Ueyama
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Two Dimensional ◽  
Structures And Properties

Sr3B14O24: A New Borate with [B14O30] Fundamental Building Block and Unwonted 2D Double Layer

2021 ◽  
Author(s):  
Chengfa Wu ◽  
Zilong Chen ◽  
Jianbang Chen ◽  
Zhihua Yang ◽  
Fangfang Zhang ◽  
...  
Keyword(s):  
Building Block ◽  
Alkaline Earth ◽  
Solution Method ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Monoclinic Space Group ◽  
High Temperature Solution ◽  
Fundamental Building Block ◽  
Temperature Solution ◽  
Metal Borate

A new alkaline-earth metal borate, Sr3B14O24, was successfully synthesized by high temperature solution method. It crystallizes in the monoclinic space group P21/c (No. 14) and features a fundamental building block...

A new alkaline-earth metal borate SrB 3 O 4 (OH) 3 ·H 2 O with UV cutoff edge below 190 nm

2018 ◽  
Vol 92 ◽  
pp. 35-39 ◽  
Author(s):  
Hong-Jun Zhou ◽  
Li-Xian Chang ◽  
Yan-Hui Zhang ◽  
Li Wang ◽  
Mohamedally Kurmoo
Keyword(s):  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Borate

Ba2B10O17: a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge

2014 ◽  
Vol 43 (23) ◽  
pp. 8905-8910 ◽  
Author(s):  
Lili Liu ◽  
Xin Su ◽  
Yun Yang ◽  
Shilie Pan ◽  
Xiaoyu Dong ◽  
...  
Keyword(s):  
Band Gap ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Transmission Range ◽  
Barium Borate ◽  
Deep Uv ◽  
Metal Borate

Ba2B10O17, a new barium borate, with a band-gap of 5.97 eV, possesses a wide transmission range from 180 to 3000 nm.

Über Erdalkalimetallverbindungen des 1,1-Dicyanoethylen-2,2-dithiolats, III+ Die Kristallstruktur von SrS2C4N2 · 5 H2O / On Alkaline-Earth Metal Compounds of 1 ,1-Dicyanoethylene-2 ,2 -dithiolate, III+ Crystal Structure of SrS2C4N2 · 5 H2O

1986 ◽  
Vol 41 (10) ◽  
pp. 1206-1210 ◽  
Author(s):  
Hans-U. Hummel ◽  
C. Wolf
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Coordination Sphere ◽  
Alkaline Earth ◽  
Structural Model ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Compounds ◽  
Space Group ◽  
Trigonal Prismatic

Abstract By reaction of CS2 with maleonitrile in presence of sodiumethanolate in ethanol, Na2S2C4N2 is obtained. SrS2C4N2 · 5 H2O was synthesized by reaction of Sr(NCS)2 with Na2S2C4N2 in ethanol. It crystallizes monoclinically, space group P21/c, with a = 9.201(2), b = 9.990(6), c = 14.605(5) Å, β = 122.3(3)°, Z = 4. The compound is isotypical with CaS2C4N2 · 5 H2O. A structural model based on equivalent metal positions was refined to R = 0.057. The crystal structure contains layers of nearly planar [S2C = C(CN)2]2- anions held together by interspersed Sr2+ cations in a tricapped trigonal prismatic surrounding of 6O and 3N atoms. The S atoms of the ligand are not included in the coordination sphere of Sr2+ but are involved in several O - H···S hydrogen bonds.

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