Light Emission Properties of Thermally Evaporated CH3NH3PbBr3 Perovskite from Nano- to Macro-Scale: Role of Free and Localized Excitons

Over the past decade, interest about metal halide perovskites has rapidly increased, as they can find wide application in optoelectronic devices. Nevertheless, although thermal evaporation is crucial for the development and engineering of such devices based on multilayer structures, the optical properties of thermally deposited perovskite layers (spontaneous and amplified spontaneous emission) have been poorly investigated. This paper is a study from a nano- to micro- and macro-scale about the role of light-emitting species (namely free carriers and excitons) and trap states in the spontaneous emission of thermally evaporated thin layers of CH3NH3PbBr3 perovskite after wet air UV light trap passivation. The map of light emission from grains, carried out by SNOM at the nanoscale and by micro-PL techniques, clearly indicates that free and localized excitons (EXs) are the dominant light-emitting species, the localized excitons being the dominant ones in the presence of crystallites. These species also have a key role in the amplified spontaneous emission (ASE) process: for higher excitation densities, the relative contribution of localized EXs basically remains constant, while a clear competition between ASE and free EXs spontaneous emission is present, which suggests that ASE is due to stimulated emission from the free EXs.

Investigation of Threshold Carrier Densities in the Optically Pumped Amplified Spontaneous Emission of Formamidinium Lead Bromide Perovskite Using Different Excitation Wavelengths

The high crystal quality of formamidium lead bromide perovskite (CH(NH2)2PbBr3 = FAPbBr3) was infiltrated in a mesoporous TiO2 network. Then, high-quality FAPbBr3 films were evaluated as active lasing media, and were irradiated with a picosecond pulsed laser to demonstrate amplified spontaneous emission (ASE), which is a better benchmark of its intrinsic suitability for gain applications. The behavior was investigated using two excitation wavelengths of 440 nm and 500 nm. Due to the wavelength-dependent absorbance spectrum and the presence of a surface adsorption layer that could be reduced using the shorter 440 nm wavelength, the ASE power dependence was strongly reliant on the excitation wavelength. The ASE state was achieved with a threshold energy density of ~200 µJ/cm2 under 440 nm excitation. Excitation at 500 nm, on the other hand, needed a higher threshold energy density of ~255 µJ/cm2. The ASE threshold carrier density, on the other hand, was expected to be ~4.5 × 1018 cm−3 for both excitations. A redshift of the ASE peak was detected as bandgap renormalization (BGR), and a BGR constant of ~5–7 × 10−9 eV cm was obtained.

Loss prediction of three-level amplified spontaneous emission sources in radiation environment

A model of three-level amplified spontaneous emission (ASE) sources, considering radiation effect, is proposed to predict radiation induced loss of output power in radiation environment. Radiation absorption parameters of ASE sources model are obtained by the fitting of color centers generation and recovery process of and gain loss data at lower dose rate. Gain loss data at higher dose is applied for self-validating. This model takes both the influence of erbium ions absorption and photon bleaching effect into consideration, which makes the prediction of different dose and dose rate more accurate and flexible. The fitness value between ASE model and gain loss data is 99.98%, which also satisfies the extrapolation at the low dose rate. The method and model may serve as a valuable tool to predict ASE performance in harsh environment.

The effects of pump pulse fluence on the output energy and amplified spontaneous emission of a femtosecond regenerative amplifier

In this paper, the effects of pump pulse fluence on the output energy and amplified spontaneous emission (ASE) of a femtosecond regenerative amplifier are investigated. One can easily enhance the output energy of laser amplifiers by increasing their pump fluence. This in turn can increase the ASE and reduce the performance of amplifiers in terms of output beam quality, beam stability, etc. This effect would eventually lead to what is called ‘temporal intensity contrast deterioration’. In this work, it is shown that an optimum state of the pump pulse fluence can indeed optimize the amount of the output energy from a regenerative amplifier without much reducing the performance of the amplifier due to the higher ASE. Temporal gain characteristics were employed to achieve this optimum value for a better design, performance, and maintenance of femtosecond laser amplifiers. The results of the current study can be effectively used in designing a wide range of regenerative amplifiers for femtosecond pulses.