Stereodynamic insight into the thermal history effects on poly(vinyl chloride) calorimetric sub-glass and glass transitions as a fragile glass model

Exploration of the dynamic thermal history impact on a model polymer in the sub-glass/glass transition regions.

The amorphous state: first-principles derivation of the Gordon–Taylor equation for direct prediction of the glass transition temperature of mixtures; estimation of the crossover temperature of fragile glass formers; physical basis of the “Rule of 2/3”

Predicting the glass transition and crossover temperatures of pure amorphous phases and mixtures finds broad application across different fields of study.